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Application of Modified Electrodes for Analysis in Flowing Solutions

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Contemporary Electroanalytical Chemistry

Abstract

Analysis in flowing solutions, as performed in particular with high performance liquid chromatography (HPLC) and flow injection analysis, (FIA) has developed rapidly over the last decade and now plays an important function in most analytical laboratories throughout the world. There is little doubt, however, that even HPLC lacks the resolving power required to solve analytical problems in complex matrices with minimal sample preparation. Often, the resolving power of the detection method is called upon to assist in the solution of these problems. This is particularly true with electrochemical detection (ED) systems which offer a certain degree of selectivity based on differences in oxidation or reduction potentials of the species to be determined.1 In recent years, the advent of chemically modified electrodes (CMEs) has provided a stimulus to further improve both the sensitivity and selectivity of ED systems used in HPLC and FIA.

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References

  1. P.T. Kissinger and W.R. Heineman, in: “Laboratory Techniques in Electroanalytical Chemistry”, Marcel Dekker, New York, 1984.

    Google Scholar 

  2. G.G. Wallace, in: “Chemical Sensors”, T.E. Edmonds (Ed.), Blackie and Son, Glasgow, 1988.

    Google Scholar 

  3. R.P. Baldwin, J.K. Christensen and L. Kryger, Anal. Chem., 58 (1986) 1790.

    Article  CAS  Google Scholar 

  4. G.G. Wallace and L. Yuping, J. Electroanal. Chem., in press.

    Google Scholar 

  5. S.M. Geraty, D.W.M. Arrigan and J.G. Vos, in: “Electrochemistry, Sensors and Analysis”, M.R. Smyth and J.G. Vos (Eds), Anal. Chem. Symposia Series, 25 Elsevier, Amsterdam, 1986, p. 303.

    Google Scholar 

  6. G. Batley, T.M. Florence and B. Hoyer, Anal. Chem., 59 (1987) 1608.

    Article  Google Scholar 

  7. M.R. Gregg, Chromatographia, 20 (1985) 129.

    Article  CAS  Google Scholar 

  8. M.R. Gregg, Chromatographia, 21 (1986) 705.

    Article  CAS  Google Scholar 

  9. T. Iwamoto, M. Yoshiura and K. Iriyama, Bunseki Kagaku, 36 (1987) 98.

    Article  CAS  Google Scholar 

  10. J. Wang and T. Peng, Anal. Chem., 58 (1986) 1787.

    Article  CAS  Google Scholar 

  11. J.C. Hoogvliet, C.M.B. van der Beld, C.J. van der Poel and W.P. van Bennekom, J. Electroanal. Chem., 201 (1986) 11.

    Article  CAS  Google Scholar 

  12. M.L. Hitchman and F.W.M. Nyasulu, J. Chem. Soc., Faraday Trans. I, 82 (1986) 1223.

    Article  Google Scholar 

  13. R.L. St. Claire (III) and J.W. Jorgensen, J. Chromat. Sci., 23 (1985) 186.

    Article  Google Scholar 

  14. L. Campanella, M. Tomasetti, B. Rappuoli and M.R. Bruni, Int. Clin. Prod. Rev., 4 (1985) 46.

    Google Scholar 

  15. G.J. Moody, G.S. Sanghera and J.D.R. Thomas, Analyst, 111 (1986) 665.

    Article  Google Scholar 

  16. J.A. Osborn, A.M. Yacynych and D.C. Roberts, Anal. Chim. Acta, 183 (1986) 287.

    Article  CAS  Google Scholar 

  17. M.K. Halbert and R.P. Baldwin, Anal. Chim. Acta, 187 (1986) 89.

    Article  CAS  Google Scholar 

  18. L.M. Santos and R.P. Baldwin, J. Chromat., Biomed. Applic., 58 (1987) 161.

    Article  Google Scholar 

  19. G. Marko-Varga, R. Appelqvist and L. Gorton, Anal. Chim. Acta, 179 (1986) 371.

    Article  CAS  Google Scholar 

  20. P.J. Kulesza, K. Bratjer and E. Dabek-Zlotorzynska, Anal. Chem., 59 (1987) 2776.

    Article  CAS  Google Scholar 

  21. J. Wang and L.D. Hutchins, Anal. Chem., 57 (1985) 1536.

    Article  CAS  Google Scholar 

  22. J.A. Cox and K.R. Kulkarni, Analyst, 111 (1986) 1219.

    Article  CAS  Google Scholar 

  23. Y. Ikariyama and W.R. Heineman, Anal. Chem., 58 (1986) 1803.

    Article  CAS  Google Scholar 

  24. N. Barisci, G.G. Wallace, E.A. Wilke, M. Meaney, M.R. Smyth and J.G. Vos, Electroanalysis, in press, 1989.

    Google Scholar 

  25. G.G. Wallace, M. Meaney, M.R. Smyth and J.G. Vos, Electroanalysis, in press, 1989.

    Google Scholar 

  26. M. Meaney, J.G. Vos, M.R. Smyth and G.G. Wallace, Analytical Proceedings, 26 (1989) 15.

    Article  CAS  Google Scholar 

  27. J. Wang, P. Tuzhi and T. Golden, Anal. Chem., 59 (1987) 740.

    Article  CAS  Google Scholar 

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© 1990 Springer Science+Business Media New York

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Wallace, G.G., Meaney, M., Smyth, M.R. (1990). Application of Modified Electrodes for Analysis in Flowing Solutions. In: Ivaska, A., Lewenstam, A., Sara, R. (eds) Contemporary Electroanalytical Chemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-3704-9_30

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  • DOI: https://doi.org/10.1007/978-1-4899-3704-9_30

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4899-3706-3

  • Online ISBN: 978-1-4899-3704-9

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