Abstract
Chromatographic columns in which the moving phase is a liquid were described in Chapter 2; columns where the moving phase is a gas such as nitrogen or hydrogen will now be considered. Adsorption and partition systems are possible; the respective techniques are known as gas-solid chromatography (GSC) and gas-liquid chromatography (GLC). In gas-solid chromatography the column is packed with an adsorbent such as silica gel and the components of the mixture distribute themselves between the gas phase and the adsorbed phase, that is, on the surface of the solid. Separation is due to differences in adsorptive behaviour. In gas-liquid chromatography the column is packed with a porous solid coated with a thin layer of involatile liquid as the stationary phase. Separation is due to differences in solution behaviour. Components of the mixture distribute themselves between the gas phase and the stationary liquid phase according to their partition coefficients. The solid functions only as a support for the liquid stationary phase, enabling it to present a large surface to the gas.
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References
Knapman, C. E. H., Gas Chromatography Abstracts, 1958–1962 Butterworths, London; 1963–1969 Institute of Petroleum, London; Gas and Liquid Chromatography Abstracts, 1970–1972 Institute of Petroleum, London; 1973 et seq. Applied Science Publishers, Barking, England.
Martin, A. J. P., Synge, R. L. M., Biochem. J., 1941, 35, 1358.
Claesson, S., Arkiv KemL, Min. GeoL, 1946, A23, 1.
Phillips, C. S. G., Discuss. Faraday Soc., 1949, No. 7, 241.
Griffiths, J., James, D., Phillips, C. S. G., Analyst, 1952, 77, 897.
Glueckauf, E., Barker, K. H., Kitt, G. P., Discuss. Faraday Soc., 1949, No. 7, 199.
Cremer, E., Prior, F., Z. Electrochem., 1951, 55, 66.
Cremer, E., Muller, R., Ibid., p. 217.
Martin, A. J. P., James, A. T., Biochem. J., 1952, 50, 679.
Golay, M. J. E., Gas Chromatography, Editors Coates, Noebels and Fagerson, Academic Press, New York, 1959, p. 1.
Stack, M. V. Gas Chromatography 1968, Editor Harbourne, C. L. A. Institute of Petroleum, London 1969, p. 109.
Littlewood, A. B., Phillips, C. S. G., Price, D. T., J. Chem. Soc. 1955, 1480.
James, D., Phillips, C. S. G., J. Sci. Inst., 1952, 29, 362.
Hall, R. A., Ibid, 1955, 32, 116.
Harrison, G. F., Vapour Phase Chromatography 1956, Editor Desty, D. H., Butterworth, London, 1956, p. 332.
Scott, R. P. W., Gas Chromatography 1958, Editor Desty, D. H., Butterworth, London, 1958, p. 189.
McCreadie, S. W. S., Williams, A. F., J. App1 Chem., 1957, 7, 47.
Otte, E., Jentzsch, D., Gas Chromatography 1970, Editor Stock, R., Institute of Petroleum, London, 1971, p. 218.
Kolb, B., Hoser, W., Chromatographia 1973, 6, 28.
Astbury, G. K., Davies, A. J., Drinkwater, J. W., Analyt. Chem., 1957, 29, 918.
Fischer, H., Neufelder, M., Pruggmeyer, D. Chromatographia 1972, 8, 613.
Halasz, I., Analyt. Chem. 1964, 36, 1428.
Guiochon, G., Goedert, M., Jacob, L. Gas Chromatography 1970, Editor Stock, R., Institute of Petroleum, London 1971, p. 160.
Clarke, A., Grant, D. W. Ibid., p. 189;
Wittebrood, R. T. Chromatographia 1972, 8, 454.
Littlewood, A. B., Gas Chromatography, Academic Press New York, 1970 p. 339.
Martin, A. J. P., James, A. T., Biochem. J., 1956, 63, 138.
Phillips, C. S. G., Timms, P. L., J. Chromatog., 1961, 5, 131.
McWilliam, I. G., Dewar, R. A., Gas Chromatography 1958, Editor Desty, D. H. Butterworth, London, 1958, p. 142.
Lovelock, J. E., J. Chromatog., 1958, 1, 35;
Lovelock, J. E., Gas Chromatography 1960, Editor Scott, R. P. W., Butterworth, London, 1960, p. 16.
Lovelock, J. E., Analyt. Chem., 1961, 33, 162.
Condon, R. D., Scholly, P. R., Averill, W., Gas Chromatography 1960, Editor Scott, R. P. W., Butterworth, London. 1960, p. 30.
Willis, V., Nature, 1959, 184, 894.
