Abstract
The iodide ion is large and polarizable; the Cu+ and Ag+ ions are quadrupolarizable because they have spherical d10 cores that may be transformed to ellipsoidal shape by energetically accessible, intraatomic d-s hybridization. Consequently the effective Rexcl is particularly softened, and even the simple salts exhibit transitions to fast ionic conduction at a Tt below the melting point Tm.
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References
J. B. Boyce, T. M. Hayes, and J. C. Mikkelson, Jr., Phys. Rev. B23, 2876 (1981).
W. Schröter and J. Nölting, J. Phys. (Paris) 41: C6, 20 (1980).
M. Schultz, Proc. 2nd European Conf. Solid State Chemistry, Eindhoven Univ. of Technology, 7–9 June 1982.
M. O’Keefe and B. G. Hyde, J. Solid State Chem. 13, 172 (1975).
T. Takahashi, H. Iwahara, and T. Esaka, J. Electrochem. Soc. 124, 1563 (1977).
J. E. Ruiz-Diaz, D. Phil. Thesis, University of Oxford (1985).
U. Von Alpen, A. Rabenau, and G. M. Talat, Appl. Phys. Lett. 30, 621 (1977).
H. Schulz and K. H. Thiemann, Act. Cryst. A35, 309 (1978); H. Schulz, Ann. Rev. Materials Science 12, 351 (1982).
D. Brinkmann, M. Mali, and J. Roos, Phys. Rev. B26, 4810 (1982).
H. Y-P Hong, J. A. Kafalas, and J. B. Goodenough, J. Solid State Chem. 9, 345 (1974).
G. V. Chandrashekar and L. M. Foster, J. Electrochem. Soc. 124, 329 (1977).
J. B. Goodenough, H. Y-P Hong, and J. A. Kafalas, Mat. Res. Bull., 11, 203 (1976).
P. Spiegelberg, Ark. Kemi 14A, 1 (1940).
W. L. Roth, F. Reidinger, and S. La Placa, in Superionic Conductors, G. D. Mahan and W. L. Roth, eds. ( Plenum Press, N. Y. 1976 ), p. 223.
R. A. Huggins, in Defects and Transport in Oxides, M. S. Seltzer and R. I. Jaffee, eds. ( Plenum Press, N. Y. 1974 ), p. 549.
L. O. Hagman and P. Kierkegaard, Acta. Chem. Scand. 22, 1822 (1968).
R. E. Zizova, A. A. Voronkov, N. G. Shumyatskaya, V. V. Ilyukhin, and N. V. Belov, Sov. Phys. Dokl. 17, 618 (1973).
R. D. Shannon, B. E. Taylor, A. D. English, and T. Berzins, Electrochim. Acta. 22, 783 (1977).
H. Y-P Hong, Adv. Chem. Ser. 163, 179 (1977).
R. D. Shannon, H. Y. Chen, and T. Berzins, Mat. Res. Bull. 12, 969 (1977).
H. V. Beyeler and T. Hibma, Solid State Comm. 27, 641 (1978).
H. Y-P. Hong, J. A. Kafalas, and M. Bayard, Mat. Res. Bull, 13, 757 (1978).
B. A. Maksimov, Yu. A. Kharitonov, and N. V. Belov, Sov. Phys. Dokl. 18, 763 (1974).
B. A. Maximov, I. V. Petrov, A. Rabenau, and H. Schultz, Solid State Ionics 5, 311 (1982).
C. Delmas, A. Maazog, C. FouasSier, J. M. Réau, and P. Hagenmuller, in Fast Ionic Transport in Solids. Vashista, Mundy, and Shenoy, eds. ( Elsevier, North Holland, 1979 ) p. 451.
W. A. England, M. G. Cross, A. Hammett, P. J. Wiseman, and J. B. Goodenough, Solid State Ionics 1, 231 (1980).
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Goodenough, J.B. (1990). Designing a Solid Electrolyte II. Strategies and Illustrations. In: Akridge, J.R., Balkanski, M. (eds) Solid State Microbatteries. NATO ASI Series, vol 217. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-2263-2_9
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