Abstract
In condensed-phase molecular systems, and particularly insulating molecular crystals, infrared and Raman spectroscopies are well-established tools for investigating molecular and crystalline structural properties.1 On the other hand, in inorganic semiconductors and metals the same spectroscopic methods are widely used to evaluate electronic band structure parameters.2 Organic charge transfer (CT) crystals, as molecular conductors and semiconductors, share some properties of both the above classes of solids, and, therefore, new spectroscopic phenomena are expected, and indeed observed for these materials.3
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Bozio, R., Feis, A., Pedron, D., Zanon, I., Pecile, C. (1990). Structural Properties of Molecular Charge-Transfer Conductors and Semiconductors from Infrared and Raman Spectroscopy. In: Metzger, R.M., Day, P., Papavassiliou, G.C. (eds) Lower-Dimensional Systems and Molecular Electronics. NATO ASI Series, vol 248. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-2088-1_2
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