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Bonding of Foreign Species at the Solid Surface

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The Chemical Physics of Surfaces

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Abstract

In this and all subsequent chapters, we will be concerned with foreign species at the surface of a solid and how these foreign species affect the chemical and electrical properties of the surface. Here and in the next chapter the emphasis will be on describing the energy levels associated with the sorbate/sorbent bond. In Chapters 7–9 the emphasis will be switched to the processes of adsorption and desorption, of electron transfer, and of chemical reaction.

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References

  1. C. B. Duke and N. O. Lipari, J. Vac. Sci. Technol. 12, 222 (1975).

    CAS  Google Scholar 

  2. A. Ignatiev, F. Jona, D. W. Depsa, and P. M. Marcus, J. Vac. Sci. Technol. 12, 226 (1975).

    CAS  Google Scholar 

  3. J. W. May, Adv. Catal. 21, 151 (1970).

    CAS  Google Scholar 

  4. M. Henzler, Surf. Sci. 24, 209 (1971).

    CAS  Google Scholar 

  5. W. M. H. Sachtler, Surf. Sci. 22, 468 (1970).

    CAS  Google Scholar 

  6. A. A. Holscher and W. M. H. Sachtler, Discuss Faraday Soc. 41, 29 (1966).

    Google Scholar 

  7. R. Riwan, C. Guillot, and J. Paigne, Surf. Sci. 47, 183 (1975).

    CAS  Google Scholar 

  8. J. E. Demuth, D. W. Jepsen, and P. M. Marcus, Phys. Rev. Lett. 32, 1182 (1974).

    CAS  Google Scholar 

  9. T. E. Madey, J. J. Czyzewski, and J. T. Yates, Jr., Surf. Sci. 49, 465 (1975).

    CAS  Google Scholar 

  10. M. A. Van Hove, in The Nature of the Surface Chemical Bond, p. 277, edited by T. N. Rhodin and G. Ertl ( North-Holland, Amsterdam, 1979 ).

    Google Scholar 

  11. J. N. Butler, J. Giner, and J. M. Parry, Surf. Sci. 18, 140 (1969).

    CAS  Google Scholar 

  12. D. A. Rand and R. Woods, Surf Sci. 41, 611 (1974).

    Google Scholar 

  13. V. Ponec, Catal. Rev. 11, 41 (1975).

    CAS  Google Scholar 

  14. W. M. H. Sachtler and P. van der Plank, Surf. Sci. 18, 62 (1969).

    CAS  Google Scholar 

  15. Y. Soma and W. M. H. Sachtler, Jpn. J. Appl. Phys., Suppl. 2, Pt. 2, 241 (1974).

    Google Scholar 

  16. M. Ya. Hodos, E. V. Bazarova, A. P. Palkin, and Kh. Z. Brunina, J. Electroanal. Chem. 164, 121 (1984).

    CAS  Google Scholar 

  17. G. Ertl, in The Nature of the Surface Chemical Bond, p. 315, edited by T. N. Rhodin and G. Ertl ( North-Holland, Amsterdam, 1979 ).

    Google Scholar 

  18. M. Tsukada, H. Adachi, and C. Satoko, Prog. Surf Sci. 14, 113 (1983).

    CAS  Google Scholar 

  19. L. Pauling, The Nature of the Chemical Bond ( Cornell University Press, Ithaca, N.Y., 1960 ).

    Google Scholar 

  20. R. T. Sanderson, Chemical Periodicity ( Van Nestrand Reinhold, New York, 1971 ).

    Google Scholar 

  21. R. Ludeke and A. Koma, Phys. Rev. Lett. 34, 1170 (1975).

    CAS  Google Scholar 

  22. G. A. Bootsma and F. Meyer, Surf Sci. 18, 123 (1969).

    CAS  Google Scholar 

  23. J. Fahrenfort, L. L. van Rijen, and W. M. H. Sachtler, in Proceedings of Symposium on Mechanics of Heterogeneous Catalysis, p. 23, Amsterdam, 1959.

