Abstract
Cobalt(III) complexes of the type [Co(en)2X2]+ have long been known, and extensively investigated with regard to mechanisms of reactions in these systems.1 Some years ago it was decided to extend these studies to include analogous compounds of the other members of this triad, rhodium(III) and iridium(III). It was then learned that very few such compounds had been prepared and it was necessary to start the laborious task of the syntheses and characterizations of these desired complexes. Several salts of [Rh(en)2X2] + were prepared2 and the rates of substitution of some of these have been investigated.3
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
F. Basolo and R. G. Pearson, Mechanisms of Inorganic Reactions, John Wiley and Sons, New York, 2nd edition, 1967.
S. A. Johnson and F. Basolo, Inorg. Chem. 1: 925 (1962).
S. A. Johnson, F. Basolo and R. G. Pearson, J. Am. Chem. Soc. 85: 1741 (1963);
A. J. Poe, K. Shaw, and M. J. Wendt, Inorg. Chim. Acta 1: 371 (1967), and references therein.
A. Werner and A. P. Smirnoff, Helv. Chim. Acta 3: 472 (1920).
S. Kida, Bull. Chem. Soc. Japan 39: 2415 (1966).
M. Delepine, Ann. Chim. (France) 19:174 (1923);
M. Delepine, Compt. Rend. 236: 559 (1953).
M. Delepine and F. Lareze, ibid, 256: 3912 (1963).
J. V. Rund, F. Basolo and R. G. Pearson, Inorg. Chem. 3: 658 (1964);
J. V. Rund, ibid. 7: 24 (1968).
R. D. Gillard, J. A. Osborn, and G. Wilkinson, J. Chem. Soc. 4107 (1965); D. J. Baker and R. D. Gillard, Chem. Comm. 520 (1967).
R. A. Bauer and F. Basolo, Chem. Comm. 458 (1968).
R. A. Bauer and F. Basolo, J. Am. Chem. Soc. 90: 2437 (1968).
A. W. Adamson, J. Phys. Chem. 71: 798 (1967).
G. Gire, Ann. Chim. 9 (11): 278 (1938).
M. E. Baldwin, J. Chem. Soc. 4369 (1960).
W. A. Milien and D. W. Watts, J. Am. Chem. Soc. 89: 6858 (1967).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1969 Springer Science+Business Media New York
About this chapter
Cite this chapter
Bauer, R.A., Basolo, F. (1969). Syntheses and Reactions of Some Diacidobis(Ethylenediamine)-Iridium(III) Complexes. In: Kirschner, S. (eds) Coordination Chemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-6555-4_10
Download citation
DOI: https://doi.org/10.1007/978-1-4899-6555-4_10
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4899-6256-0
Online ISBN: 978-1-4899-6555-4
eBook Packages: Springer Book Archive