Abstract
The intention of the present study is to investigate the coordination chemistry and the magnetic and conducting properties of polynuclear coordination compounds containing 1,2-dithiolenes. DMIT-based (H2DMIT =4,5-dimercapto-1, 3-dithiol-2-thione) complexes have become of particular interest since the discovery of superconductivity in (TTF)[Ni(DMIT)2]21. With DMIT and related ligands square planar compounds are obtained for M = Ni, Cu, Pd and Pt, see Figure 1.
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Groeneveld, L.R., Kramer, G.J., von Marinelli, T.B.L.W., Brom, H.B., Haasnoot, J.G., Reedijk, J. (1987). Counter-Ion Influences on the Electrical Conduction Properties of 1,2-Dithiolene Coordination Compounds. In: Delhaes, P., Drillon, M. (eds) Organic and Inorganic Low-Dimensional Crystalline Materials. NATO ASI Series, vol 168. Springer, New York, NY. https://doi.org/10.1007/978-1-4899-2091-1_33
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DOI: https://doi.org/10.1007/978-1-4899-2091-1_33
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