Abstract
It is well known that α, β disubstituted olefins cannot usually be polymerized to high polymers, especially by free-radical-type polymerization. The difficulty of polymerization has been attributed to the steric repulsion induced by the β substituted group in the transition state of the propagating reaction1.
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Mizote, A., Higashimura, T., Okamura, S. (1968). Cationic Polymerization of α, β-Disubstituted Olefins. In: La Chimie Macromoléculaire—4 / Macromolecular Chemistry—4. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-6407-6_13
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DOI: https://doi.org/10.1007/978-1-4899-6407-6_13
Publisher Name: Springer, Boston, MA
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