Abstract
The intercalation of graphite with various alkali metal and rare-earth oxides has been well characterized [1]. However, the synthesis of organic intercalates of graphite has, up to now, been limited to solvent inclusion of small-ring systems. Reported here are the first intercalates of graphite with large aromatic ring systems that are used to form organic metals.
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References
M. S. Whittingham and A. Jacobson, Editors, “Intercalation Chemistry” (Academic Press, New York, 1982) pages 31, 44.
K. Chatakondu, M. Green, M. Thompson, and K. Suslick, The enhancement of intercalation reactions by ultrasound, J. Chem. Soc. Chem. Commun. 900 (1987).
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Sutto, T.E., Averill, B.A. (1990). Synthesis, Structural Characterization, and Conductivity of the First Large Organic Electron Intercalates of Graphite. In: Metzger, R.M., Day, P., Papavassiliou, G.C. (eds) Lower-Dimensional Systems and Molecular Electronics. NATO ASI Series, vol 248. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-2088-1_31
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DOI: https://doi.org/10.1007/978-1-4899-2088-1_31
Publisher Name: Springer, Boston, MA
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