Abstract
The second chapter covers the main liquid biofuels such as bioethanol, biomethanol, liquid fuels from Fischer–Tropsch Synthesis (FTS), and bio-syngas and biohydrogen. Biomass energy technologies (liquefaction, pyrolysis and gasification), liquid biofuels (bioethanol and biomethanol) for automobiles from lignocellulosic materials by hydrolysis and fermentation, syngas by FTS, gasoline and diesel like oils by FTS, and biohydrogen from biomass by steam reforming have been investigated. Progress and recent trends in biofuels and global biofuel senarios have been presented in this chapter.
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References
Adeeb Z. 2004. Glycerol delignification of poplar wood chips in aqueous medium. Energy Edu Sci Technol 13:81-88
Ahón, V.R., Costa, E.F., Jr., Monteagudo, J.E.P., Fontes, C.E., Biscaia, E.C., Jr., Lage, P.L.C. 2005. A comprehensive mathematical model for the Fischer–Tropsch synthesis in well-mixed slurry reactors. Chem Eng Sci 60:677-694
Anderson, R.B. 1984. The Fischer–Tropsch Synthesis. Academic, New York
Azar, C., Lindgren, K., Andersson, B.A. 2003. Global energy scenarios meeting stringent CO2 constraints—cost-effective fuel choices in the transportation sector. Energy Policy 31: 961-976
Bala, B.K. 2005. Studies on biodiesels from transformation of vegetable oils for diesel engines. Edu Sci Technol 15:1-45
Balat, M. 2005. Biodiesel from vegetable oils via transesterification in supercritical ethanol. Energy Edu Sci Technol 16:45-52
Balat, M. 2006. Sustainable transportation fuels from biomass materials. Energy Edu Sci Technol 17:83-103
Baltz, R.A., Burcham, A.F., Sitton, O.C., Book, N.L. 1982. The recycling of sulfuric acid and xylose in the prehydrolysis of corn stover. Energy 7:259-265
Berg, C. 1988. Towards a world ethanol market? F.O. Licht Commodity Analysis, Ratzeburg, Germany.
Bothast, R.J., Schlicher, M.A. 2005. Biotechnological processes for conversion of corn into ethanol. Appl Microbiol Biotechnol 67:19-25
Bowen, D.A., Lau, F., Zabransky, R., Remick, R., Slimane, R., Doong, S. 2003. Techno-economic analysis of hydrogen production by gasification of biomass. NREL 2003 progress report, Renewable Energy Laboratory, Golden, CO.
Bridgwater, A.V. 2003. Renewable fuels and chemicals by thermal processing of biomass. Chem Eng J 91:87-102
Brown, H.P., Panshin, A. J., Forsaith, C.C. 1952. Textbook of wood technology, Vol. II. Hill, New York
Bukur, D.B., Nowicki, L., Manne, R.V., Lang, X. 1995. Activation studies with a precipitated iron catalysts for the Fischer–Tropsch synthesis. J Catal 155:366-375
Cadenas, A., Cabezudo, S. 1998. Biofuels as sustainable technologies: perspectives for less developed countries. Technol Forecast Social Change 58:83–103
Canakci, M., Van Gerpen, J. 2001. Biodiesel production from oils and fats with high free fatty acids. Am Soc Agric Eng 4:1429-1436
Castro, F.B., Hotten, P.M., Ørskov, E.R. 1993. The potential of dilute-acid hydrolysis as a treatment for improving the nutritional quality of industrial lignocellulosic by products. Animal Feed Sci Technol 42:39-53
Chmielniak, T., Sciazko, M. 2003. Co-gasification of biomass and coal for methanol synthesis. Energy 74:393-403
Choudhary, T.V., Goodman, D.W. 2000. CO-free production of hydrogen via stepwise steam reforming of methane. J Catal 192:316-321
Davis, B.H. 2002. Overview of reactors for liquid phase Fischer–Tropsch synthesis. Catal Today 71:249-300
Demirbas, A. 1999. Fuel properties of charcoal derived from hazelnut shell and the production of briquets using pyrolytic oil. Energy 24:141-150
Demirbas, A. 2000. Mechanisms of liquefaction and pyrolysis reactions of biomass. Energy Convers Mgmt 41:633-646
Demirbas, A. 2002. Biodiesel from vegetable oils via transesterification in supercritical methanol. Energy Convers Mgmt 43:2349-2356
Demirbas, A. 2003. Biodiesel fuels from vegetable oils via catalytic and non-catalytic supercritical alcohol transesterifications and other methods: a survey. Energy Convers Mgmt 44:2093-2109
Demirbas, A. 2004. Hydrogen rich gas from fruit shells via supercritical water extraction. Int J Hydrogen Energy 29:1237-1243
Demirbas, A. 2005. Biodiesel production from vegetable oils via catalytic and non-catalytic supercritical methanol transesterification methods. Prog Energy Combust Sci 31:466-487
Demirbas, A. 2006a. Global biofuel strategies. Energy Edu Sci Technol 17:27-63.
