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Introduction. Advantages and Disadvantages of Gas-Adsorption Chromatography and Gas—Liquid Chromatography

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Gas-Adsorption Chromatography

Abstract

Tsvet [2] founded a chromatography in adsorption form in 1903. Some topics closely related to frontal gas-adsorption chromatography were considered without relation to gas chromatography in connection with the performance of gasmasks [3] (see also [4, 5]), but gas-chromatographic analysis of mixtures began to develop rapidly only from 1952, when James and Martin [6] described the development form of gas-liquid partition chromatography. This has since been the main method used in analysis. Gas-liquid partition has advantages over gas adsorption in that a wide range of fixed liquids can be used and also that a liquid is homogeneous, so the solubility isotherms are virtually linear over a wide range in concentration starting with the very lowest. The range of commercially available adsorbents is very small; moreover, these adsorbents are geometrically and chemically inhomogeneous.

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Authors and Affiliations

  1. Department of Chemistry, Moscow University, Russia

    Andrei V. Kiselev

  2. Institute of Physical Chemistry, Academy of Sciences of the USSR, Russia

    Yakov I. Yashin

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  1. Andrei V. Kiselev
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Kiselev, A.V., Yashin, Y.I. (1969). Introduction. Advantages and Disadvantages of Gas-Adsorption Chromatography and Gas—Liquid Chromatography. In: Gas-Adsorption Chromatography. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-6503-5_1

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