    Google Scholar 

  24. G. C. Bond, Surf. Sci. 18, 11 (1969).

    CAS  Google Scholar 

  25. Z. Knor, Adv. Catal. 22, 51 (1972).

    CAS  Google Scholar 

  26. O. Johnson, J. CataL 28, 503 (1973).

    CAS  Google Scholar 

  27. G. C. Bond and P. B. Wells, Adv. CataL 15, 92 (1964).

    Google Scholar 

  28. J. L. Garnett, Catal. Rev. 5, 229 (1971).

    CAS  Google Scholar 

  29. R. B. Moyes and P. B. Wells, Adv. Catal. 23, 121 (1973).

    CAS  Google Scholar 

  30. M. Orchin, Adv. Catal. 16, 1 (1966).

    CAS  Google Scholar 

  31. : W. H. W.inberg, H. A. Deans, and R. P. Merrill, Surf. Sci. 41, 312 (1974).

    Google Scholar 

  32. R.-G. Windham, M. E. Bartram, and B. E. Koel, J. Vac. Sci. TechnoL A5, 457 (1987).

    Google Scholar 

  33. J. Stoehr, F. Selte, and A. L. Johnson, Phys. Rev. Lett. 53, 1684 (1984).

    Google Scholar 

  34. D. Arvanitis, U. Doebier, L. Wenzel, and K. Baberschke, Surf. Sci. 178, 686 (1986).

    CAS  Google Scholar 

  35. J. L. Gland and G. A. Somorjai, Surf. Sci. 41, 387 (1974).

    Google Scholar 

  36. R. Queau and R. Poilblanc, J. CataL 27, 200 (1972).

    CAS  Google Scholar 

  37. A. J. Goodsel and G. Blyholder, Chem. Comm. 17, 1132 (1970).

    Google Scholar 

  38. A. J. Sargood, C. W. Jowett, and B. J. Hopkins, Surf. Sci. 22, 343 (1970).

    CAS  Google Scholar 

  39. K. Shinjo, Prog. Surf Sci. 27, 161 (1988).

    CAS  Google Scholar 

  40. P. Mark, J. Phys. Chem. Solids 29, 689 (1968).

    CAS  Google Scholar 

  41. J. W. Rogers, Jr., C. T. Campbell, R. L. Hance, and J. M. White, Surf. Sci. 97, 425 (1980).

    CAS  Google Scholar 

  42. R. O. James and T. W. Healey, J. Coll. Interface Sci. 40, 42, 53, 65 (1972).

    Google Scholar 

  43. J. van Laar and J. J. Scheer, Surf. Sci. 8, 347 (1967).

    Google Scholar 

  44. R. Dorn, H. Lueth, and G. J. Russel, Phys. Rev. B9, 1951 (1974).

    Google Scholar 

  45. P. E. Gregory and W. E. Spicer, Surf. Sci. 54, 229 (1976).

    CAS  Google Scholar 

  46. F. S. Stone, Adv. Catal. 13, 1 (1962).

    CAS  Google Scholar 

  47. H. P. Boehm, Adv. Catal. 16, 179 (1966).

    CAS  Google Scholar 

  48. R. Kh. Burshtein, L. A. Larin, and S. I. Sergeev, in Surface Properties of Semiconductors, edited by A. N. Frumkin ( Consultants Bureau, New York, 1964 ).

