Skip to main content

Supported Metal Nanoparticles

  • Chapter
  • First Online:
  • 1424 Accesses

Part of the book series: Nanostructure Science and Technology ((NST,volume 170))

Abstract

The purpose of this chapter is to summarize the main synthetic techniques used to prepare supported metal nanoparticles for use in electrolytic cells (primarily fuel cells and electrolyzers). Each method provides a strategy which has the main goal of controlling particle size, alloy composition and catalyst distribution over the support material. As a consequence the reader is presented here with a general overview of the most common synthetic methods. Some of the more established procedures are now used industrially to produce large quantities of materials. This does not mean they are superior to the others, depending on the end application of the catalyst and the instrumentation available, one method may be advantageous over another. Therefore, the reader is advised to consider the intrinsic advantages and disadvantages of each method when selecting which to use. More recently methods have been developed to control structure on an atomic scale by the formation of surface defects such as twins or stacking faults that can lead to dramatic increases in activity. This will be covered in detail elsewhere.

This is a preview of subscription content, log in via an institution.

Buying options

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   129.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD   169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD   169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

References

  1. C. Bock, B. MacDougall, Y. LePage, J. Electrochem. Soc. 151, A1269–A1278 (2004)

    Google Scholar 

  2. N. Alonso-Vante, Fuel Cells 6, 182–189 (2006)

    Google Scholar 

  3. A.J. Dickinson, L.P.L. Carrette, J.A. Collins, K.A. Friedrich, U. Stimming, Electrochim. Acta 47, 3733–3739 (2002)

    Google Scholar 

  4. M. Haruta, S. Tsubota, T. Kobayashi, H. Kageyama, M.J. Genet, B. Delmon, J. Catal. 144, 175–192 (1993)

    Google Scholar 

  5. G.Y. Chen, D.A. Delafuente, S. Sarangapani, T.E. Mallouk, Catal. Today 67, 341–355 (2001)

    Google Scholar 

  6. O.V. Cherstiouk, P.A. Simonov, V.I. Zaikovskii, E.R. Savinova, J. Electroanal. Chem. 554, 241–251 (2003)

    Google Scholar 

  7. C. Baatz, N. Decker, U. Prusse, J. Catal. 258, 165–169 (2008)

    Google Scholar 

  8. H.S. Liu, C.J. Song, L. Zhang, J.J. Zhang, H.J. Wang, D.P. Wilkinson, J. Power Sources 155, 95–110 (2006)

    Google Scholar 

  9. N. Fujiwara, K. Yasuda, T. Ioroi, Z. Siroma, Y. Miyazaki, Electrochim. Acta 47, 4079–4084 (2002)

    Google Scholar 

  10. B. Yang, Q.Y. Lu, Y. Wang, L. Zhuang, J.T. Lu, P.F. Liu, Chem. Mater. 15, 3552–3557 (2003)

    Google Scholar 

  11. E.V. Spinace, A.O. Neto, M. Linardi, J. Power Sources 124, 426–431 (2003)

    Google Scholar 

  12. J. Tayal, B. Rawat, S. Basu, Int. J. Hydrogen Energ. 37, 4597–4605 (2012)

    Google Scholar 

  13. M. Watanabe, M. Uchida, S. Motoo, J. Electroanal. Chem. Interfacial Electrochem. 229, 395–406 (1987)

    Google Scholar 

  14. T. Yoshitake, Y. Shimakawa, S. Kuroshima, H. Kimura, T. Ichihashi, Y. Kubo, D. Kasuya, K. Takahashi, F. Kokai, M. Yudasaka, S. Iijima, Phys. B 323, 124–126 (2002)

    Google Scholar 

  15. M.P. Pileni, Adv. Colloid Interfac. 46, 139–163 (1993)

    Google Scholar 

  16. L. Xiong, A. Manthiram, Solid State Ionics 176, 385–392 (2005)

    Google Scholar 

  17. D.R.M. Godoi, J. Perez, H.M. Villullas, J. Electrochem. Soc. 154, B474–B479 (2007)

    Google Scholar 

  18. S. Eriksson, U. Nylen, S. Rojas, M. Boutonnet, Appl. Catal. a-Gen. 265, 207–219 (2004)

    Google Scholar 

  19. V. Uskokovic, M. Drofenik, Adv. Colloid Interfac. 133, 23–34 (2007)

    Google Scholar 

  20. I. Lisiecki, M.P. Pileni, J. Am. Chem. Soc. 115, 3887–3896 (1993)

    Google Scholar 

  21. J.S.F. Wang, H.B. Pan, C.M. Wai, J. Nanosci. Nanotechnol. 6, 2025–2030 (2006)

    Google Scholar 

  22. M.J. Escudero, E. Hontanon, S. Schwartz, M. Boutonnet, L. Daza, J. Power Sources 106, 206–214 (2002)

    Google Scholar 

  23. C.Z. Yang, N.K. van der Laak, K.Y. Chan, X. Zhang, Electrochim. Acta 75, 262–272 (2012)

    Google Scholar 

  24. J. Ahmed, K.V. Ramanujachary, S.E. Lofland, A. Furiato, G. Gupta, S.M. Shivaprasad, A.K. Ganguli, Colloid Surf. A 331, 206–212 (2008)

