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Role of the Geometrical Structure of Adsorbents

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Gas-Adsorption Chromatography

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Abstract

The choise of gross geometrical structure (specific surface and porosity) for a given surface composition is governed by the mixture to be separated. The lifetimes in the adsorbed state are small for gases and light hydrocarbons at ordinary temperatures, so the adsorbent must have a reasonably large specific surface. On the other hand, ordinary (or slightly elevated) temperatures are sufficient to prevent substantial peak broadening from surface inhomogeneity and pore exchange for gases (including light hydrocarbons) on amorphous adsorbents of high specific surface. Zeolites,* microporous silica gels, microporous glasses, and capillary glass columns with porous surfaces are used. For example, hydrogen isotopes and isomers have been separated on zeolites in a capillary column [1] and on glass capillary columns with a porous layer on the walls [2].

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Authors and Affiliations

  1. Department of Chemistry, Moscow University, Russia

    Andrei V. Kiselev

  2. Institute of Physical Chemistry, Academy of Sciences of the USSR, Russia

    Yakov I. Yashin

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  1. Andrei V. Kiselev
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  2. Yakov I. Yashin
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Kiselev, A.V., Yashin, Y.I. (1969). Role of the Geometrical Structure of Adsorbents. In: Gas-Adsorption Chromatography. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-6503-5_3

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  • DOI: https://doi.org/10.1007/978-1-4899-6503-5_3

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