    Google Scholar 

  49. A. J. Schell-Sorokin and J. E. Demuth, Surf Sci. 157, 273 (1985).

    CAS  Google Scholar 

  50. H. Ibach, H. D. Bruchmann, and H. Wagner, Appl. Phys. A29, 113 (1982).

    Google Scholar 

  51. P. E. Gregory and W. E. Spicer, Surf. Sci. 54, 229 (1976).

    CAS  Google Scholar 

  52. G. J. Russell and D. Haneman, Surf. Sci. 27, 362 (1971).

    CAS  Google Scholar 

  53. G. A. Somorjai, J. Phys. Chem. Solids 24, 175 (1963).

    CAS  Google Scholar 

  54. E. Guesne, C. Sebenne, and M. Balkanski, Surf. Sci. 24, 18 (1971).

    CAS  Google Scholar 

  55. A. M. Morgan and D. A. King, Surf Sci. 23, 259 (1970).

    Google Scholar 

  56. P. H. Holloway, J. Vac. Sci. Technol. 18, 653 (1981).

    CAS  Google Scholar 

  57. H. J. Elmers and U. Gradman, Surf. Sci. 193. 44 (1988).

    Google Scholar 

  58. G. K. Hall and C. H. B. Mee, Surf. Sci. 28. 598 1971 ).

    CAS  Google Scholar 

  59. M. W. Roberts and B. R. Wells, Surf Sci. 15, 325 (1969).

    CAS  Google Scholar 

  60. A. Benninghoven and L. Wiedmann, Surf. Sci. 41, 483 (1974).

    Google Scholar 

  61. T. Robert, M. Bartel, and G. Offergeld, Surf. Sci. 33, 123 (1972).

    CAS  Google Scholar 

  62. J. W. Gadzuk, in Surface Physics of Materials, edited by J. M. Blakely ( Academic Press, New York, 1975 ).

    Google Scholar 

  63. T. B. Grimley, Ber. Bunsenges. Phys. Chem. 75, 1003 (1971).

    CAS  Google Scholar 

  64. T. B. Grimley, Adv. Catal. 12, 1 (1960).

    CAS  Google Scholar 

  65. J. C. Robertson and C. W. Wilmsen, J. Vac. Sci. Technol. 8, 53 (1971).

    CAS  Google Scholar 

  66. L. W. Anders, R. S. Hansen, and L. S. Bartell, J. Chem. Phys. 10, 5277 (1973).

    Google Scholar 

  67. R. P. Messmer, B. McCarroll, and C. M. Singal, J. Vac. Sci. Technol. 9, 891 (1972).

    CAS  Google Scholar 

  68. A. J. Bennett, B. McCarroll, and R. B. Messmer, Surf. Sci. 24, 191 (1971).

    CAS  Google Scholar 

  69. R. P. Messmer, in The Nature of the Chemical Bond, edited by T. N. Rhodin and G. Ertl ( North-Holland, Amsterdam, 1979 ).

    Google Scholar 

  70. G. A. Benesh and J. R. Hester, Surf. Sci. 194, 567 (1986).

    Google Scholar 

  71. H. Krakauer, M. Posternak, and A. J. Freeman, Phys. Rev. B19, 1706 (1979).

    CAS  Google Scholar 

  72. T. B. Grimley, in The Nature of the Surface Chemical Bond, edited by T. N. Rhodin and G. Ertl ( North-Holland, Amsterdam, 1979 ).