Berry, R., Nature, 1960`, 186, 578
Berry, R., Gas Chromatography 1962, Editor van Swaay, M., Butterworth, London, 1962, p. 321.
Bevan, S. C., Thorburn, S., J. Chromatog. 1965, 11, 301;
Bevan, S. C., Thorburn, S., Chem. Brit., 1965, 2, 206.
Janak, J., Chem. Listy, 1953, 47, 464
Janak, J., Collection Czech. Chem. Communs., 1954, 19, 684.
Ambrose, D., Kuelemans, A. I. M., Purnell. J. H., Analyt. Chem., 1958, 30, 1582.
Preliminary recommendations on nomenclature and presentation of data in gas chromatography. Pure and Applied Chemistry, 1, No. 1.
Thombs, D. A., Chromatographia 1973, 6, 111.
Ambrose, D., Purnell, J. H., Gas Chromatography 1958, Editor Desty, D. H., Butterworth, London, 1958, p. 363.
Adlard, E. R.. Khan, M. A., Whitman, B. T., Gas Chromatography 1960, Editor Scott, R. P. W., Butterworth, London 1960, p. 251.
Kovats, E., et al., Heiv. Chim. Acta, 1958, 41, 1915;
Kovats, E., et al., Ibid.,1959, 42, 2519; Ibid., 2709.
Smith, J. F., Chem. and Ind., 1960, 1024.
Evans, M. B., Smith, J. F., J. Chromatog., 1961, 5, 300; 1961 6, 293.
Peetre, I-B., Chromatographia 1973, 6, 257.
Haarhoff, P. C., van der Linde, H., J. Analyt. Chem. 1966, 38, 573;
Sewell, P. A., Stock, R., J. Chromatog. 1970, 50, 10.
Watson, J. T., Biemann, K., Analyt. Chem., 1964, 36, 1135;
Ryhage, R., Ibid. p. 759;
Henneberg, D., Schomburg, G., Gas Chromatography 1970, Editor Stock, R., Institute of Petroleum, London, 1971, p. 141.
Neuner-Jehle, N., Etzweiler, F., Zarske, G., Chromatographia, 1973, 6, 211.
Anthony, G. M., Brooks, C. J. W., Gas Chromatography 1970, Editor Stock, R., Institute of Petroleum, London 1971, p. 70.
Guiochon, G., Goedert, M., Jacob, L., Ibid. p. 160.
Deans, D. R., Chromatographia 1968, 1, 187.
Stock, R., Mainwaring, J., unpublished work.
Ettre, L. S., J. Chromatog., 1960, 4, 166.
Drew, C. M., Bens, E. M., Gas Chromatography 1968, Institute of Petroleum, London 1969, p. 3.
Bens, E. M., Analyt. Chem., 1961, 33, 179.
Knight, H. S., Ibid., 1958, 30, 2030.
Littlewood, A. B., Gas Chromatography 1958, Editor Desty, D. H., Butterworth, London, 1968, p. 23.
Halasz, I., Wegner, E. E., Nature, 1961, 189, 570.
Keulemans, A. I. M., Kwantes, A., Zaal, P., Analyt. Chim. Acta, 1955, 13, 357.
Materials for Gas Chromatography, 2nd Edition. May and Baker (Dagenham, England).
Porter, R. S., Johnson, J. F., Analyt. Chem., 1961, 33, 1152.
Cartoni, G. P., Lowrie, R. S., Phillips, C. S. G., Venanzi, L. M., Gas Chromatography 1960, Editor Scott, R. P. W., Butterworth, London, 1960, p. 273;
Maczek, A. O. S., Phillips, C. S. G., Ibid., p. 284.
Schurig, V., Chang, R. C., Zlatkis, A., Chromatographia 1973, 6, 223.
Freeguard, G. F., Stock, R., Gas Chromatography 1962, Editor van Swaay, M., Butterworth, London, 1962, p. 102.
Spencer, C. F., Johnson, J. F., Analyt. Chem., 1960, 32, 1386.
Martin, R. L., Ibid., 1961, 33, 347.
Watson, D., Cocker Chemical Co., Oswaldtwistle. Personal communication.
Kirkland, J. J., Analyt. Chem., 1960, 32, 1388.
Gray, G. M., J. Chromatog., 1960, 4, 52.
Kircher, H. W., Analyt. Chem., 1960, 32, 1103.
Ruhlmann, O. K., Giesecke, W., Angew Chem. 1961, 73, 113.
Bayer, E., Gas Chromatography 1958, Editor Desty, D. H., Butterworth, London 1958, p. 333.
