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The Metal—Nonmetal Bond in the Solid State

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Part of the book series: Modern Inorganic Chemistry ((MICE))

Abstract

Undoubtedly, the most useful tools for understanding chemical bonds in molecules or solids are those that serve to correlate the wealth of structural and physical data known to chemists. This means that the Zintl concept and the simple ideas of the electron pair bond handed down by Lewis, Pauling and others will and should have a prominent role in the way chemists think about chemical bonds. Bearing this in mind our discussion below will begin with a review of the kinds of solid state compounds that can be best understood with the Zintl viewpoint.

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References

  1. Schäfer, H.; Eisenmann, B.; Müller, W. Angew. Chem., Int. Ed. Engl. 1973, 12, 694.

    Article  Google Scholar 

  2. Schäfer, H. Ann. Rev. Mater. Sci. 1985, 15, 1.

    Article  ADS  Google Scholar 

  3. Wells, A. F. “Structural Inorganic Chemistry,” 5th; Oxford: New York, 1984.

    Google Scholar 

  4. Braun, P.J.; Jeitschko, W. Z Anorg. Allg. Chem. 1978, 445, 157.

    Article  Google Scholar 

  5. Jeitschko, W.; Braun, P. J. Acta Crystallogr. 1978, B34, 3196.

    Article  Google Scholar 

  6. Krebs, H.; Müller, K.-H.; Zura, G.Z. Anorg. Allg. Chem. 1956, 285, 15.

    Article  Google Scholar 

  7. King, R.B. Inorg. Chem. 1989, 28, 3048.

    Article  Google Scholar 

  8. Sunshine, S.A.; Kang, D.; Ibers, J.A. J. Am. Chem. Soc. 1987, 109, 6202.

    Article  Google Scholar 

  9. Kang, D.; Ibers, J.A. Inorg. Chem. 1987, 27, 549.

    Article  Google Scholar 

  10. Kanatzidas, M.G. Chem. Mater. 1990, 2, 353.

    Article  Google Scholar 

  11. Burshka, C. Z Naturforsh. 1980, 35B, 1511.

    Google Scholar 

  12. Kanatzidas, M.G.; Park, Y. J. Am. Chem. Soc. 1990, 111, 3767.

    Article  Google Scholar 

  13. Ackermann, J.; Wold, A. J. Phys. Chem. Solids 1911, 38, 1013.

    Article  Google Scholar 

  14. Lutz, H.D.; Küche, G. Z. Anorg. Allg. Chem. 1981, 480, 105.

    Article  Google Scholar 

  15. Küche, G.; Lutz, H.D. Infrared Phys. 1984, 24, 171.

    Article  Google Scholar 

  16. Küche, G.; Bauhofer, W. Mater. Res. Bull. 1987, 22, 551.

    Article  Google Scholar 

  17. Küche, G.; Bauhofer, W. J. Phys. Chem. Solids 1988, 49, 267.

    Article  Google Scholar 

  18. Korenstein, R.; Soled, S.; Wold, A.; Collin, G. Inorg. Chem. 1977, 16, 1977.

    Article  Google Scholar 

