Abstract
The behavior of dissociating oxides at high temperatures is briefly reviewed. At low pressures the composition of the oxide will correspond to an equilibrium oxygen pressure quite different from the ambient oxygen pressure. Evaporation rate studies on cuprous oxide in various atmospheres show that this oxide dissociates according to Cu2O (solid) → 2Cu (gas) + 1/2O2 (gas).
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References
C. L. Hoenig and A. W. Searcy, Am. Ceram. Soc. 49: 128 (1966).
C. L. Hoenig, Ph.D. Thesis, University of California, UCRL-7521 (1964).
R. T. Grimley, R. P. Burns, and M. G. Inghram, J. Chem. Phys. 34: 664 (1961).
R. H. Campbell, M. S. Thesis, Arizona State University, 1966.
M. Knudsen, Ann. Phys. 47: 697 (1915).
R. P. Burns, J. Chem. Phys. 44: 3307 (1966).
G. N. Lewis and M. Randall, Thermodynamics (ref. ed., K. S. Pitzer and L. Brewer) McGraw-Hill, New York 1961, Chapter 33.
M. H. Zirin and D. Trivich, J. Chem. Phys. 39: 870 (1963).
M. O’Keeffe and W. J. Moore, J. Chem. Phys. 36: 3009 (1962).
U. S. Bureau of Mines, Bulletins 584 (1960), 592 (1961), and 605 (1963).
J. P. Hirth and G. M. Pound, J. Chem. Phys. 26: 1216 (1957).
Additional Reference
R. P. Burns, J. Chem. Phys. 44: 3307 (1966).
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© 1969 Springer Science+Business Media New York
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Campbell, R.H., O’Keeffe, M. (1969). Vaporization of Cuprous Oxide and Other Dissociating Oxides. In: Gray, T.J., Fréchette, V.D. (eds) Kinetics of Reactions in Ionic Systems. Materials Science Research. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-6461-8_24
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DOI: https://doi.org/10.1007/978-1-4899-6461-8_24
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