Demirbas, A. 2006b. Biogas potential of manure and straw mixtures. Energy Sour 28:71-78
Demirbas, M.F. 2006c. Hydrogen from various biomass species via pyrolysis and steam gasification processes. Energy Sour A 28:245-252
Demirbas, A., Arin, G. 2002. An overview of biomass pyrolysis. Energy Sour 5:471-482
Demirbas, M.F., Balat, M. 2006. Recent advances on the production and utilization trends of bio-fuels: a global perspective. Energy Convers Mgmt 47:2371-2381
Demirbas, A., Gullu, D. 1998. Acetic acid, methanol and acetone from lignocellulosics by pyrpolysis. Edu Sci Technol 1:111-115
Difiglio, C. 1997. Using advanced technologies to reduce motor vehicle greenhouse gas emissions. Energy Policy 25:1173-1178
Dong, Y., Steinberg, M. 1997. Hynol—an economical process for methanol production from biomass and natural gas with reduced CO2 emission. Int J Hydrogen Energy 22:971-977
Dry, M.E. 1999. Fischer-Tropsch reactions and the environment. Appl Catal A General 189:185-190
Dry, M.E. 2002a. High quality diesel via the Fischer–Tropsch process-a review. J Chem Technol Biotechnol 77:43-50
Dry, M.E. 2002b. The Fischer–Tropsch process: 1950-2000. Catal Today 71:227-241.
Dry, M.E. 2004. Present and future applications of the Fischer-Tropsch process. Appl Catal AÂ 276:1-3.
EC (European Commission). 2004. Promoting Biofuels in Europe. European Commission, Directorate -General for Energy and Transport, B-1049 Brussels, Belgium. http://europa.eu.int/comm/dgs/energy_transport/index_en.html.
Encinar, J.M., Beltran, F.J., Ramiro, A., Gonzalez, J.F. 1998. Pyrolysis/gasification of agricultural residues by carbon dioxide in the presence of different additives: influence of variables. Fuel Process Technol 55:219-233.
Ghadge, S.V., Raheman, H. 2006. Process optimization for biodiesel production from mahua (Madhuca indica) oil using response surface methodology. Bioresour Technol 97:379-384.
Grassi, G. 1999. Modern bioenergy in the European Union. Renew Energy 6:985-990.
Gullu, D., Demirbas, A. 2001. Biomass to methanol via pyrolysis process. Energy Convers Mgmt 42:1349-1356.
Haas, M.J., McAloon, A.J., Yee, W.C., Foglia, T.A. 2006. A process model to estimate biodiesel production costs. Bioresour Technol 97:671-678.
Hall, D.O., Rosillo-Calle, F., Williams, R.H., Woods, J. 1993. Biomass for energy: supply prospects: Johansson, T.B., Kelly, H., Reddy, A.K.N., Williams, R.H. (eds.) Renewable Energy–for Fuels and Electricity. Island Press, Washington, D.C.
Hansen, A.C., Zhang, Q., Lyne, P.W.L. 2005. Ethanol–diesel fuel blends—a review. Technology 96:277-285.
Hao, X.H., Guo, L.J. 2002. A review on investigation of hydrogen production by biomass catalytic gasification in supercritical water. Huagong Xuebao 53:221-8 [in Chinese].
IEA (International Energy Agency). 2004. Biofuels for transport: an international perspective. 9, rue de la Fédération, 75739 Paris, cedex 15, France. www.iea.org.
IPCC. 1997. Greenhouse Gas Inventory Reference Manual: Revised 1996 IPCC Guidelines for National Greenhouse Gas Inventories, Report Vol. 3, p. 1.53, Intergovernmental Panel on Climate Change (IPCC), Paris, France. www.ipcc.ch/pub/guide.htm.
Iwasa, N., Kudo, S., Takahashi, H., Masuda, S., Takezawa, N. 1993. Highly selective supported Pd catalysts for steam reforming of methanol. Catal Lett 19:211-216.
Jager, B. 1998. Proceedings of the 5th Natural Gas Conversion Symposium, Taormina, Italy, September 1998.
Jin, Y., Datye, A.K. 2000. Phase transformations in iron Fischer–Tropsch catalysts during temperature-programmed reduction. J Catal 196:8-17.
Jothimurugesan, K., Goodwin, J.G., Santosh, S.K., Spivey, J.J. 2000. Development of Fe Fischer–Tropsch catalysts for slurry bubble column reactors. Catal Today 58:335-344.
Jun, K.W., Roh, H.S., Kim, K.S., Ryu, J.S., Lee, K.W. 2004. Catalytic investigation for Fischer–Tropsch synthesis from bio-mass derived syngas. Appl Catal A 259:221-226.