  19. Kjekshus, A.; Rakke, T. Acta Chem. Scand. 1974, A28, 99.

    Article  Google Scholar 

  20. Braun, D.J.; Jeitschko, W. J. Less-Common Met. 1980, 72, 147.

    Article  Google Scholar 

  21. Braun, D.J.; Jeitschko, W. J. Solid State Chem. 1980, 32, 357.

    Article  ADS  Google Scholar 

  22. Jeitschko, W.; Braun, D. Acta Crystallogr. 1977, B33, 3401.

    Google Scholar 

  23. Boonk, L.; Jeitschko, W.; Scholz, U.D.; Braun, D.J. Z. Kristallogr. 1987, 178, 30.

    Google Scholar 

  24. Stetson, N. T.; Kauzlarich, S. M., J. Solid State Chem., in press.

    Google Scholar 

  25. Jung, D.; Whangbo, M.-H.; Alvarez, S. Inorg. Chem. 1990, 29, 2252.

    Article  Google Scholar 

  26. DeLong, L.E.; Meisner, G.P. Solid State Commun. 1985, 53, 119.

    Article  ADS  Google Scholar 

  27. Yamane, H.; Kikkawa, S.; Koizumu, M. J. Solid State Chem. 1987, 71, 1.

    Article  ADS  Google Scholar 

  28. Yamane, H.; Kikkawa, S.; Horiuchi, H.; Koizumu, M. J. Solid State Chem. 1986, 65, 6.

    Article  ADS  Google Scholar 

  29. Evers, J.; Munsterkotter, M.; Oehünger, G.; Polborn, K.; Sendünger, B. J. Less-Common Metals. 1990, 162, L17.

    Article  Google Scholar 

  30. Chern, M.Y.; DiSalvo, F.J. J. Solid State Chem. 1990, 88, 528.

    Article  ADS  Google Scholar 

  31. Ennos, D.A.; Badding, M.E.; DiSalvo, F.J. Inorg. Chem. 1990, 29, 4059.

    Article  Google Scholar 

  32. Ordier, G.; Höhn, P.; Kniep, R.; Rabenau, A.Z. Anorg. Allg. Chem. 1990, 591, 58.

    Article  Google Scholar 

  33. Gerss, M. H.; Jeitschko, W. Z. Naturforsch. 1986, 41b, 946.

    Google Scholar 

  34. Chern, M.Y.; Disalvo, F.J. J. Solid State Chem 1990, 88, 459.

    Article  ADS  Google Scholar 

  35. Hoffmann, R.; Li, J.; Wheeler, R. J. Am. Chem. Soc. 1987, 109, 6600.

    Article  Google Scholar 

  36. Jacobs, H.; Pinkowski, E.V. J. Less-Common Met. 1989, 146, 147.

    Article  Google Scholar 

  37. Herrmann, W.A. Angew. Chem., Int. Ed. Engl. 1986, 25, 56.

    Article  Google Scholar 

  38. Huttner, G.; Weber, U.; Sigwarth, B.; Scheidsteger, O.; Lang, H.; Zsolnai, L. J. Organomet. Chem. 1985, 282, 331.

    Article  Google Scholar 

  39. Strube, A.; Huttner, G.; Zsolnai, L. Angew. Chem., Int. Ed. Engl. 1988, 27, 1529.

    Article  Google Scholar 

  40. Kostic, N.M.; Fenske, R.F. J. Organomet. Chem. 1982, 233, 337.

    Article  Google Scholar 

  41. The majority of the work discussed here has emerged from Corbett’s laboratories. For a more complete review, see: Hughbanks, T. Prog. Solid State Chem. 1989, 19, 329.