    Google Scholar 

  25. I. Capek, Adv. Colloid Interfac. 110, 49–74 (2004)

    Google Scholar 

  26. C. Stubenrauch, T. Wielpuetz, T. Sottmann, C. Roychowdhury, F.J. DiSalvo, Colloid Surf. A 317, 328–338 (2008)

    Google Scholar 

  27. A.K. Ganguli, A. Ganguly, S. Vaidya, Chem. Soc. Rev. 39, 474–485 (2010)

    Google Scholar 

  28. J. Ahmed, S. Sharma, K.V. Ramanujachary, S.E. Lofland, A.K. Ganguli, J. Colloid Interf. Sci. 336, 814–819 (2009)

    Google Scholar 

  29. D.H. Chen, C.J. Chen, J. Mater. Chem. 12, 1557–1562 (2002)

    Google Scholar 

  30. M.L. Wu, D.H. Chen, T.C. Huang, J. Colloid Interf. Sci. 243, 102–108 (2001)

    Google Scholar 

  31. M.L. Wu, D.H. Chen, T.C. Huang, Langmuir 17, 3877–3883 (2001)

    Google Scholar 

  32. M.L. Wu, D.H. Chen, T.C. Huang, Chem. Mater. 13, 599–606 (2001)

    Google Scholar 

  33. P.Y. He, X.Y. Wang, Y.J. Liu, L.H. Yi, X. Liu, Int. J. Hydrog. Energ. 37, 1254–1262 (2012)

    Google Scholar 

  34. P.Y. He, X.Y. Wang, Y.J. Liu, X. Liu, L.H. Yi, Int. J. Hydrog. Energ. 37, 11984–11993 (2012)

    Google Scholar 

  35. L.H. Yi, Y.F. Song, X. Liu, X.Y. Wang, G.S. Zou, P.Y. He, W. Yi, Int. J. Hydrog. Energ. 36, 15775–15782 (2011)

    Google Scholar 

  36. J. Ahmed, A. Ganguly, S. Saha, G. Gupta, P. Trinh, A.M. Mugweru, S.E. Lofland, K.V. Ramanujachary, A.K. Ganguli, J. Phys. Chem. C 115, 14526–14533 (2011)

    Google Scholar 

  37. J. Ahmed, B. Kumar, A.M. Mugweru, P. Trinh, K.V. Ramanujachary, S.E. Lofland, Govind, A.K. Ganguli, J. Phys. Chem. C 114, 18779–18784 (2010)

    Google Scholar 

  38. J. Ahmed, T. Ahmad, K.V. Ramanujachary, S.E. Lofland, A.K. Ganguli, J. Colloid Interf. Sci. 321, 434–441 (2008)

    Google Scholar 

  39. C. Bock, C. Paquet, M. Couillard, G.A. Botton, B.R. MacDougall, J. Am. Chem. Soc. 126, 8028–8037 (2004)

    Google Scholar 

  40. H.S. Oh, J.G. Oh, Y.G. Hong, H.S. Kim, Electrochim. Acta 52, 7278–7285 (2007)

    Google Scholar 

  41. E. Ribadeneira, B.A. Hoyos, J. Power Sources 180, 238–242 (2008)

    Google Scholar 

  42. W.Y. Yu, W.X. Tu, H.F. Liu, Langmuir 15, 6–9 (1999)

    Google Scholar 

  43. G. Glaspell, H.M.A. Hassan, A. Elzatahry, V. Abdalsayed, M.S. El-Shall, Top. Catal. 47, 22–31 (2008)

    Google Scholar 

  44. G. Glaspell, L. Fuoco, M.S. El-Shall, J. Phys. Chem. B 109, 17350–17355 (2005)

    Google Scholar 

  45. J.M. Campelo, T.D. Conesa, M.J. Gracia, M.J. Jurado, R. Luque, J.M. Marinas, A.A. Romero, Green Chem. 10, 853–858 (2008)

