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Acid Catalysis by Insoluble Macromolecular Acids

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Proton-Transfer Reactions

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Abstract

Insoluble materials containing acidic or basic functions are commonly known as ion exchangers, in recognition of their most useful property. Typical cation exchangers, for example, are polymeric acids. Their acidic hydrogen is exchangeable for metal ions which are retained whilst the displaced hydrogen ions pass into the solution phase. As they are acids, such cation exchangers, in the hydrogen form, can act as catalysts of reactions in solution that are accelerated by proton transfer from catalyst to substrate. Correspondingly, anion exchangers in their basic form can function as base or nucleophilic catalysts. Many examples of these phenomena, mostly concerned with polymeric organic sulphonic acids and far too numerous even to catalogue here, are known [1].

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Authors
  1. Victor Gold
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  2. Colin J. Liddiard
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  3. Gareth D. Morgan
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Editor information

Editors and Affiliations

  1. University Chemical Laboratory, University of Kent, Canterbury, New Zealand

    Edward Caldin

  2. Department of Chemistry, King’s College, London, UK

    Victor Gold F.R.S.

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Gold, V., Liddiard, C.J., Morgan, G.D. (1975). Acid Catalysis by Insoluble Macromolecular Acids. In: Caldin, E., Gold, V. (eds) Proton-Transfer Reactions. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-3013-2_13

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  • DOI: https://doi.org/10.1007/978-1-4899-3013-2_13

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-0-412-12700-7

  • Online ISBN: 978-1-4899-3013-2

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