    Google Scholar 

  73. A. B. Kuntz, Prog. Surf. Sci. 26, 165 (1987).

    Google Scholar 

  74. J. R. Schrieffer and P. Soven, Phys. Today 28, 24 (1975).

    CAS  Google Scholar 

  75. A. van der Avoird, S. P. Liebmann, and D. J. M. Fassaert, Phys. Rev. B10, 1230 (1974).

    Google Scholar 

  76. J. C. Slater and K. H. Johnson, Phys. Today 27, 34 (1974).

    CAS  Google Scholar 

  77. R. P. Messmer, S. K. Knudson, K. H. Johnson, J. B. Diamond, and C. Y. Yang, Phys. Rev. B13, 1396 (1976).

    CAS  Google Scholar 

  78. I. P. Batra and O. Robaux, Surf. Sci. 49, 653 (1975).

    CAS  Google Scholar 

  79. I. P. Batra and P. S. Bagus, Solid State Comm. 16, 1097 (1975).

    CAS  Google Scholar 

  80. P. S. Bagus and K. Hermann, Phys. Rev. B33, 2987 (1986).

    CAS  Google Scholar 

  81. D. E. Eastman and J. K. Cashion, Phys. Rev. Lett. 27, 1520 (1971).

    CAS  Google Scholar 

  82. N. Roesch and T. N. Rhodin, Phys. Rev. Lett. 32, 1123 (1974); Discuss Faraday Soc. 58, 28 (1974).

    Google Scholar 

  83. J. E. Demuth and D. E. Eastman, Phys. Rev. Lett. 32, 1189 (1974); Jpn. J. Appl. Phys., Suppl. 2, Pt. 2, 827 (1974).

    Google Scholar 

  84. J. E. Demuth and D. E. Eastman, Phys. Rev. B13, 1523 (1976).

    CAS  Google Scholar 

  85. A. Kuntz, Prog. Surf. Sci. 26, 165 (1987).

    Google Scholar 

  86. J. A. Rodriguez and C. T. Campbell, Surf. Sci. 194, 475 (1988).

    CAS  Google Scholar 

  87. R. Kubawara, H. Adachi, and T. Morimoto, Surf Sci. 193, 271 (1988).

    Google Scholar 

  88. M. Tsukada, H. Adachi, and C. Satoko, Prog. Surf. Sci. 14, 113 (1983).

    CAS  Google Scholar 

  89. T. B. Grimley, J. Vac. Sci. Technol. 8, 31 (1971).

    CAS  Google Scholar 

  90. D. R. Penn, Surf Sci. 39, 333 (1973).

    CAS  Google Scholar 

  91. D. M. Newns, Phys. Rev. 178, 1123 (1969).

    CAS  Google Scholar 

  92. P. W. Anderson, Phys. Rev. 124, 41 (1961)

    CAS  Google Scholar 

  93. J. R. Schrieffer, J. Vac. Sci. Technol. 9, 561 (1971).

    Google Scholar 

  94. J. P. Muscat and D. M. Newns, Prog. Surf. Sci. 9, 1 (1978).

    CAS  Google Scholar 

  95. L. G. Parent and S. G. Davison, J. Electroanal. Chem. 163, 23 (1984).

    CAS  Google Scholar 

  96. E. A. Hyman, Phys. Rev. B11, 3739 (1975).

    Google Scholar 

  97. H. Ueba, Surf. Sci. 215, 232 (1989).

    CAS  Google Scholar 

  98. S. K. Lyo and R. Gomer, Phys. Rev. B10, 4161 (1974).

    CAS  Google Scholar 

  99. S. G. Davison and Y. S. Huang, Solid State Comm. 15, 863 (1974).

    CAS  Google Scholar 

  100. E. N. Foo and S. G. Davison, Surf Sci. (1976).

    Google Scholar 

  101. E. N. Korol and O. Yu. Posudievsky, Surf. Sci. 169, 104 (1986).

    CAS  Google Scholar 

  102. K. Shingo, Prog. Surf Sci. 27, 161 (1988).

    Google Scholar 

  103. D. J. M. Fassaert, H. Verbeeck, and A. van der Avoird, Surf. Sci. 29, 501 (1972).

    CAS  Google Scholar 

  104. S. P. Liebmann, A. van der Avoird, and D. J. M. Fassaert, Phys. Rev. Bll, 1503 (1975).