Eaborn, C., Walton, D. R. M., Thomas, B. S., Chem. Ind. 1967, 827.
Kresze, G., Schauffelhaut, F., Z. anal Chem. 1967, 229, 401.
Dunges, W., Chromatographia 1973, 6, 196.
Perry, S. G., Adv. in Chromatog. 1968, 7, 221;
McKinney, R. W., McFadden, W. H., Ancillary Techniques of Gas Chromatography, Editor Ettre, L. S., Wiley-Interscience, New York 1969, p. 55;
Levy, R. L., Chrom. Rev. 1967, 8, 49.
Coupe, N. B., Jones, C. E. R., Perry, S. G., J. Chrom. 1970, 47, 291;
Coupe, N. B., Jones, C. E. R., Perry, S. G., Gas Chromatography 1970, Editor Stock R., Institute of Petroleum London 1971, p. 399;
Coupe, N. B., Jones, C. E. R., Stockwell, P. B., Chromatographia 1973, 6, 483.
Lerhle, R. S., Robb, J. C., J. Gas. Chrom. 1967, 5, 89.
Simon, W., Giacobbo, H., Chem-Ingr-Techr. 1965, 37, 709.
Ellis, J. F., Iveson, G., Gas Chromatography 1958, Editor Desty, D. H. Butterworth, London, 1958, p. 300.
Phillips, T. R., Owens, D. R., Gas Chromatography 1960, Editor Scott, R. P. W., Butterworth, London, 1960, p. 308.
Keller, R. A. Freiser, H., Ibid., p. 301.
Brandt, W. W., Ibid., p. 305.
Bierman, W. J., Gesser, H., Analyt. Chem., 1960, 32, 1525.
Keulemans, A. I. M., Gas Chromatography 1960, Editor Scott, R. P. W., Butterworth, London, 1960, p. 306.
Shipotofsky, S. H., Moser, H. C., Analyt. Chem. 1961, 33, 521.
Abel, E. W., Nickless, G., Pollard, F. H., Proc. Chem. Soc., 1960, 288.
Juvet, R. S., Wachi, F. M., Analyt. Chem., 1960, 32, 290.
Seely, G. R., Oliver, J. P., Ritter, D. M., Ibid., 1959, 31, 1993.
Kaufman, J. J., Todd, J. E., Koski, W. S., Ibid., 1957, 29, 1032.
Schomburg, G., Gas Chromatography 1962, Editor van Swaay, M., Butterworth, London, 1962, p. 292.
Ross, W. D., Scribner, W. G., Sievers, R. E., Gas Chromatography 1970, Editor, Stock, R., Institute of Petroleum, London, 1971, p. 369.
Sievers, R. E., Ibid., p. 378.
Pommier, C., Ibid. p. 379.
Schwedt, G., Rüssel, H. A., Chromatographia 1972, 5, 242.
Tournes, D. A., Ibid., p. 441.
Belcher, R., Jenkins, C. R., Stephen, W. I., Uden, P. C., Talanta 1970, 17, 455.
Golay, M. J. E., Gas Chromatography 1958, Editor Desty, D. H., Butterworth, London, 1958, p. 36.
Ettre, L. S., Averill, W., Analyt. Chem. 1961, 33, 680.
Desty, D. H., Haresnape, J. N., Whyman, B. H. F., Analyt. Chem., 1960, 32, 302.
Condon, R. D., Ibid., 1959, 31, 1717.
Scott, R. P. W., Hazeldean, G. S. F., Gas Chromatography 1960, Editor Scott, R. P. W., Butterworth, London, 1960, p. 144.
Scott, R. P. W., Nature, 1959, 188, 1753.
Desty, D. H., Goldup, A., Gas Chromatography 1960, Editor Scott, R. P. W., Butterworth, London, 1960, p. 162.
Turner, N. C., Petrol. Refiner 1943, 22, 98.
Ray, N. H., J. Appl. Chem., 1954, 4, 21;
Ray, N. H., Ibid., p. 82;
Ray, N. H., Analyst, 1956, 80, 863.
Janak, J., Vapour Phase Chromatography 1956, Editor Desty, D. H. Butterworth, London, 1956, p. 235.
McKenna, T. A., Idleman, J. A., Analyt. Chem., 1960, 32, 1299.
Greene, S. A., Pust, H., Ibid., 1957, 29, 1055.
Szculczewski, D. H., Higuchi, T., Ibid., p. 1541.
Marvillet, L., Tranchant, J., Gas Chromatography 1960, Editor Scott, R. P. W., Butterworth, London, 1960, p. 321.
Scott, C. G., Phillips, C. S. G., Gas Chromatography 1964, Editor Goldup, A., Institute of Petroleum, London 1965, p. 266.