Kapdi, S.S., Vijay, V.K., Rajesh, S.K., Prasad, R. 2005. Biogas scrubbing, compression and storage: perspective and prospectus in Indian context. Renew Energy 30:1195-1202.
Kartha, S., Larson, E.D. 2000. Bioenergy primer: modernised biomass energy for sustainable development, Technical Report UN Sales Number E.00.III.B.6, United Nations Development Programme, 1 United Nations Plaza, New York, NY 10017.
Kim, S., Dale, B.E. 2005. Life cycle assessment of various cropping systems utilized for producing: bioethanol and biodiesel. Biomass Bioenergy 29:426-439.
Kumar, A., Cameron, J.B., Flynn, P.C. 2005. Pipeline transport and simultaneous saccharification of corn stover. Bioresour Technol 96:819-829.
Larson, E. D, Jin H. 1999. In: Overend, R., Chornet, E. (eds.) Proceedings of the 4th Biomass Conference of the Americas, Kidlington, UK, 29 August 1999, Elsevier, Amsterdam.
Lee, K.-W., Kim, S.-B., Jun, K.-W., Choi, M.-J. 2001. In: Williams, D.J., Durie, R.A., McMullan, P., Paulson, A.J., Smith, A.Y. (eds.) Proceedings of the 5th International Conference on Greenhouse Gas Control Technology, Cairns, Australia, 13 August 2000, CSIRO.
Li, S., Krishnamoorthy, S., Li, A., Meitzner, G.D., Iglesia, E. 2002. Promoted iron-based catalysts for the Fischer–Tropsch synthesis: design, synthesis, site densities, and catalytic properties. J Catal 206:202-217.
MacLean, H.L., Lave, L.B. 2003. Evaluating automobile fuel/propulsion system technologies. Energy Combust Sci 29:1-69.
Madras, G., Kolluru, C., Kumar, R. 2004. Synthesis of biodiesel in supercritical fluids. Fuel 83:2029-2033.
Maschio, G., Lucchesi, A., Stoppato, G. 1994. Production of syngas from biomass. Bioresour Technol 48:119-126.
Matsumura, Y., Minowa, T. 2004. Fundamental design of a continuous biomass gasification process using a supercritical water fluidized bed. Int J Hydrogen Energy 29:701-707.
May, M. 2003. Development and demonstration of Fischer–Tropsch fueled heavy-duty vehicles with control technologies for reduced diesel exhaust emissions. 9th Diesel Engine Emissions Reduction Conference. Newport, RI, 24-28 August 2003.
McKendry, P. 2002. Energy production from biomass (part 1): overview of biomass. Bioresour Technol 83:37-46.
Meher, L.C., Sagar, D.V., Naik, S.N. 2006. Technical aspects of biodiesel production by transesterification—a review. Renew Sustain Energy Rev 10:248-268.
Mirzaei, A.A., Habibpour, R., Faizi, M., Kashi, E. 2006. Characterization of iron-cobalt oxide catalysts: effect of different supports and promoters upon the structure and morphology of precursors and catalysts. Appl Catal A General 301:272-283.
Nath, K., Das, D. 2003. Hydrogen from biomass. Curr Sci 85:265-271.
Ouellette, N., Rogner, H.-H., Scott, D.S. 1997. Hydrogen-based industry from remote excess hydroelectrıcıty. Int J Hydrogm Energy 22:397-403.
Phillips, V.D., Kinoshita, C.M., Neill, D.R., Takashi, P.K. 1990. Thermochemical production of methanol from biomass in Hawaii. Appl Energy 35:167-175.
Prakash, C.B. 1998. A critical review of biodiesel as a transportatıon fuel in Canada. A Technical Report. GCSI - Global Change Strategies International, Canada.
Prins, M.J., Ptasinski, K.J., Janssen, F.J.J.G. 2004. Exergetic optimisation of a production process of Fischer–Tropsch fuels from biomass. Fuel Process Technol 86:375-389.
Puhan, S., Vedaraman, N., Rambrahaman, B.V., Nagarajan, G. 2005. Mahua (Madhuca indica) seed oil: a source of renewable energy in India. J Sci Ind Res 64:890-896.
Puppan, D. 2002. Environmental evaluation of biofuels. Periodica Polytechnica Ser Soc Man Sci 10:95-116.
Reijnders, L. 2006. Conditions for the sustainability of biomass based fuel use. Energy Policy 34:863-876.
Rao, V.U.S., Stiegel, G.J., Cinquergrane, G.J., Srivastava, R.D. 1992. Iron-based catalysts for slurry-phase Fischer-Tropsch process: Technology review. Fuel Process Technol 30: 83-107.
Rapagna, S., Jand, N., Foscolo, P.U. 1998. Catalytic gasification of biomass to produce hydrogen rich gas. Int J Hydrogen Energy 23:551-557.
