Abstract
The ammonium salt of the anion [FeW17O56F6H5]8− has been isolated in the crystalline form. Chemical analysis, FABMS, visible and FTIR spectroscopy indicate that the anion has the Dawson structure with one of the W+6 in the original 2:18 replaced by Fe+3 ion. The anion appears to be isomorphous with that reported by Baker et al in the Third Chemical Congress of North America, June 5–10, 1988, [ZnW17O56H4NaF6]9−. Single crystal structure study is now underway.
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© 1990 Springer Science+Business Media New York
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Wasfi, S.H. (1990). The Preparation and Characterization of New Heteropolyoxofluorometalate Anion, [FeW17O56F6H5]8− . In: Fackler, J.P. (eds) Metal-Metal Bonds and Clusters in Chemistry and Catalysis. Industry-University Cooperative Chemistry Program Symposia. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-2492-6_22
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DOI: https://doi.org/10.1007/978-1-4899-2492-6_22
Publisher Name: Springer, Boston, MA
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Online ISBN: 978-1-4899-2492-6
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