Abstract
A lot can happen in twenty five years. Actually, the roots of my work on metal-metal multiple bonds go back even more than twenty five years. As early as the late 1950’s I wondered about how many instances of definite, confirmed M-M bonds (even single ones) were to be found in the literature. Very few, I quickly discovered. I then wondered whether it would make sense to seek out more. However, it was not until I had acquired the knowledge and equipment necessary for X-ray crystallography that I could actually embark on such a program. It also happened that chance favored a prepared mind. Although I undertook a structural study of “CsReCl4,” without anticipating that it would turn out to be Cs3[Re3Cl12], the interpretation of that structure in terms of metal-metal bonds, but particularly double bonds, was almost automatic to me.1
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References
J. A. Bertrand, F. A. Cotton and W. A. Dollase, J. Am. Chem. Soc., 1963, 85, 1349.
F. A. Cotton and R. A. Walton, Multiple Bonds Between Metal Atoms, John Wiley & Sons, New York, 1982, pp 4 et seq.
E. Peligot, C. R. Acad. Sci., 1844, 19, 609; Ann. Chim. Phys., 1844, 12, 528.
E. W. Abel, A. Singh and G. Wilkinson, J. Chem. Soc., 1959, 3097; T. A. Stephenson, E. Bannister and G. Wilkinson J. Chem. Soc., 1964, 2538.
D. A. Edwards and G. W. A. Fowles, J. Less-Common Metals, 1962, 4, 512.
M. Blondel, Ann. Chim. Phvs., 1905, 8, 110.
J. D. Eakins, D. G. Humphreys and C. E. Mellish, J. Chem. Soc., 1963, 6012.
V. G. Tronev and S. M. Bondin, Dokl. Akad. Nauk SSSR, 1952, 86, 87.
F. A. Cotton, S. A. Koch and M. Millar, J. Am. Chem. Soc., 1977, 99, 7273.
See R. D. Davy and M. B. Hall, J. Am. Chem. Soc., 1989, 111, 1268 for the most recent calculations.
F. A. Cotton and R. Poli, Inorg. Chem., 1987, 26, 3652.
F. A. Cotton and R. Poli, Polyhedron, 1987, 6, 1625.
F. A. Cotton, M. P. Diebold and W. J. Roth, J. Am. Chem. Soc., 1987, 109, 5506.
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Cotton, F.A. (1990). A Quarter-Century of Metal-Metal Multiple Bonds. In: Fackler, J.P. (eds) Metal-Metal Bonds and Clusters in Chemistry and Catalysis. Industry-University Cooperative Chemistry Program Symposia. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-2492-6_1
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