Abstract
Asphaltene represents the most refractory fraction of petroleum liquids. It is defined by the solubility in alkyl solvents, such as pentane or heptane [1,2]. For example, heptane asphaltene is defined as the fraction in the petroleum liquid that is insoluble in heptane but soluble in toluene.
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References
J. G. Speight, The chemistry and Technology of Petroleum. Marcel Dekker, New York, (1980).
J. G. Speight, Fuel Science and Technology Handbook. Marcel Dekker, New York 1193 pp (1990).
T.F. Yen, “The role of asphaltene in heavy crude and tar sands.” In: R.F. Meyer and C.T. Steele (Editors), The Future of Heavy Crude and Tar Sands, McGral-Hill, New York, pp 174–179 (1980).
R. S. Sanders, R. S. Chow and J. H. Masliyah, J. Coll. Int. Sci., 174, 230 (1995).
J. Escobedo and G. A. Mansoori, SPE 23696, paper presented at the Second Latin American Petroleum Engineering Conference, II LAPEC of the SPE held in Caracas, Venezuela, March 8-11 (1992).
G. A. Mansoori, T. S. Jiang, and S. Kawanaka, Arabian J. Sci. & Eng., 13, 17 (1988).
J. H. Pfeiffer, The Properties of Asphaltic Bitumen. Elsevier, Amsterdam, 285 pp. (1950).
J.W. Bunger and N.C. Li, Chemistry of Asphaltenes. Advances in Chemistry Series 195. American Chemical Society, Washington D.C. (1981).
T.F. Yen and G.V. Chilingarian (editor) Asphaltenes and Asphaltes, 1, Eiservier, Amsterdam (1994).
M.K. Sharma and T.F. Yen (editors) Asphaltene Particles in Fossil Fuel Exploration, Recovery, Refining, and Production Processes, Plenum Press, New York (1994).
E. Y. Sheu and D. A. Storm, “Colloidal Properties of Asphaltenes in Organic Solvents” In Asphaltenes — Fundamentals and Applications, edited by E. Y. Sheu and O. C. Mullins, Plenum Press, New York (1995).
Marusk H. P., and Rao, B. M. L., Fuel Sci. & Tech. Int., 5(2) 119 (1987).
B. Shiffert, J. Kuczinski, and E. J. Papirer, J. Coll. Int. Sci., 135, 107 (1990).
Eric Y. Sheu and D. A. Storm, Energy & Fuel, 8, 552 (1994).
B. Tissor, Rev. Inst. Fr. Pet., 36(4), 429 (1981)
B. Tissot, D. H. Weite, Petroleum Formation and Occurrence; 2nd Ed., Spring Verlag, Berlin, pp 538 (1984).
F. J. Nellensteyn, Oxfor Univ. Press, London, 4, 2760 (1938).
J. P. Dickie and T. F. Yen, Analy. Chem., 39,(14)1847 (1967).
S. S. Pollack, and T. F. Yen, Analytical Chemistry, 42(6) 23 (1970).
T. F. Yen, Am. Chem. Soc, Div. Petrol. Chem. Preprint, 17(1): 102–104 (1972).
I. A. Eldib, H. N. Dunning and R. J. Bolen, J. Chemical & Eng. Data, 5(4) 550, 1960.
B. R. Ray, P. A. Witherspoon and R. E. Grim, J. Phys. Chem., 61, 1296 (1957).
T.F. Yen, Energy Source, 1(4): 447–463 (1974).
E.Y. Sheu, K.S. Liang, S.K. Sinha, and R.E. Overfield, J. Coll. Int. Sci., 153, 399 (1992).
F.J. Nellensteyn, Chem. Weekblad, 28, 313 (1931).
F. J. Nellensteyn and N. M. Roodenburg, Chem.-Zeiyung, 545, 819(1930).
C. Mack, Phys. Chem., 36, 2901 (1932).
J. P. Pfeiffer and R. N. J. Saal, J. Phys. Chem., 44, 139 (1940).
H. Eiler, Kolloid-ZZ. Polym., 97, 313 (1941).
E.Y. Sheu, D.A. Storm and M.M. De Tar, J. Non-crystal Sloids, 131-133, 347 (1991).
Xu, Yingnian; Koga, Yoshikata; Strausz, Otto P., Fuel, 74(7), 960–4 (1995).
L. Schramm, R. G. Smith, and J. A. Stone, Colloids and Surfaces, 11, 247 (1984).
S. Acevedo, M. A. Ranaudo, G. Escobar, L. Gutierrez and P. Ortega, Fuel, 74(4) 595 (1995).
E.M. Trujillo, Soc. Petro. Eng AIME, 645, Aug. (1983).
Y. Xu, Energy & Fuel, 9, 148 (1995).
K. C. Khulbe, G. H. Neale, and V Hornof, Fuel Proc. Tech., 19, 61 (1988).
H. A. Nasr-El-Din and K. C. Taylor, Colloid and Surfaces, A: 75, 169 (1993).
G. Gonzalez and A. Middea, Golloids and Surfaces, 33, 217(1988).
O. V. Rogacheva, R. N. Rimaev, V. Z. Gubaidullin, and D. K. Khakimov, Kolloidnyi Zhurnal, 42(3) 586 (1980).
E. Y Sheu, M. M. De Tar, D. A. Storm, and S. J. DeCanio, Fuel, 71, 299 (1992).
E.Y. Sheu, M.M. De Tar and D.A. Storm, “Surface Activity and Dynamics of Asphaltenes.” In: M.K. Sharma and T.F. Yen (editors) Asphaltene Particles in Fossil Fuel Exploration, Recovery, Refining, and Production Processes, 115 pp Plenum Press, New York (1994).