Phillips, C. S. G., Gas Chromatography 1970, Editor Stock, R., Institute of Petroleum, London 1971, p. 1.
Scott, C. G., J. Inst. Petrol. 1959, 45, 118;
Scott, C. G., Gas Chromatography 1960, Editor Scott, R. P. W., Butterworth, London, 1960, p. 137;
Scott, C. G., Gas Chromatography 1962, Editor van Swaay, M. Butterworth, London, 1962, p. 36.
Halasz, I., Gas Chromatography 1962, Editor van Swaay, M., Butterworth, London, 1962, p. 133.
Scott, R. P. W., Lawrence, J. G., J. Chrom. Sci 1969, 7, 65.
McCreery, R. L., Sawyer, D. T., J. Chrom. Sci. 1970, 8, 122;
McCreery, R. L., Sawyer, D. T., Analyt. Chem. 1968, 40, 106.
Kirkland, J. J., Gas Chromatography 1964, Editor Goldup, A., Institute of Petroleum, London, 1965, p. 285.
Genty, C., Schott, R., Analyt. Chem. 1970, 42, 7.
West, D. L., Martson, A. L., J. Amer. Chem. Soc. 1964, 86, 4731.
Petrova, R. S., Khrapova, E. V., Scherbakova, K. D., Gas Chromatography 1962, Editor van Swaay, M., Butterworth, London, 1962, p. 18.
Kirkland, J. J., J. Chrom. Sci., 1970, 8, 303.
Little, J. N., Ibid. p. 647.
Hawton, I. J., Campbell, P., Ibid. p. 675.
Eggertsen, F. T., Knight, H. S., Groennings, S., Analyt. Chem., 1955, 27, 170.
Petov, G. M., Scherbakova, K. D., Gas Chromatography 1966, Editor Littlewood, A. B., Institute of Petroleum, London 1967, p. 50.
Vidal-Madjar, C., Ganansia, J., Guiochon, G., Gas Chromatography 1970, Editor, Stock, R., Institute of Petroleum, London 1970, p. 20.
Goretti, G., Liberti, A., Nota, G., Gas Chromatography 1968, Editor Harbourn, C. L. A., Institute of Petroleum, London 1969, p. 22.
Brunnock, J. V., Luke, L. A., Analyt. Chem. 1968, 40, 2158.
Hollis, O. L., Ibid. 1966, 38, 309.
Sakodynsky, K. I., Klinskaya, N. S., Panina, L. I., Ibid. 1973, 45, 1369.
Sie, S. T., Bleumer, J. P. A., Rijnders, G. W. A., Gas Chromatography 1968, Editor Harbourn, C. L. A., Institute of Petroleum, London 1969, p. 235.
Glueckauf, E., Discuss. Faraday Soc., 1949, No. 7, 12.
Wilson, J. N., J. Amer. Chem. Soc., 1940, 62, 1583.
de Vault, D., Ibid., 1943, 65, 532.
Glueckauf, E., Trans. Faraday Soc., 1955, 51, 34.
Keulemans, A. I. M., Gas Chromatography, Reinhold, New York, 1959.
Porter, P. E., Deal, C. H., Stross, F. H., J. Amer. Chem. Soc., 1956, 78, 2999.
Green, S. A., Pust, H., J. Phys. Chem., 1958, 62, 55.
Kwantes, A., Rijnders, G. W. A., Gas Chromatography 1958, Editor Desty, D. H., Butterworth, London, 1958, p. 128.
Anderson, J. R., Napier, K. H., Austral. J. Chem., 1956, 9, 541.
Hardy, C. J., J. Chromatog., 1959, 2, 490.
Evered, E., Pollard, F. H., Ibid., 1960, 4, 451;
Pollard, F. H., Hardy, C. J., Analyt. Chim. Acta, 1957, 16, 135.
Phillips, C. S. G., Gas Chromatography 1958, Editor Desty, D. H., Butterworth, London, 1958, p. 340.
van Deemter, J. J., Zuiderweg, F. J., Klinkenberg, A., Chem. Eng. Sci., 1956, 5, 271.
Scott, R. P. W., Gas Chromatography 1958, Editor Desty, D. H. Butterworth, London, 1958, p. 189.
Bohemen, J., Purnell, J. H., Ibid., p. 6.
Golay, M. J. E., Gas Chromatography 1960, Editor Scott, R. P. W., Butterworth, London, 1960, p. 139.
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Stock, R., Rice, C.B.F. (1974). Gas Chromatography. In: Chromatographic Methods. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-3360-7_4
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