Rowell, R.M., Hokanson, A.E. 1979. Methanol from wood: a critical assessment. In: K.V. Sarkanen,. A. Tillman (eds.) Progress in Biomass Conversion. Vol. 1. Academic, New York.
Santos, D.C.R.M., Lisboa, J.S., Passos, F.B., Noronha, F.B. 2004. Characterization of steam-reforming catalysts. Braz J Chem Eng 21:203-209.
Schulz, H. 1999. Short history and present trends of FT synthesis. Appl Catal A General 186: 1-16.
Sheehan, J., Cambreco, V., Duffield, J., Garboski, M., Shapouri, H. 1998. An overview of biodiesel and petroleum diesel life cycles. A report by US Department of Agriculture and Energy, Washington, D.C., pp. 1-35.
Sie, S. T., Krishna, R. 1999. Fundamentals and selection of advanced FT-reactors. Appl Catal General 186:55–70.
Sokhansanj, S., Turhollow, A., Cushman, J., Cundiff, J. 2002. Engineering aspects of collecting corn stover for bioenergy. Biomass Bioenergy 23:347-355.
Sorensen, H.A. 1983. Energy conversion systems. Wiley, New York.
Spath, P.L., Mann, M.K. 2000. Life Cycle Assessment of hydrogen production via natural gas steam reforming. National Renewable Energy Laboratory, Golden, CO, TP-570-27637, November 2000.
Spath, P.L., Dayton, D.C. 2003. Preliminary Screening — Technical and Economic Assessment of Synthesis Gas to Fuels and Chemicals with Emphasis on the Potential for Biomass-Derived Syngas. NREL/TP-510-34929.
Specht, M., Bandi, A., Baumgart, F., Murray, C.N., Gretz, J. (eds.) 1999. Proceedings of the 4th International Conference on Greenhouse Gas Control Technologies.
Stelmachowski, M., Nowicki, L. 2003. Fuel from the synthesis gas—the role of process engineering. Energy 74:85-93.
Taherzadeh, M.J. 1999. Ethanol from Lignocellulose: Physiological effects of inhibitors and fermentation strategies. PhD thesis, Department of Chemical Reaction Engineering, Chalmers University of Technology, Göteborg, Sweden.
Takezawa, N., Shimokawabe, M., Hiramatsu, H., Sugiura, H., Asakawa, T., Kobayashi, H. 1987. reforming of methanol over Cu/ZrO2. Role of ZrO2support. React Kinet Catal Lett 33:191-196.
Theander, O. 1985. In: Overand, R.P., Mile, T.A., Mudge, L.K. (eds.) Fundamentals of thermochemical biomass conversion. Elsevier, New York.
Tijmensen, M.J.A., Faaij, A.P.C., Hamelinck, C.N., van Hardeveld, R.M.R. 2002. Exploration of the possibilities for production of Fischer Tropsch liquids and power via biomass gasification. Biomass Bioenergy 23:129-152.
Tran, D.Q., Charanjit, R. 1978. A kinetic model for pyrolysis of Douglas fir bark.Fuel 57:293-298
UNDP (United Nations Development Programme). 2000. World Energy Assessment. Energy and the Challenge of Sustainability, New York.
Usta, N., Ozturk, E., Can, O., Conkur, E.S., Nas, S., Con, A.H., Can, A.C., Topcu, M. 2005. of biodiesel fuel produced from hazelnut soapstock/waste sunflower oil mixture in a diesel engine. Energy Convers Mgmt 46:741–755.
Vasudevan, P., Sharma, S., Kumar, A. 2005. Liquid fuel from biomass: an overview. J Sci Ind Res 64:822-831.
Vosloo, A.C. 2001. Fischer–Tropsch: a futuristic view. Fuel Process Technol 71:149-155.
Wang, D., Czernik, S., Chornet, E. 1998. Production of hydrogen from biomass by catalytic steam reforming of fast pyrolysis oils. Energy Fuels 12:19–24.
Wang, D., Czernik, S., Montane, D., Mann, M., Chornet, E. 1997. Biomass to hydrogen via fast pyrolysis and catalytic steam reforming of the pyrolysis oil or its fractions. Ind Eng Chem Res 36:1507-1518.
Wu, B.S., Bai, L., Xiang, H.W., Li, Y.W., Zhang, Z.X., Zhong, B. 2004. An active iron catalyst containing sulfur for Fischer–Tropsch synthesis. Fuel 83:205–512.
Yoshida, T., Oshima, Y., Matsumura, Y. 2004. Gasification of biomass model compounds and real biomass in supercritical water. Biomass Bioenergy 26:71-78.
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(2008). Biofuels. In: Biodiesel. Springer, London. https://doi.org/10.1007/978-1-84628-995-8_2
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