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Uses of Metal Clusters in Homogeneous and Heterogeneous Catalysis

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Metal-Metal Bonds and Clusters in Chemistry and Catalysis

Abstract

Molecular metal carbonyl clusters can serve as pivotal metal derivatives for a large variety of chemical processes. These are illustrated in Scheme 1, where a tetranuclear cluster, the majority of which are 3-dimensional and tetrahedral, is indicated.

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References

  1. E. L. Muetterties, Bull. Soc. Chim, Bela. 84, 959 (1975); ibid. 85, 451 (1976).

    CAS  Google Scholar 

  2. D. J. Darensbourg, Israel J. Chem. 15, 247 (1976).

    Google Scholar 

  3. R M. Laine, R G. Rinker, and P. C. Ford, J. Am. Chem. Soc. 99, 252 (1977).

    Article  CAS  Google Scholar 

  4. C. Ungermann, V. Landis, S. A. Moya, H. Cohen, H. Walker, R G. Pearson, R. G. Rinker, and P. C. Ford, J. Am. Chem. Soc., 101, 5922 (1979).

    Article  CAS  Google Scholar 

  5. P. C. Ford, Acc. Chem. Res. 14, 31 (1981).

    Article  CAS  Google Scholar 

  6. J. C. Bricker, C. C. Nagle, and S. G. Shore, J. Am. Chem. Soc. 104, 1444 (1982).

    Article  CAS  Google Scholar 

  7. M. M. Taqui Khan, S. B. Halligudi, and S. Shukla, Angew. Chem. Int. Ed. Engl. 27, 1735 (1988).

    Google Scholar 

  8. R. M. Laine and R. B. Wilson, Jr. in: “Aspects of Homogeneous Catalysis,” Renato Ugo, ed., D. Reidel Publishing Co., Dordrecht (1984).

    Google Scholar 

  9. D. J. Darensbourg and R. A. Kudaroski, Adv. Organomet. Chem. 22, 129 (1983). (b) D. A. Palmer and R Van Eldik, Chem. Rev. 83, 651 (1983). (c) D. Walter, Coord. Chem. Rev. 79, 135 (1987). (d) A. Behr Angew. Chem. Int. Engl. Ed. 27, 661 (1989).

    Google Scholar 

  10. D. A. Palmer and R Van Eldik, Chem. Rev. 83, 651 (1983).

    Google Scholar 

  11. D. Walter, Coord. Chem. Rev. 79, 135 (1987).

    Google Scholar 

  12. A. Behr Angew. Chem. Int. Engl. Ed. 27, 661 (1989).

    Google Scholar 

  13. D. J. Darensbourg and C. Ovalles, J. Am. Chem. Soc. 106, 3750 (1984).

    Article  CAS  Google Scholar 

  14. D. J. Darensbourg, R L. Gray, C. Ovalles, and M. Pala J. Mol. Catal., 29, 285 (1985).

    Article  CAS  Google Scholar 

  15. D. J. Darensbourg, R. L. Gray, and C. Ovalles, J. Mol. Catal. 41, 329 (1987).

    Article  CAS  Google Scholar 

  16. D. J. Darensbourg and G. Gibson, in: “Experimental Organometallic Chemistry”, A. L. Wayda and M. Y. Darensbourg, Eds., American Chemical Society, Washington, D. C. (1987).

    Google Scholar 

  17. D. J. Darensbourg, C. Ovalles, and M. Pala, J, Am. Chem. Soc. 105, 5937 (1983).

    Article  CAS  Google Scholar 

  18. D. J. Darensbourg, M. Pala, and J. Waller, Organometallics 2, 1285 (1983).

    Article  CAS  Google Scholar 

  19. G. R Steinmetz, A. D. Harley, and G. L. Geoffroy, Inorg. Chem. 19, 2985 (1980).

    Article  CAS  Google Scholar 

  20. J. C. Bricker, C. C. Nagel, A. A. Bhattacharyya, and S. G. Shore J. Am. Chem. Soc. 107, 377 (1985).

    Article  CAS  Google Scholar 

  21. D. J.Darensbourg, M.Y. Darensbourg, L. Y. Goh, M. Ludvig, and P. Wiegreffe, J. Am. Chem. Soc., 109, 7539 (1987).

    Google Scholar 

  22. D. J. Darensbourg and P. Wiegreffe, unpublished results.

    Google Scholar 

  23. D. J. Darensbourg and H. Pickner, Inorg. Chem., in press.

    Google Scholar 

  24. D. J. Darensbourg, R. L. Gray, and M. Pala, Organometallics, 1984, 3, 1928.

    Article  CAS  Google Scholar 

  25. D. C. Gross and P. C. Ford, Inorg, Chem. 21, 1702 (1982).

    Article  CAS  Google Scholar 

  26. D. J. Darensbourg, C. Ovalles, C. G. Bauch Rev. Inorg. Chem., 7, 315 (1985).

    CAS  Google Scholar 

  27. D. J. Darensbourg and C. Ovalles Inorg. Chem.. 25, 1603 (1986).

    CAS  Google Scholar 

  28. V. L. Kuznetsov and A. T. Bell, J. Catal., 68, 374, (1980).

    Article  Google Scholar 

  29. D. J. Darensbourg and D. J. Mangold, unpublished results.

    Google Scholar 

  30. J. G. Goodwin and C. Naccache, J. Mol. Cat. 14, 259 (1982).

    Article  CAS  Google Scholar 

  31. T. Bein and P. A. Jacobs, J. Chem. Soc., Faraday Trans., 79, 1819 (1983).

    Article  CAS  Google Scholar 

  32. N. Henon G. D. Stucky, C. A. Tolman Inorg. Chim. Acta. 100, 135 (1985).

    Google Scholar 

  33. D. J. Darensbourg and G. Gibson, unpublished results.

    Google Scholar 

  34. J. J. Verdonck, P. A. Jacobs, M. Genet, and G. Poncelet, J. Chem. Soc. Faraday I. 76, 403 (1980).

    Google Scholar 

  35. L. A. Pederson and J. H. Lunsford, J. Catal. 61, 39 (1980).

    Article  Google Scholar 

  36. B. Denise and R P. A. Sneeden, Chemtech. 108 (1982).

    Google Scholar 

  37. D. J. Darensbourg and Melissa Wagner, unpublished results.

    Google Scholar 

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Darensbourg, D.J. (1990). Uses of Metal Clusters in Homogeneous and Heterogeneous Catalysis. In: Fackler, J.P. (eds) Metal-Metal Bonds and Clusters in Chemistry and Catalysis. Industry-University Cooperative Chemistry Program Symposia. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-2492-6_4

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  • DOI: https://doi.org/10.1007/978-1-4899-2492-6_4

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