Abstract
The series of structurally ordered bimetallic chains formulated as MM′ (EDTA).6H2O, in short (MM′), provides the most versatile known example of 1-dimensional ferrimagnets, since on the same structural support many different magnetic ions (Mn, Co, Ni and Cu(II)) can be selectively accommodated.1 Consequently, many choices of alternating magnetic moments with Heisenberg or Ising exchange couplings can be investigated. Moreover, taking into account that the M-M′ distances along the chain are alternating, this series could show at the same time an alternation of the exchange parameter2.
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References
C.P. Landee, Insulating Magnetic Chains: Recent Models and Materials, in this book, and references therein.
E. Coronado, M. Drillon, A. Fuertes, D. Beltrán, A. Mosset and J. Galy, Structural and Magnetic Study of Ni2(EDTA) (H2O)4. 2H2O. Alternating Landé Factors in a Two-Sublattice 1D System, J.Am.Chem.Soc. 108:900 (1986)
M. Drillon, E. Coronado, D. Beltrán and R. Georges, Ferrimagnetic Heisenberg Chain. Influence of a Random Exchange Interaction, J.Appl.Phys. 57:3353 (1985).
E. Coronado, M. Drillon, P.R. Nugteren, L.J. de Jongh and D. Beltrán, Anisotropic Exchange in The CO2(EDTA)6H2O and CoCu(EDTA) 6H2O Bimetallic Ordered Chains; Low Temperature Investigation of The Thermal and Magnetic Properties, submitted to J.Am.Chem.Soc..
M. Drillon, E. Coronado, D. Beltrán, J. Curely, R. Georges, P.R. Nugteren, L.J. de Jongh and J.L. Genicon, J.Mag.Mag.Mater. 54-57:1507 (1986).
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© 1987 Springer Science+Business Media New York
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Coronado, E., Nugteren, P.R., Drillon, M., Beltrán, D., de Jongh, L.J., Georges, R. (1987). Low Temperature Investigation of the Thermal and Magnetic Properties of 1-d Ferrimagnetic Systems. In: Delhaes, P., Drillon, M. (eds) Organic and Inorganic Low-Dimensional Crystalline Materials. NATO ASI Series, vol 168. Springer, New York, NY. https://doi.org/10.1007/978-1-4899-2091-1_47
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DOI: https://doi.org/10.1007/978-1-4899-2091-1_47
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