    Article  Google Scholar 

  42. Simon, A. J. Solid State Chem. 1985, 57, 2.

    Article  ADS  Google Scholar 

  43. Simon, A. Agnew. Chem., Int. Ed. Engl. 1988, 27, 160.

    Google Scholar 

  44. Vaughan, P.A.; Sturtivant, J.H.; Pauling, L. J. Am. Chem. Soc. 1950, 72, 5477.

    Article  Google Scholar 

  45. Cotton, F.A.; Haas, T.E. Inorg. Chem. 1964, 3, 10.

    Article  Google Scholar 

  46. Bursten, B.E.; Cotton, F.A.; Stanley, G.G. Isr. J. Chem. 1980, 19, 132.

    Google Scholar 

  47. Wooley, R.G. Inorg. Chem. 1985, 24, 3519.

    Article  Google Scholar 

  48. Klendworth, D.D.; Walton, R.A. Inorg. Chem. 1981, 20, 1151.

    Article  Google Scholar 

  49. Mackay, R.A.; Schneider, R.F. Inorg. Chem. 1967, 6, 549.

    Article  Google Scholar 

  50. Chu, P.J.; Ziebarth, R.P.; Corbett, J.D.; Gerstein, B.C. J. Am. Chem. Soc. 1988, 110, 5324.

    Article  Google Scholar 

  51. Payne, M.; Dorhaut, P.; Corbett, J. D., personal communication.

    Google Scholar 

  52. Goldschmidt, H. J. “Interstitial Alloys”; Butterworths: London, 1967.

    Google Scholar 

  53. Franzen, H.F.; Smeggil, J.G. Acta Crystallogr., Sect. B 1970, 26, 125.

    Article  Google Scholar 

  54. Harbrecht, B. J. Less Common Met. 1988, 138, 225.

    Article  Google Scholar 

  55. Wada, H.; Onoda, M. Mater. Res. Bull. 1989, 24, 191.

    Article  Google Scholar 

  56. Kim, S.-J.; Nanjundaswamy, K.S.; Hughbanks, T. Inorg. Chem. 1991, 30, 159.

    Article  Google Scholar 

  57. Li, J.; Hoffmann, R.; Badding, M.E.; DiSalvo, F.J. Inorg. Chem. 1990, 29, 3943.

    Article  Google Scholar 

  58. Badding, M.E.; DiSalvo, F.J. Inorg. Chem. 1990, 29, 3952.

    Article  Google Scholar 

  59. Harbrecht, B.; Franzen, H.F. J. Less-Common Met. 1985, 113, 349.

    Article  Google Scholar 

  60. Harbrecht, B. J. Less-Common Met. 1986, 124, 125.

    Article  Google Scholar 

  61. Harbrecht, B. J. Less-Common Met. 1988, 141, 59.

    Article  Google Scholar 

  62. Franzen, H.F.; Smeggil, J.G. Acta Crystallogr., Sect. B 1969, 25, 1736.

    Article  Google Scholar 

  63. Pauling, L. “The Nature of the Chemical Bond;” 3, Cornell University Press: Ithaca, New York, 1960.

    Google Scholar 

  64. Corbett, J.D. J. Solid State Chem. 1981, 39, 56.

    Article  ADS  Google Scholar 

  65. Chevrel, R. In “Crystal Chemistry and Properties of Materials with Quasi-One-Dimensional Structures”; Rouxel, J., Ed.; Reidei: New York, 1986.

    Google Scholar 

  66. Adolphson, D.G.; Corbett, J.D. Inorg. Chem. 1976, 15, 1820.

    Article  Google Scholar 

  67. Torardi, C.C.; McCarley, R.E. J. Am. Chem. Soc. 1979, 101, 1963.

    Article  Google Scholar 

  68. Torardi, C.C.; McCarley, R.E. Inorg. Chem. 1985, 24, 476.

    Article  Google Scholar 

  69. McCarley, R.E. Polyhedron 1986, 5, 51.

    Article  Google Scholar 

  70. Lokken, D.A.; Corbett, J.D. Inorg. Chem. 1973, 12, 556.

    Article  Google Scholar 

  71. Harbrecht, B.V. Angew. Chem., Int. Ed. Engl. 1989, 28, 1660.

    Article  Google Scholar 

  72. Conard, B. R.; Norrby, L. J.; Franzen, H. F. Acta Crystallogr. 1969, B25, 1729.

    Google Scholar 

  73. Nanjundaswamy, K. S.; Hughbanks, T., unpublished research.

    Google Scholar 

  74. Franzen, H. F., personal communication.

    Google Scholar 

  75. Harbrecht, B.U.; Schmidt, S.R.; Franzen, H.F. J. Solid State Chem. 1984, 53, 113.

    Article  ADS  Google Scholar 

  76. Aronsson, B. Acta Chem. Scand. 1955, 9, 1107.

    Article  Google Scholar 

  77. Horyn, R.; Lukaszewicz, K. Bull. Acad. Pol. Sci., Ser. Sci. Chim. 1970, 18, 59.

    Google Scholar 

  78. Ukei, K.; Shishido, T.; Fukuda, T. Acta Crystallogr. 1989, C45, 349.

    Google Scholar 

  79. A book that contains some of the best illustrations for intermetallic compounds is: Pearson, W. B. “The Crystal Chemistry and Physics of Metals and Alloys”; Wiley-Interscience: New York, 1972.

    Google Scholar 

  80. For a valuable compilation of data for intermetallics up to the mid-1980s, see: Villars, P.; Calvert, L. D. “Pearson’s Handbook of Crystallographic Data for Intermetallic Phases”; American Society for Metals: Metals Park, Ohio, 1985.

    Google Scholar 

  81. For a derivation of pseudopotential radii, see: Zunger, A. In “Structure and Bonding in Crystals;” O’Keeffe, M., Navrotsky, A., Eds.; Academic Press: New York, 1981, and references cited therein.

    Google Scholar 

  82. A structure map example can be found in: Villars, P. J. Less-Common Met. 1983, 92, 215.

    Article  Google Scholar 

  83. For examples, see: Hoffmann, R. “Solids and Surfaces”; VCH Publishers Inc.: New York, 1988.

    Google Scholar 

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Hughbanks, T. (1992). The Metal—Nonmetal Bond in the Solid State. In: Fehlner, T.P. (eds) Inorganometallic Chemistry. Modern Inorganic Chemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-2459-9_7

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  • DOI: https://doi.org/10.1007/978-1-4899-2459-9_7

  • Publisher Name: Springer, Boston, MA

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