S.E. Taylor, Fuel, 71, 1338 (1992).
E.Y. Sheu and D.A. Storm, Fuel, 73, 1368 (1994).
K. C. Kyriacou, R. E. Baltus and P. Rahimi, Fuel, 67, 109 (1988).
R. E. Baltus, K. C. Kyriacou, V. V. Sivaramakrishna, and P. Rahimi, AICheE Symposium Series, No. 266, Vol. 84, 50(1988).
D. A. Storm and E. Y Sheu, Energy & Fuel, 9, 168 (1995).
C. W. Dwiggins Jr., J. Phys. Chem. 69, 3500, (1965).
C. W. Dwiggins Jr., J. Appl. Cryst. 11, 615,(1978).
S. I. Anderson and K. S. Birdi, J. Coll. Int. Sci., 142, 497 (1991).
P. Herzog, D. Tchoubar, and D. Espinat, Fuel, 67, 245 (1988).
J. C. Ravey, G. Ducouret, and D. Espinat, Fuel, 67, 1560 (1988).
Thiyagarajan, P.; Hunt, Jerry E.; Winans, Randall E.; Anderson, Ken B.; Miller, Jeffrey T., Energy & Fuels, 9(5), 829–33(1995).
I. Kowalewski, M. Vandenbroucke, A. Y Huc, M. J. Taylor, and J. L. Faulon, Energy & Fuel, 10, 97–107 (1996).
J. Murgich, J. Rodriguez, and Y Aray, Energy & Fuel, 10, 68–76 (1996).
L. A. Feigin and D. I. Svergun, Structure Analysis By Small Angle X-ray and Neutron Scattering, Plenum Press, New York (1987).
E.Y. Sheu, Phys. Rev. A., 45, 2428(1992).
G. Porod, “General Theory”, in O. Glatter and O. Kratky edited Small Angle X-ray Scattering, Academic Press, New York (1982).
P. Debye, Ann. Physik, 46, 809 (1915).
M. Borkovec, J. Chem. Phys., 91(19) 6268 (1989).
G. S. Grest, I. Webman, S. A. Safran and A. L. R. Bug, Phys. Rev. A 33, 2842 (1986).
H. E. Stanley and N. Ostrowsky eds, On Growth and Form, Martinus Nijhoff Publisher, New York (1986).
D. P. Landau and F. Family, Eds., Kinetics of Aggregation and Gelation, North Holland, Amsterdam, (1984).
R. Pynn and A. Skeltorp, Eds. Scaling Phenomena in Disordered System, Plenum New York (1986).
J. Feder, Fractal, Plenum, New York (1988).
T. Jøssang, J. Feder, and E. Rosenqvist, J. Chem. Phys. 120, 1–30, 1984.
J. Feder, T. Jossang, and E. Rosenqvist, Phys. Rev. Lett. 53, 1403, 1984.
D. Stauffer, in On Growth and Form, edited by H. E. Stanley and N. Ostrowsky, Martinus Nijhoff Publisher, New York (1986).
C. Y Ralston, S. Mitra-Kirtley and O. C. Mullins, Energy & Fuels, 10, 623 (1996).
Cerius2 is marketed by BIOSYM/Molecular Simulations Inc., 9685 Scarnton Road, San Diego, California, USA.
Mayo, S. L.; Olafson, B. D.; Goddard III, W. A. J. Phys. Chem. 1990, 94, 8897.
MOPAC6 is a semi empirical package available from Quantum Chemistry Program Exchange (QCPE), Indiana University.
CHARMm (Brooks, B. R.; Bruccoleri, R. E; Olafson, B. D.; States, D. J.; Swaminathan, S.; Karplus, M., J. Comput. Chem., 1983, 4, 187).
J. Peyerelasse and C. Boned, Phys. Rev. A 41, 938 (1990).
M. Lagure, J. Phys. Lett., 40, L331 (1979).
M. I. Clarkson, Phys. Rev. A. 37, 2079(1988).
S. K. Mehta et al., Phys. Rev. E., 50, 4759 (1994).
J. P. Straley, Phys. Rev. B 15, 5733 (1977).
I. Webman et al., Phys. Rev. B 16, 2593 (1977).
Y C. Liu, E. Y Sheu, S. H. Chen, and D. A. Storm, Fuel, 74, 1352 (1995).
Kusaka, I.; Wang, Z.-G.; Seinfeld, J. H., J. Chem. Phys., 103(20), 8993–9009, (1995).
V. E. Galtsev, I. M. Ametov and O. Y Grinberg, Fuel, 74(5) 670 (1995).
B. A. Watson and M. A. Barteau, Ind. Eng. Chem. Res., 33, 2358 (1994).
M. A. Anisimov, I. K. Yudin, V. Nikitin, G. Nikolaenko, A. Chernoutsan, H. Touhoat, D. Frot, and Y Briolant, J. Phys. Chem., 99, 9577 (1995).
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Sheu, E.Y. (1998). Self-Association of Asphaltenes. In: Mullins, O.C., Sheu, E.Y. (eds) Structures and Dynamics of Asphaltenes. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-1615-0_4
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