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Part of the book series: Food Engineering Series ((FSES))

Abstract

For more than 30 years, near infrared spectroscopy has been a widely used analytical method of the agricultural, food, pharmaceutical, and chemical industries because of its versatility in quantitative and qualitative analyses, rapidness, accuracy, and ease of use. During the same period, digital image analysis has evolved for use in online inspection of products from these same industries. It has only been in the past few years that the combination of these technologies, hyperspectral image (HSI) analysis, has developed to the point where it can be used outside of research laboratories. The imaging capability adds another layer of complexity to spectral analysis with rewards of pixel-level precision, yet the underlying principles of quantum mechanics, light scatter, vibrational spectroscopy, and statistical regression all continue have importance in understanding HSI behavior. This chapter serves as a brief primer on these principles and draws knowledge from well accepted texts on spectroscopy as well as showcasing applications derived from agricultural food quality and safety research.

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References

  • Barnes RJ, Dhanoa MS, Lister SJ (1989) Standard normal variate transformation and detrending of near infrared diffuse reflectance. Appl Spectrosc 43:772–777

    Article  CAS  Google Scholar 

  • Beer A (1852) Bestimmung der absorption des rothen Lichts in farbigen Flüssigkeiten (Determination of the absorption of red light in colored liquids). Annalen der Physik und Chemie 86:78–88

    Article  Google Scholar 

  • Bouguer P (1729) Essai d’Optique Sur la Gradation de la Lumiere (Test of optics on the gradation of light) Claude Jombert, Paris, 164pp

    Google Scholar 

  • Brown CD, Wentzell PD (1999) Hazards of digital smoothing filters as a preprocessing tool in multivariate calibration. J Chemometrics 13:133–152

    Article  CAS  Google Scholar 

  • Brown CD, Vega-Montoto L, Wentzell PD (2000) Derivative preprocessing and optimal corrections for baseline drift in multivariate calibration. Appl Spectrosc 54:1055–1068

    Article  CAS  Google Scholar 

  • Burger J, Geladi P (2005) Hyperspectral NIR image regression part I: calibration and correction. J Chemometrics 19:355–363

    Article  CAS  Google Scholar 

  • Cristianini N, Shawe-Taylor J (2000) An introduction to support vector machines and other kernel-based learning methods. Cambridge University Press, Cambridge, 189pp

    Book  Google Scholar 

  • Dahm DJ, Dahm KD (2007) Interpreting diffuse reflectance and transmittance: a theoretical introduction to absorption spectroscopy of scattering materials. NIR, Chichester, 286pp

    Google Scholar 

  • Delwiche SR, Norris KH, Pitt RE (1992) Temperature sensitivity of near-infrared scattering transmittance spectra of water-adsorbed starch and cellulose. Appl Spectrosc 46:782–789

    Article  CAS  Google Scholar 

  • Delwiche SR, Souza EJ, Kim MS (2012) Near-infrared hyperspectral imaging for milling quality of soft wheat. Trans ASABE, submitted

    Google Scholar 

  • Farrell TJ, Patterson MS, Wilson B (1992) A diffusion theory model of spatially resolved, steady-state diffuse reflectance for the noninvasive determination of tissue optical properties in vivo. Med Phys 19:879–888

    Article  CAS  Google Scholar 

  • Geladi P, McDougel D, Martens H (1985) Linearization and scatter-correction for near-infrared reflectance spectra of meat. Appl Spectrosc 39:491–500

    Article  Google Scholar 

  • Griffiths PR (1995) Practical consequences of math pre-treatment of near infrared reflectance data: log(1/R) vs F(R). J Near Infrared Spectrosc 3:60–62

    Article  CAS  Google Scholar 

  • Groenhuis RAJ, Ferwerda HA, Bosch JJT (1983) Scattering and absorption of turbid materials determined from reflection measurements. 1: theory. App Opt 22:2456–2462

    Article  CAS  Google Scholar 

  • Jolliffe IT (2002) Principal component analysis, 2nd edn. Springer, New York, 487pp

    Google Scholar 

  • Kortüm G (1969) Reflectance spectroscopy: principles, methods, applications. Springer, Berlin, 366pp

    Book  Google Scholar 

  • Kubelka P, Munk F (1931) Ein beitrag zur optik der farbanstriche. Zeitschrift fur Technische Physik 12:593–601

    Google Scholar 

  • Lambert JH (1760) Photometria sive de Mensura et gradibus Luminis, Colorum et Umbrae (Photometria or of the measure and degrees of light, colors, and shade) Augustae Vindelicorum Eberhardt Klett, Germany

    Google Scholar 

  • Lu R, Cen H, Huang M, Ariana DP (2010) Spectral absorption and scattering properties of normal and bruised apple tissue. Trans ASABE 53:263–269

    Article  Google Scholar 

  • Lu R, Ariana DP, Cen H (2011) Optical absorption and scattering properties of normal and defective pickling cucumbers for 700–1000 nm. Sens Instrum Food Qual 5:51–56

    Article  Google Scholar 

  • Mark H, Workman J Jr (2007) Chemometrics in spectroscopy. Academic, Amsterdam, 526pp+24 color plates

    Google Scholar 

  • Martens H, Næs T (1989) Multivariate calibration. Wiley, Chichester, 419pp

    Google Scholar 

  • Miller CE (2001) Chemical principles of near-infrared technology. In: Williams PC, Norris KH (eds) Near-infrared technology in the agricultural and food industries, 2nd edn. American Association of Cereal Chemists, St. Paul, pp 19–37

    Google Scholar 

  • Naes T, Isaksson T, Fearn T, Davies T (2002) A user-friendly guide to multivariate calibration and classification. NIR, Chichester, 344pp

    Google Scholar 

  • Olinger JM, Griffiths PR (1988) Quantitative effects of an absorbing matrix on near-infrared diffuse reflectance spectra. Anal Chem 60:2427–2435

    Article  CAS  Google Scholar 

  • Olinger JM, Griffiths PR, Burger T (2001) Theory of diffuse reflection in the NIR region. In: Burns DA, Ciurczak EW (eds) Handbook of near-infrared analysis, 2nd edn. Marcel Dekker, New York, pp 19–51

    Google Scholar 

  • Qin J, Lu R (2008) Measurement of the optical properties of fruits and vegetables using spatially resolved hyperspectral diffuse reflectance imaging technique. Postharvest Bio Technol 49:355–365

    Article  Google Scholar 

  • Savitzky A, Golay MJE (1964) Smoothing and differentiation of data by simplified least squares procedures. Anal Chem 36:1627–1639

    Article  CAS  Google Scholar 

  • Steinier J, Termonia Y, Deltour J (1972) Comments on smoothing and differentiation of data by simplified least squares procedure. Analytical Chem 44:1906–1909

    Article  CAS  Google Scholar 

  • Varmuza K, Filzmoser P (2009) Introduction to multivariate statistical analysis in chemometrics. CRC, Boca Raton, 321pp

    Book  Google Scholar 

  • Wilson EB Jr, Decius JC, Cross PC (1985) Molecular vibrations: the theory of infrared and Raman vibrational spectra (388pp.), originally published in 1955 by McGraw Hill and republished by Dover, New York

    Google Scholar 

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Correspondence to Stephen R. Delwiche .

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Delwiche, S.R. (2015). Basics of Spectroscopic Analysis. In: Park, B., Lu, R. (eds) Hyperspectral Imaging Technology in Food and Agriculture. Food Engineering Series. Springer, New York, NY. https://doi.org/10.1007/978-1-4939-2836-1_3

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