    Google Scholar 

  105. T. L. Einstein, Phys. Rev. B11, 577 (1975).

    Google Scholar 

  106. S. C. Ying, J. R. Smith, and W. Kohn, Phys. Rev. B11, 1483 (1975).

    CAS  Google Scholar 

  107. H. B. Huntington, L. A. Turk, and W. W. White, Surf. Sci. 48, 187 (1975).

    CAS  Google Scholar 

  108. J. W. Gadzuk, J. Vac. Sci. Technol. 12, 289 (1975).

    CAS  Google Scholar 

  109. P. J. Feibelman and D. E. Eastman, Phys. Rev. B10, 4932 (1974).

    Google Scholar 

  110. D. Menzel, J. Vac. Sci. Technol. 12, 313 (1975).

    CAS  Google Scholar 

  111. C. R. Brundle, Surf Sci. 48, 99 (1975).

    CAS  Google Scholar 

  112. K. Y. Yu, J. C. McMenamin, and W. E. Spicer, J. Vac. Sci. Technol. 12, 286 (1975).

    CAS  Google Scholar 

  113. E. Sickafus and F. Steinrisser, Phys. Rev. B6, 3714 (1972).

    CAS  Google Scholar 

  114. A. Liebsch, Phys. Rev. Lett. 32, 1203 (1974).

    Google Scholar 

  115. A. Liebsch and G. W. Plummer, Discuss Faraday Soc. 58, 19 (1974).

    Google Scholar 

  116. J. W. Gadzuk, Phys. Rev. B10, 5030 (1974); Surf. Sci. 43, 44 (1974).

    CAS  Google Scholar 

  117. M. M. Traum, J. E. Rowe, and N. E. Smith, J. Vac. Sci. Technol. 12, 298 (1975).

    CAS  Google Scholar 

  118. M. M. Traum, N. V. Smith, and I. J. DiSalvo, Phys. Rev. Lett. 32, 1241 (1974).

    CAS  Google Scholar 

  119. J. Anderson and G. J. Lapeyre, Phys. Rev. Lett. 36, 376 (1976).

    CAS  Google Scholar 

  120. B. Feuerbacher and B. Fitton, Solid State Comm. 15, 209 (1974).

    Google Scholar 

  121. J. E. Rowe and S. B. Christman, J. Vac. Sci. Technol. 12, 293 (1975).

    CAS  Google Scholar 

  122. B. J. Waclawski, T. V. Vorburger, and R. J. Stein, J. Vac. Sci. Technol. 12, 301 (1975).

    CAS  Google Scholar 

  123. T. E. Madey, J. J. Czyzerski, and J. T. Yates, Jr., Phys. Rev. Len. 32, 777 (1974).

    Google Scholar 

  124. S. J. Morgan, A. R. Law, R. H. Williams, D. Norman, R. McGrath, and I. T. McGovern, Surf. Sci. 204, 428 (1988).

    CAS  Google Scholar 

  125. K. L. I. Kobayashi, Y. Siraki, F. Gerken, and J. Barth, Phys. Rev. B24, 3575 (1981).

    CAS  Google Scholar 

  126. X. Xide and Z. Kaiming, Prog. Surf Sci. 28, 71 (1988).

    Google Scholar 

  127. R. J. Hamers and J. E. Demuth, J. Vac. Sci. Technol. A6, 512 (1988).

    CAS  Google Scholar 

  128. D. A. Wesner, F. P. Coenin, and H. P. Bonzel, Surf. Sci. 199, L419 (1988).

    CAS  Google Scholar 

  129. R. Gomer, Jpn. J. Appl. Phys., Suppl. 2, 213 (1974).

    Google Scholar 

  130. B. Feuerbacher, Surf. Sci. 47, 115 (1975).

    CAS  Google Scholar 

  131. P. L. Young and R. Gomer, Surf Sci. 44, 277 (1974).

    CAS  Google Scholar 

  132. J. Rubio, J. M. Lopez-Sancho, and M. P. Lopez-Sancho, J. Vac. Sci. Technol. 20, 217 (1982).

    CAS  Google Scholar 

  133. A. Wastberg and A. Rosen, Surf Sci. 193, L7 (1988).

    Google Scholar 

  134. P. J. Estrup and J. Anderson, J. Chem. Phys. 45, 2254 (1966).