    Google Scholar 

  46. Z.L. Liu, L.M. Gan, L. Hong, W.X. Chen, J.Y. Lee, J. Power Sources 139, 73–78 (2005)

    Google Scholar 

  47. Z.L. Liu, X.Y. Ling, X.D. Su, J.Y. Lee, L.M. Gan, J. Power Sources 149, 1–7 (2005)

    Google Scholar 

  48. S. Stevanovic, D. Tripkovic, J. Rogan, K. Popovic, J. Lovic, A. Tripkovic, V.M. Jovanovic, J. Solid State Electr. 16, 3147–3157 (2012)

    Google Scholar 

  49. C.T. Hsieh, W.M. Hung, W.Y. Chen, J.Y. Lin, Int. J. Hydrogen Energ. 36, 2765–2772 (2011)

    Google Scholar 

  50. D.M. Gu, Y.Y. Chu, Z.B. Wang, Z.Z. Jiang, G. Yin, Y. Liu, Appl. Catal. B-Environ. 102, 9–18 (2011)

    Google Scholar 

  51. C.T. Hsieh, W.Y. Chen, I.L. Chen, A.K. Roy, J. Power Sources 199, 94–102 (2012)

    Google Scholar 

  52. C.T. Hsieh, Y.Y. Liu, W.Y. Chen, Y.H. Hsieh, Int. J. Hydrogen Energ. 36, 15766–15774 (2011)

    Google Scholar 

  53. Y.Y. Chu, Z.B. Wang, Z.Z. Jiang, D.M. Gu, G.P. Yin, J. Power Sources 203, 17–25 (2012)

    Google Scholar 

  54. Y.Y. Huang, S.Y. Zheng, X.J. Lin, L.Q. Su, Y.L. Guo, Electrochim. Acta 63, 346–353 (2012)

    Google Scholar 

  55. C.T. Hsieh, Y.Y. Liu, Y.S. Cheng, W.Y. Chen, Electrochim. Acta 56, 6336–6344 (2011)

    Google Scholar 

  56. E. Lebegue, S. Baranton, C. Coutanceau, J. Power Sources 196, 920–927 (2011)

    Google Scholar 

  57. S. Harish, S. Baranton, C. Coutanceau, J. Joseph, J. Power Sources 214, 33–39 (2012)

    Google Scholar 

  58. S. K, W. D, K. T, J. Electroanal. Chem. 223, 223–224 (1987)

    Google Scholar 

  59. J.V. Zoval, J. Lee, S. Gorer, R.M. Penner, J. Phys. Chem. B 102, 1166–1175 (1998)

    Google Scholar 

  60. G.J. Lu, G. Zangari, J. Phys. Chem. B 109, 7998–8007 (2005)

    Google Scholar 

  61. O. Antoine, R. Durand, Electrochem. Solid State 4, A55–A58 (2001)

    Google Scholar 

  62. Z.B. He, J.H. Chen, D.Y. Liu, H. Tang, W. Deng, W.F. Kuang, Mater. Chem. Phys. 85, 396–401 (2004)

    Google Scholar 

  63. G. N, J. D, K. P, J. Electroanal. Chem. Interf. Electrochem. 264, 235–245 (1989)

    Google Scholar 

  64. E. Budevski, G. Staikov, W.J. Lorenz, Electrochemical Phase Formation and Growth: An Introduction to the Initial Stages of Metal Deposition (VCH, Weinheim, New York, 1996)

