Abstract
The importance of the interactions between water and soil colloid surfaces was stressed in Section 2.4 of this book. Special attention was focused there on water at clay surfaces, on the associations between water and the soil organic colloids, and on the influences of water on the swelling and shrinking of soils. Further attention is given to the swelling of clays in Sections 14.2 and 16.5, and some concepts of the behaviour and properties of films of water at clay surfaces are outlined in Section 16.6.
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References
Barnes, J.D. 1973. Inelastic neutron scattering study of the ‘rotor’ phase transition in n-nonadecane. J. Chem. Phys 58, 5193–5201.
Burchill, S., Hayes, M.H.B. and Greenland, DJ. 1981. Adsorption. In D.G. Greenland and M.H.B. Hayes (eds.), The Chemistry of Soil Processes. Wiley, Chichester pp. 221–400.
Conard, J., Hestrade-Szwarkopf, H., Poinsignon, C. and Dinoux, A.J. 1984. Dynamical Properties of the Li+ 3 H2O lithium hydrate in the interlamellar space of a swelling clay. J. Phys. Colloq. C7, 169–172.
Farmer, V.C. 1978. Water on particle surfaces. In D.G. Greenland and M.H.B. Hayes (eds.), The Chemistry of Soil Processes. Wiley, Chichester pp. 405–448.
Franks, F., Ravenhill, J., Egelstaff, P.A. and Page, D.I. 1970. Motions of water molecules in dilute aqueous solutions of tertiary butyl alcohol; a neutron scattering study of hydrophobic hydration. Proc. Roy. Soc, Ser. A. 319, 189–208.
Fripiat, J.J. 1980. The application of NMR to the study of clay minerals. In J.W. Stucki and W.L. Banwart (eds.), Advanced Chemical Methods for Soil and Clay Minerals Research. NATO Advanced Study Inst. Series. D. Reidel Co., Dordrecht and Boston, pp. 245–315.
Giese, R.F. and Fripiat, J.J. 1979. Water molecule positions, orientations, and motions in the dihydrates of magnesium and sodium vermiculites. J. Colloid Interface Sci. 71, 441–450.
Hall, P.L. 1981. Neutron scattering techniques of clay minerals. In J.J. Fripiat (ed.), Advanced Techniques for Clay Mineral Analysis. Elsevier, Amsterdam. pp. 51–75.
Hall, P.L., Churchman, G.J. and Theng, B.K.G. 1985. Size distribution of allophane unit particles in aqeous suspensions. Clays and Clay Minerals 33, 345–349.
Hall, P.L., Ross, D.K., Tuck, J.J. and Hayes, M.H.B. 1979a. Neutron scattering studies of the dynamics of interlamellar water in montmorillonite and vermiculite. In M.M. Mortland and V.C. Farmer (eds.), Proc. Intern. Clay Conf. (Oxford, 1978). Elsevier, Amsterdam. pp. 121–130.
Newman, A.C.D. 1978. The interaction of water with clay mineral surfaces. In A.C.D. Newman (ed.), Chemistry of Clays and Clay Minerals. Longman, Harlow, and Mineralogical Society, London. pp. 237–274.
Prost, R. 1975. Interactions between adsorbed water molecules and the structure of clay minerals: Hydration mechanism of smectites. In S.W. Bailey (ed.), Proc. Intern. Clay Conf. (Mexico City). Applied Publishing Ltd., Wilmette, Illinois. pp. 351–359.
Ricci, F.D., Ricci, M.A. and Rocca, D. 1974. Role of hydrogen bond in self diffusion process in liquid water. Phys Lett. A 48, 289–290.
Ross, D.K. and Hall, P.L. 1980. Neutron scattering methods of investigating clay systems. In J.W. Stucki and W.L. Banwart (eds.), Advanced Chemical Methods for Soil and Clay Minerals Research. NATO Advanced Study Inst. Series. D. Reidel Co., Dordrecht and Boston. pp. 93–168.
Singwi, K.S. and Sjolander, A. 1960. Diffusive motions in water and cold neutron scattering. Phys. Rev. 119, 863–871.
Sposito, G. and Prost, R. 1982. Structure of water adsorbed on smectites. Chem. Rev. 82, 573–593.
Tuck, J.J., Hall, P.L., Hayes, M.H.B., Ross, D.K. and Poinsignon, C. 1984. Quasi-elastic neutron-scattering studies of the dynamics of intercalated molecules in charge-deficient layer silicates. Part 1. Temperature dependence of the scattering from water in Ca2+-exchanged montmorillonite. J. Chem. Soc. Faraday Trans. 1 80, 309–324.
Tuck, J.J., Hall, P.L., Hayes, M.H.B, Ross, D.K. and Hayter, J.B. 1985. Quasi-elastic neutron-scattering studies of the dynamics of intercalated molecules in charge-deficient layer silicates. Part 2. High resolution measurements of the diffusion of water in montmorillonite and vermiculite. J. Chem. Soc. Faraday Trans. 1 81, 833–846.
Van Hove, L. 1954. Correlations in space and time and Born approximation scattering in systems of interacting particles. Phys. Rev. 95, 249–262.
Von Blanckenhagen, P. 1972. Intermolecular vibrations and diffusion in water investigated by scattering of cold neutrons. Ber. Bunsenges Phys. Chem. 76, 891–903.
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Tuck, J.J., Hayes, M.H.B. (1990). Structure and Dynamics of Water at Clay Surfaces. Inferences from Neutron Scattering Studies. In: De Boodt, M.F., Hayes, M.H.B., Herbillon, A., De Strooper, E.B.A., Tuck, J.J. (eds) Soil Colloids and Their Associations in Aggregates. NATO ASI Series, vol 214. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-2611-1_13
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