Abstract
There have been two dominant models used in describing the chemical and electronic behavior of a surface. One is the atomistic model, or the “surface molecule” model; the other is the band model, often called for emphasis the “rigid band” model. The atomistic model has been preferred in general in discussions of the chemical processes at a solid surface; the rigid band model is often preferred in discussions of electron exchange between the solid (especially a semiconductor) and a surface group, where, for example, the conductivity of the solid is changed. The atomistic model describes the solid surface in terms of surface sites, atoms, or groups of atoms at the surface, essentially ignoring the band structure of the solid. The rigid band model describes the surface in terms of surface states, localized electronic energy levels available at the surface, to a great extent ignoring the microscopic details of atom/atom interaction between the surface species and its neighboring substrate atom.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
F. F. Volkenshtein, The Electronic Theory of Catalysis on Semiconductors ( MacMillan, New York, 1963 ).
S. G. Davison and J. P. Levine. 25 of Solid State Physics, edited by F. Seitz and D. Turnbull ( Academic Press, New York, 1970 ).
W. M. H. Sachtler and P. Van der Plank, Surf Sci. 18, 62 (1969).
O. Johnson, J. Catal 28, 503 (1973).
Z. Knor, Adv. Catal 22, 51 (1972).
J. R. Schrieffer and P. Soven, Phys. Today 28, 24 (1975).
J. W. Gadzuk, Surf Sci. 43, 44 (1974).
M. J. Kelly, Surf Sci. 43, 587 (1974).
D. R. Penn, Surf. Sci 39, 333 (1973).
J. C. Slater and K. H. Johnson, Phys. Today 27, 34 (1974).
H. H. Ibach, K. Horn, R. Dorn, and H. Luth, Surf. Sci 38, 433 (1973).
F. Beck and H. Gerischer, Z. Electrochem 63, 943 (1959).
S. R. Morrison, Prog. Surf Sci 1, 105 (1971).
H. Gerischer, Surf. Sci 18, 97 (1969).
M. Green and M. J. Lee, in Vol. 1 of Solid State Surface Science, edited by M. Green ( Marcel Dekker, New York, 1969 ).
P. Mark, J. Phys. Chem. Solids 29, 689 (1968).
D. A. Dowden, Catal. Rev 5, 1 (1971).
S. Siegel, Adv. Catal 16, 123 (1966).
J. P. Muscat and D. M. Newns, Prog. Surf. Sci 9, 1 (1978).
R. T. Sanderson, Chemical Periodicity ( Van Nostrand Reinhold, New York, 1971 ).
F. Seel, Atomic Structure and Chemical Bonding, p. 38 ( Wiley, New York, 1963 ).
J. C. Phillips, Surf. Sci 37, 24 (1973).
H. Pines and J. Manassen, Adv. Catal 16, 49 (1966).
K. Tanabe, Solid Acids and Bases ( Academic Press, New York, 1970 ).
S. R. Morrison, Surf. Sci 50, 329 (1975).
J. W. May, Adv. Catal 21, 151 (1970).
H. Ohtani, C.-T. Kao, M. A. van Hove, and G. A. Somorjai, Prog. Surf. Sci 23, 155 (1986).
M. Prettre and B. Claudel, Elements of Chemical Kinetics ( Gordon and Breach, London, 1970 ).
J. C. Phillips, Surf. Sci 44, 290 (1974).
G. Blyholder and R. W. Sheets, J. Catal 39, 152 (1975).
L. Pauling, The Nature of the Chemical Bond ( Cornell University Press, Ithaca, N.Y., 1960 ).
H. P. Boehm, Discuss Faraday Soc. 52, 264 (1971).
J. T. Kummer and Y. Y. Yao, Can. J. Chem 45, 421 (1967).
R. Nosker, P. Mark, and J. D. Levine, Surf. Sci 19, 291 (1970).
G. I. Young, J. Colloid. Sci 13, 67 (1958).
H. S. Taylor, J. Am. Chem. Soc 53, 578 (1931).
L. D. Schmidt, Catal. Rev. Sci. Eng 9, 115 (1974).
R. D. Giles, J. A. Harrison, and H. R. Thrisk, J. Electroanal. Chem 20, 47 (1969).
J. M. Thomas, Adv. Catal 19, 293 (1969).
B. Lang, R. W. Joyner, and G. A. Somorjai, Surf. Sci 30, 454 (1972).
Author information
Authors and Affiliations
Rights and permissions
Copyright information
© 1990 Springer Science+Business Media New York
About this chapter
Cite this chapter
Morrison, S.R. (1990). Introduction. In: The Chemical Physics of Surfaces. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-2498-8_1
Download citation
DOI: https://doi.org/10.1007/978-1-4899-2498-8_1
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4899-2500-8
Online ISBN: 978-1-4899-2498-8
eBook Packages: Springer Book Archive