Abstract
Cooked egg white, frankfurters, yogurt, jellies, and gelatin desserts are traditional food products that are gels. All start as some liquid mixture of ingredients in water which solidify as a result of processing. Hard-boiled eggs are one of the simplest; by placing whole eggs in boiling water for 5 min, you cause the liquid suspension of proteins in the egg albumen to denature, aggregate, and form a gel network. Changing the cooking time allows some control of the texture of the product. Another interesting egg product is the “thousand-year-old egg.” Strong black tea, salt, lime, and wood ash are combined into a paste and buried in soil. After 100 days in a cool dark place, the egg white forms a translucent gel. Different processing conditions convert the same protein into gels with different properties. Other food ingredients form more complex gels, for example, in making cheddar cheese, the initial process involves forming the liquid milk into a soft-solid curd by starter cultures lowering the pH, and by the enzymatic action of chymosin. The gel is weak and fractures with minimal deformation.
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Notes
- 1.
In some cases, the knots and tangles formed in concentrated polymer solutions can lead to gel-like behavior (e.g., shower “gels”). However Clark and Ross-Murphy (2009) argue that these should be regarded as viscous, non-Newtonian fluids rather than gels, because they will flow, however, incredibly slowly. Other workers disagree (Raghavan and Douglas 2012), and in practice it may not be useful to make the distinction.
- 2.
A third elastic modulus, the bulk modulus, can be measured as the change in volume under uniform external pressure.
- 3.
The viscous modulus captures the response of a liquid in oscillatory shear but is not the same as the viscosity measured in steady shear. A dynamic viscosity can be calculated by dividing the viscous modulus by angular frequency.
- 4.
A search of videos on the Internet will reveal far more entertaining examples.
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© 2014 Springer Science+Business Media New York
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Coupland, J., Foegeding, E. (2014). Gels. In: An Introduction to the Physical Chemistry of Food. Food Science Text Series. Springer, New York, NY. https://doi.org/10.1007/978-1-4939-0761-8_9
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DOI: https://doi.org/10.1007/978-1-4939-0761-8_9
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