    CAS  Google Scholar 

  135. P. W. Tamm and L. D. Schmidt, J. Chem. Phys. 55, 425 (1971).

    Google Scholar 

  136. B. Feuerbacher and R. F. Willis, Phys. Rev. Lett. 36, 1339 (1976).

    CAS  Google Scholar 

  137. J. Anderson, G. W. Rubloff, M. A. Passler, and P. J. Stiles, Phys. Rev. B10, 2401 (1974).

    CAS  Google Scholar 

  138. E. W. Plummer and A. E. Bell, J. Vac. Sci. Technol 9, 583 (1972).

    CAS  Google Scholar 

  139. J. W. Gadzuk and E. W. Plummer, Rev. Mod. Phys. 45, 487 (1973).

    CAS  Google Scholar 

  140. A. M. Bradshaw, D. Menzel, and M. Steinkelberg, Discuss. Faraday Soc. 58, 46 (1974).

    Google Scholar 

  141. K. A. Kress and G. J. Lapeyre, Phys. Rev. Lett. 28, 1639 (1972).

    CAS  Google Scholar 

  142. C. R. Helms and W. E. Spicer, Phys. Rev. Lett. 28, 565 (1972).

    CAS  Google Scholar 

  143. P. R. Norton and P. J. Richards, Surf Sci. 49, 567 (1975).

    CAS  Google Scholar 

  144. S. Ferrer, K. H. Frank, and B. Reihl, Surf Sci. 162, 264 (1985).

    CAS  Google Scholar 

  145. N. V. Smith and D. P. Woodruff, Prog. Surf. Sci. 21, 295 (1986).

    CAS  Google Scholar 

  146. E. C. Akubuiro and X. E. Verykios, J. Catal. 113, 106 (1988).

    CAS  Google Scholar 

  147. S. T. Li, S. Hasegawa, H. Iwasaki, Y. Mizokava, and S. Nakamura, Appl. Surf Sci. 22/23, 275 (1985).

    Google Scholar 

  148. R. J. Hamers, Ph. Avouris, and F. Bozso, J. Vac. Sci. Technol A6, 508 (1988).

    CAS  Google Scholar 

  149. V. E. Henrich, Prog. Surf. Sci. 9, 143 (1979).

    CAS  Google Scholar 

  150. G. W. Rubloff, H. Lueth, and W. D. Grobman, Chem. Phys. Lett. 39, 493 (1976).

    CAS  Google Scholar 

  151. H. Ibach, J. Vac. Sci. Technol A5, 419 (1987).

    CAS  Google Scholar 

  152. M. Sakurai, T. Okano, and Y. Tuzi, J. Vac. Sci. Technol A5, 431 (1987).

    CAS  Google Scholar 

  153. B. A. Sexton, Surf Sci. 88, 319 (1979).

    CAS  Google Scholar 

  154. H. Ueba, Prog. Surf. Sci. 22, 181 (1986).

    CAS  Google Scholar 

  155. S. R. Morrison, Surf. Sci. 20, 110 (1971).

    CAS  Google Scholar 

  156. K. W. Sulston, A. T. Amos, and S. G. Davison, Prog. Surf. Sci. 26, 63 (1987).

    CAS  Google Scholar 

  157. S. R. Morrison, Surf Sci. 10, 459 (1968).

    CAS  Google Scholar 

  158. H. G. Voelz, G. Kaempf, and H. G. Fitzky, Farbe u. Lack. 78, 1037 (1972).

    CAS  Google Scholar 

  159. A. Fujishima and K. Honda, Nature 238, 37 (1972).

    CAS  Google Scholar 

  160. M. S. Wrighton, D. S. Ginley, P. T. Wolczanski, A. B. Ellis, D. L. Morse, and A. Linz, Proc. Nat. Acad. Sci. U.S.A. 72, 1518 (1975).

    CAS  Google Scholar 

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    S. Roy Morrison

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Morrison, S.R. (1990). Bonding of Foreign Species at the Solid Surface. In: The Chemical Physics of Surfaces. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-2498-8_5

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