    Google Scholar 

  65. R. Greef, R. Peat, L. Peter, D. Pletcher, J. Robinson, Electrocrystallisation (Ellis Horook Limited, New York, 1985)

    Google Scholar 

  66. E.J. Taylor, E.B. Anderson, N.R.K. Vilambi, J. Electrochem. Soc. 139, L45–L46 (1992)

    Google Scholar 

  67. K. Lee, A. Ishihara, S. Mitsushima, N. Kamiya, K. Ota, J. Electrochem. Soc. 151, A639–A645 (2004)

    Google Scholar 

  68. H. Hoster, T. Iwasita, H. Baumgartner, W. Vielstich, Phys. Chem. Chem. Phys. 3, 337–346 (2001)

    Google Scholar 

  69. F. Maillard, G.Q. Lu, A. Wieckowski, U. Stimming, J. Phys. Chem. B 109, 16230–16243 (2005)

    Google Scholar 

  70. C.T. Hsieh, J.M. Wei, J.S. Lin, W.Y. Chen, Catal. Commun. 16, 220–224 (2011)

    Google Scholar 

  71. S. Woo, I. Kim, J.K. Lee, S. Bong, J. Lee, H. Kim, Electrochim. Acta 56, 3036–3041 (2011)

    Google Scholar 

  72. Y. Ra, J. Lee, I. Kim, S. Bong, H. Kima, J. Power Sources 187, 363–370 (2009)

    Google Scholar 

  73. Y.H. Zhang, Y.N. Yang, P. Xiao, X.N. Zhang, L. Lu, L. Li, Mater. Lett. 63, 2429–2431 (2009)

    Google Scholar 

  74. H. Kim, S.H. Moon, Carbon 49, 1491–1501 (2011)

    Google Scholar 

  75. J.S. King, A. Wittstock, J. Biener, S.O. Kucheyev, Y.M. Wang, T.F. Baumann, S.K. Giri, A.V. Hamza, M. Baeumer, S.F. Bent, Nano Lett. 8, 2405–2409 (2008)

    Google Scholar 

  76. J.H. Shim, X. Jiang, S.F. Bent, F.B. Prinz, J. Electrochem. Soc. 157, B793–B797 (2010)

    Google Scholar 

  77. Y.C. Hsueh, C.C. Wang, C. Liu, C.C. Kei, T.P. Perng, Nanotechnology 23 (2012)

    Google Scholar 

  78. Y.C. Hsueh, C.C. Wang, C.C. Kei, Y.H. Lin, C. Liu, T.P. Perng, J. Catal. 294, 63–68 (2012)

    Google Scholar 

  79. T. Shu, S.J. Liao, C.T. Hsieh, A.K. Roy, Y.Y. Liu, D.Y. Tzou, W.Y. Chen, Electrochim. Acta 75, 101–107 (2012)

    Google Scholar 

  80. S.F. Huang, Y. Chi, C.S. Liu, A.J. Carty, K. Mast, C. Bock, B. MacDougall, S.M. Peng, G.H. Lee, Chem. Vapor Depos. 9, 157–161 (2003)

    Google Scholar 

  81. P. Sivakumar, R. Ishak, V. Tricoli, Electrochim. Acta 50, 3312–3319 (2005)

    Google Scholar 

  82. H.T. Kim, H.I. Joh, S.H. Moon, J. Power Sources 195, 1352–1358 (2010)

    Google Scholar 

  83. S.J. Seo, H.I. Joh, H.T. Kim, S.H. Moon, J. Power Sources 163, 403–408 (2006)

    Google Scholar 

  84. S.J. Seo, H.I. Joh, H.T. Kim, S.H. Moon, Electrochim. Acta 52, 1676–1682 (2006)

    Google Scholar 

  85. J.S. Yoo, H.T. Kim, H.I. Joh, H. Kim, S.H. Moon, Int. J. Hydrogen Energ. 36, 1930–1938 (2011)

    Google Scholar 

  86. S. Mukerjee, S. Srinivasan, A.J. Appleby, Electrochim. Acta 38, 1661–1669 (1993)

    Google Scholar 

  87. S. Hirano, J. Kim, S. Srinivasan, Electrochim. Acta 42, 1587–1593 (1997)

    Google Scholar 

  88. C.C. Chen, C.F. Chen, C.H. Hsu, I.H. Li, Diam. Relat. Mater. 14, 770–773 (2005)

    Google Scholar 

  89. C.L. Sun, L.C. Chen, M.C. Su, L.S. Hong, O. Chyan, C.Y. Hsu, K.H. Chen, T.F. Chang, L. Chang, Chem. Mater. 17, 3749–3753 (2005)

    Google Scholar 

  90. P. Sakkas, O. Schneider, S. Martens, P. Thanou, G. Sourkouni, C. Argirusis, J. Appl. Electrochem. 42, 763–777 (2012)

    Google Scholar 

  91. B.G. Pollet, Int. J. Hydrogen Energ. 35(2010), 11986–12004 (2004)

    Google Scholar 

  92. R.A. Caruso, M. Ashokkumar, F. Grieser, Colloid Surf. A 169, 219–225 (2000)

    Google Scholar 

  93. D. Radziuk, H. Mohwald, D. Shchukin, J. Phys. Chem. C 112, 19257–19262 (2008)

    Google Scholar 

  94. X.G. Wang, J.H. Liao, C.P. Liu, W. Xing, T.H. Lu, Electrochem. Commun. 11, 198–201 (2009)

    Google Scholar 

  95. J. Kim, J.E. Park, T. Momma, T. Osaka, Electrochim. Acta 54, 3412–3418 (2009)

    Google Scholar 

  96. M. Nakanishi, H. Takatani, Y. Kobayashi, F. Hori, R. Taniguchi, A. Iwase, R. Oshima, Appl. Surf. Sci. 241, 209–212 (2005)

