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Ligand Exchange Reactions of Inert-Metal Complexes—Coordination Numbers 4 and 5

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Mechanisms of Inorganic and Organometallic Reactions

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Abstract

Two reviews by F. Basolo make interesting reading. Both are retrospective, and center mainly on work carried out by the author and his co-workers. One deals with conventional ligand substitutions.(1) the other with substitution reactions of carbonyl and nitrosyl complexes,(2) and both contain material on four- and five-coordinate compounds. A review by R. Romeo on dissociative reaction pathways in platinum(II) chemistry takes the form of a useful compilation of the various reaction types which might lead to three-coordinate 14-electron species. These include β-eliminations and various insertion reactions as well as ligand replacements and isomerizations.(3)

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  1. Johnson Matthey, Royston, Hertfordshire, England

    M. V. Twigg

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    M. V. Twigg

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Twigg, M.V. (1994). Ligand Exchange Reactions of Inert-Metal Complexes—Coordination Numbers 4 and 5. In: Twigg, M.V. (eds) Mechanisms of Inorganic and Organometallic Reactions. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-1624-2_5

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  • DOI: https://doi.org/10.1007/978-1-4899-1624-2_5

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