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Molecular Organization in Amphiphilic Aggregates

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Surfactants in Solution

Abstract

Molecular organization within the hydrocarbon cores of micelles, bilayers, and other amphiphilic aggregates depends on i) intramolecular structure: the continuity and flexibility of the chains, and ii) the balance of intermolecular forces. Attractive exchange interactions are responsible for the differential solubilities of polar heads and hydrocarbon tails in water, But dispersion forces among aliphatic hydrocarbons are isotropic; steric repulsive forces are required to induce the anisotropy responsible for internal structure,

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Author notes

  1. Ken A. Dill

    Present address: Departments of Pharmaceutical Chemistry and Pharmacy, University of California, San Francisco, California, 94143, USA

Authors and Affiliations

  1. Department of Chemistry, University of Florida, Gainesville, Florida, 32611, USA

    Ken A. Dill

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  1. Ken A. Dill
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Editor information

Editors and Affiliations

  1. Hopewell Junction, IBM Corporation, New York, USA

    K. L. Mittal

  2. University of Lund, Lund, Sweden

    B. Lindman

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Dill, K.A. (1984). Molecular Organization in Amphiphilic Aggregates. In: Mittal, K.L., Lindman, B. (eds) Surfactants in Solution. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-2280-9_19

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  • DOI: https://doi.org/10.1007/978-1-4899-2280-9_19

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4899-2282-3

  • Online ISBN: 978-1-4899-2280-9

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