    Google Scholar 

  97. Y. Mizukoshi, T. Fujimoto, Y. Nagata, R. Oshima, Y. Maeda, J. Phys. Chem. B 104, 6028–6032 (2000)

    Google Scholar 

  98. Z.C. Wang, D.D. Zhao, G.Y. Zhao, H.L. Li, J. Solid State Electr. 13, 371–376 (2009)

    Google Scholar 

  99. S. Shanmugam, A. Gedanken, J. Phys. Chem. C 113, 18707–18712 (2009)

    Google Scholar 

  100. X.Z. Xue, C.P. Liu, W. Xing, T.H. Lu, J. Electrochem. Soc. 153, E79–E84 (2006)

    Google Scholar 

  101. P.S. Patil, Mater. Chem. Phys. 59, 185–198 (1999)

    MathSciNet  Google Scholar 

  102. R. Mueller, L. Madler, S.E. Pratsinis, Chem. Eng. Sci. 58, 1969–1976 (2003)

    Google Scholar 

  103. Y. Zhang, C. Erkey, J Supercrit Fluid 38, 252–267 (2006)

    Google Scholar 

  104. A. Bayrakceken, U. Kitkamthorn, M. Aindow, C. Erkey, Scripta Mater. 56, 101–103 (2007)

    Google Scholar 

  105. Y. Zhang, D.F. Kang, C. Saquing, M. Aindow, C. Erkey, Ind. Eng. Chem. Res. 44, 4161–4164 (2005)

    Google Scholar 

  106. C.D. Saquing, T.T. Cheng, M. Aindow, C. Erkey, J. Phys. Chem. B 108, 7716–7722 (2004)

    Google Scholar 

  107. A. Bayrakceken, A. Smirnova, U. Kitkamthorn, M. Aindow, L. Turker, I. Eroglu, C. Erkey, J. Power Sources 179, 532–540 (2008)

    Google Scholar 

  108. L. Lü, M.O. Lai, Mechanical alloying (Kluwer Academic Publishers, Boston, 1998)

    Google Scholar 

  109. C. Suryanarayana, Prog. Mater Sci. 46, 1–184 (2001)

    Google Scholar 

  110. M.C. Denis, G. Lalande, D. Guay, J.P. Dodelet, R. Schulz, J. Appl. Electrochem. 29, 951–960 (1999)

    Google Scholar 

  111. G. Lalande, M.C. Denis, D. Guay, J.P. Dodelet, R. Schulz, J. Alloy. Compd. 292, 301–310 (1999)

    Google Scholar 

  112. M.C. Denis, P. Gouerec, D. Guay, J.P. Dodelet, G. Lalande, R. Schulz, J. Appl. Electrochem. 30, 1243–1253 (2000)

    Google Scholar 

  113. M.C. Denis, M. Lefevre, D. Guay, J.P. Dodelet, Electrochim. Acta 53, 5142–5154 (2008)

    Google Scholar 

  114. Z. Farhat, A. Alfantazi, Mat. Sci. Eng. A-Struct. 476, 169–173 (2008)

    Google Scholar 

  115. P. Pharkya, A. Alfantazi, Z. Farhat, J. Fuel Cell Sci. Tech. 2, 171–178 (2005)

    Google Scholar 

  116. M. Lucariello, N. Penazzi, E. Arca, G. Mulas, S. Enzo, Mater. Chem. Phys. 114, 227–234 (2009)

    Google Scholar 

  117. B. Liu, L.P. Zheng, S.J. Liao, J.H. Zeng, J. Power Sources 210, 54–59 (2012)

    Google Scholar 

  118. B. Millington, S.F. Du, B.G. Pollet, J. Power Sources 196, 9013–9017 (2011)

    Google Scholar 

  119. Z.Q. Jiang, Z.J. Jiang, Y.D. Meng, Appl. Surf. Sci. 257, 2923–2928 (2011)

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Alessandro Lavacchi .

Rights and permissions

Reprints and permissions

Copyright information

© 2013 Springer Science+Business Media New York

About this chapter

Cite this chapter

Lavacchi, A., Miller, H., Vizza, F. (2013). Supported Metal Nanoparticles. In: Nanotechnology in Electrocatalysis for Energy. Nanostructure Science and Technology, vol 170. Springer, New York, NY. https://doi.org/10.1007/978-1-4899-8059-5_7

Download citation

  • DOI: https://doi.org/10.1007/978-1-4899-8059-5_7

  • Published:

  • Publisher Name: Springer, New York, NY

  • Print ISBN: 978-1-4899-8058-8

  • Online ISBN: 978-1-4899-8059-5

  • eBook Packages: EnergyEnergy (R0)

Publish with us

Policies and ethics