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Nature of Adhesion Through Silane Coupling Agents

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Silane Coupling Agents

Abstract

Most thermosetting polymers undergo some shrinkage during cure. This may range from 6 to 10% for polyesters to 3 to 4% for epoxies. Such shrinkage in the presence of fillers or reinforcements sets up stresses at the polymer-resin interface. Bush1 embedded strain gauge transducers in a polyester resin cured at 120°C and measured internal static pressures of 14 to 21 MPa (2000–3000 psi). Bulk mold shrinkage may be reduced to less than 1% by loading the polymer with particulate fillers, but interfacial stresses are merely transferred to the filler surfaces.

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Authors and Affiliations

  1. Dow Corning Corporation, Midland, Michigan, USA

    Edwin P. Plueddemann (Scientist Emeritus)

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  1. Edwin P. Plueddemann
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© 1991 Springer Science+Business Media New York

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Plueddemann, E.P. (1991). Nature of Adhesion Through Silane Coupling Agents. In: Silane Coupling Agents. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-2070-6_5

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  • DOI: https://doi.org/10.1007/978-1-4899-2070-6_5

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4899-2072-0

  • Online ISBN: 978-1-4899-2070-6

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