Abstract
Compatibility of two- and threecomponent systems of poly(vinyl chloride) with homo- and copolymers of methyl methacrylate and butyl methacrylate has been studied. The mixtures were tested for compatibility in the dynamic viscosity of polymer solutions, in microscopic observations in polarized light, as well as by dynamic mechanical measurements. It was found that poly(methyl methacrylate) and methacrylic copolymers were compatible with PVC. Poly(butyl methacrylate) appears to be incompatible with PVC. Estimation of solubility parameter values δ made it possible to predict the compatibility of polymer pairs. Critical Δδ value for compatible polymers has been found to be 0.5 (cal cm−3) 1/2.
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References
G. L. Slonimski, J.Polymer Sci., 30: 625 (1958).
L. Bohn, Kolloid-Z., 213: 55 (1966).
K. Friese, Plaste u. Kautsch., 12:90 (1965); 13:65 (1966); 15: 646 (1968)
J. A. Manson, L.H. Sperling “Polymer Blends and Composites”, Plenum, New York (1976).
S. Krause, J. Macromol.Sci., C7: 251 (1972).
M. Shen, H. Kawai, AIChE J., 24: 1 (1978).
D. R. Paul, S. Newman Polymer Blends“, Academic Press, New York (1978).
R. Koningsveld, R.F.T. Stepto, Macromol., 10: 1166 (1977). 97
L. P. Mc Master, ibid., 6: 760 (1973).
D. Patterson, A. Robard, ibid., 11: 690 (1978).
P. J. Flory “Principles of Polymer Chemistry”, Cornell University Press, Ithaca (1953).
R. L. Scott, J.Chem.Phys., 17: 279 (1949).
Adv.Chem.Ser., N° 99 (1972).
B. D. Gesner, Apyl.Polymer Symp., 7: 53 (1968).
R. J. Kern, J.Polymer Sci., 21: 19 (1956).
H. Morawetz, F. Amrani, Macromol., 11: 281 (1978).
J. Stoelting, F.E. Karasz, W.J. McKnight, Po1ym,En.Sci., 10: 133 (1970).
K. Kato, Polymer Letters, 4: 35 (1966).
T. Hashimoto, K. Nagatschi, A. Todo, H. Hasegawa, H. Kawai, Macromol., 7: 364 (1974).
G. Gee, Trans.Faraday Soc., 38: 418 (1942).
J. Zelinger, V. Heidingsfeld, Sb.Vys.Sk,Chem.Technol.Praze Or1.Technol., 9: 63 (1966).
M. Rusu, D. Feldmann, Mater.Plastice, 12: 146 (1975).
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© 1984 Springer Science+Business Media New York
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Kozłowski, M., Skowroński, T. (1984). Compatibility of PVC-Polymethacrylate Systems. In: Kryszewski, M., Gałęski, A., Martuscelli, E. (eds) Polymer Blends. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-1831-4_8
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DOI: https://doi.org/10.1007/978-1-4899-1831-4_8
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