Abstract
Rising concerns over the use of fossil resources have generated renewed interest in the production of commodity chemicals via fermentation. Organic acids are a particularly attractive target because their functionality enables downstream catalytic upgrading to a variety of compounds. In this article, we survey how common technical issues are addressed in the recovery schemes for several organic acids. We present results for the recovery of acetate using a new method based on amine complexation. Our reactive separation scheme produces a high-purity product, is energy efficient, and avoids the coproduction of a waste salt coproduct, all prerequisites for a large-scale production process.
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Ardagh, E., Barbour, A., McClellan, G., and McBride, E. (1924), Ind. Eng. Chem. 16, 1133–1139.
Witzeman, J. and Agreda, V. (1993), in Acetic Acid and Its Derivatives, Agreda, V. and Zoeller, J., eds., Marcel Dekker, New York, pp. 257–284.
Colley, S. W., Fawcett, C. R., Sharif, M., Tuck, M. W. M., Watson, D. J., Wood, M. A. (2000), WO 00/20373.
Bradley, M. W., Harris, N., and Turner, K. (1982), WO 82/03854.
Winter, O. and Eng, M. (1976), Hydrocarbon Process. 55(11), 125–133.
Filachione, E. and Fisher, C. (1946), Ind. Eng. Chem. 38(2), 228–232.
Benninga, H. (1990), A History of Lactic Acid Making: A Chapter in the History of Biotechnology, Kluwer Academic, London.
Cockrem, M. and Johnson, P. (1993), US patent 5210296.
Tung, L. and King, C. (1994), Ind. Eng. Chem. Res. 33, 3217–3229.
Sarhaddar, S., Scheibl, A., Berghofer, E., and Cramer, A. (1997), US patent 5641406.
Filachione, E. and Costello, E. (1952), Ind. Eng. Chem. 44(9), 2189–2191.
Cockrem, M. (2000), WO 00/64850.
Miao, F. (1997), US patent 5681728.
Baniel, A., Eyal, A., Mizrahi, J., Hazan, B., Fisher, R., Kolstad, J., and Stewart, B. (1996), US patent 5510526.
Lopez-Garcia, R. (2002), in Kirk-Othmer Encyclopedia of Chemical Technology, Citric Acid, John Wiley, New York.
Verhoff, F (2002), in Ullmann’s Encyclopedia of Industrial Chemistry, Citric Acid, Wiley-VCH Verlag.
Noyes, R. (1969), Citric Acid Production Processes, Noyes Development, Park Ridge.
Baniel, A., Blumberg, R., and Hajdu, K. (1981), US patent 4275234.
Busche, R. (1983), Biotechnol. Bioeng. Symp. 13, 597–615.
Busche, R., Shimshick, E., and Yates, R. (1982), Biotechnol. Bioeng. Symp. 12, 249–262.
Partin, L. and Heise, W. (1993), in Acetic Acid and Its Derivatives, Agreda, V. and Zoeller, J., eds., Marcel Dekker, New York, pp. 3–13.
Urbas, B. (1983), US patent 4 405 717.
Ricker, N., Michaels, J. and King, C. (1979), J. Separ. Process. Technol. 1(1), 36–41.
Verser, D. and Eggeman, T. (2003), US patent 6509180
Drake, H. (1994), Acetogenesis., Chapman & Hall, New York.
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Eggeman, T., Verser, D. (2005). Recovery of Organic Acids from Fermentation Broths. In: Davison, B.H., Evans, B.R., Finkelstein, M., McMillan, J.D. (eds) Twenty-Sixth Symposium on Biotechnology for Fuels and Chemicals. ABAB Symposium. Humana Press. https://doi.org/10.1007/978-1-59259-991-2_52
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DOI: https://doi.org/10.1007/978-1-59259-991-2_52
Publisher Name: Humana Press
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