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The Role of Phase Boundaries During Reaction Between Single Crystals of Various Oxides

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Book cover The Role of Grain Boundaries and Surfaces in Ceramics

Part of the book series: Materials Science Research ((MSR))

Abstract

Phase-boundary reactions between single crystals of different binary oxides (e.g., NiO + Al2O3 → NiAl2C4) are described. The reaction product can be monocrystalline or polycrystalline depending upon crystal structure of reactants and reaction product and on experimental conditions. The reaction product may be a single crystal even if the crystal structures of the reactants differ from that of the reaction product. Examples are given. Epitaxy, structural relationships, and the atomic mechanism of the phase-boundary reaction are discussed. It is concluded that under certain conditions dislocations may play a decisive role for the phase-boundary reaction. The kinetics involving phase-boundary reactions is discussed.

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Author information

Authors and Affiliations

  1. Max Planck Institut für Physikalische Chemie, Göttingen, Germany

    H. G. Sockel & H. Schmalzried

Authors
  1. H. G. Sockel
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  2. H. Schmalzried
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Editor information

Editors and Affiliations

  1. Department of Mineral Industries, North Carolina State University, USA

    W. Wurth Kriegel

  2. Department of Engineering Research, North Carolina State University, USA

    Hayne Palmour III

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© 1966 Springer Science+Business Media New York

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Sockel, H.G., Schmalzried, H. (1966). The Role of Phase Boundaries During Reaction Between Single Crystals of Various Oxides. In: Kriegel, W.W., Palmour, H. (eds) The Role of Grain Boundaries and Surfaces in Ceramics. Materials Science Research. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-6311-6_5

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  • DOI: https://doi.org/10.1007/978-1-4899-6311-6_5

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4899-6162-4

  • Online ISBN: 978-1-4899-6311-6

  • eBook Packages: Springer Book Archive

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