Skip to main content
SpringerLink
Log in

Photochemistry of Complexes of First-Row Transition Metals

  • Chapter
Photochemistry and Photophysics of Metal Complexes

Part of the book series: Modern Inorganic Chemistry ((MICE))

Abstract

Many of the early principles of inorganic photochemistry have developed from studies carried out on the first-row (3d) series of transition metal ions. The majority of these ions are kinetically labile in aqueous solution, the two exceptions being complexes of the trivalent Cr3+ (d 3) and Co3+ (d 6) ions, both of which are kinetically inert. This difference in their solution lability has resulted in complexes of these two ions receiving the majority of interest, because their slow substitution rates allows the stereochemistries of the individual photoprocesses to be determined before subsequent thermal reactions occur.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 219.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 279.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 279.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Review Literature

  • Adamson, A. W. “A Celebration of Inorganic Lives,” Coord. Chem. Revs. 1991, 110, 1.

    Article  Google Scholar 

  • Adamson, A. W. “Some Aspects of the Photochemistry of Coordination Compounds,” Coord. Chem. Revs. 1968, 3, 169.

    Article  CAS  Google Scholar 

  • Endicott, J. F. “Modifications of Transition-Metal Reaction Patterns through the Manipulation of Superexchange Couplings,” Accts. Chem. Res. 1988, 21, 59.

    Article  CAS  Google Scholar 

  • Endicott, J. F.; Ramasami, T.; Tamilarasan, R.; Lessard, R. B.; Brubaker, G. R. “Structure and Reactivity of the Metal-Centered Transition Metal Excited States,” Coord. Chem. Revs. 1987, 77, 1.

    Article  CAS  Google Scholar 

  • Ferraudi, G. “Photochemical Properties of Copper Complexes,” Coord. Chem. Revs. 1981, 36, 45.

    Article  CAS  Google Scholar 

  • Ford, P. C.; Vogler, A. “Photochemical and Photophysical Properties of Tetranuclear and Hexanuclear Clusters of Metals with d 10 and s 2 Electronic Configurations,” Acc. Chem. Res. 1993, 26, 220.

    Article  CAS  Google Scholar 

  • Forster, L. S. “The Photophysics of Chromium(III) Complexes,” Chem. Rev. 1990, 90, 331.

    Article  CAS  Google Scholar 

  • Harriman, A. “Photochemistry of Manganese Complexes,” Coord. Chem. Revs. 1979, 28, 147.

    Article  CAS  Google Scholar 

  • Jamieson, M. A.; Serpone, N.; Hoffman, M. Z. “Advances in the Photochemistry and Photophysics of Chromium(III) Polypyridyl Complexes in Fluid Solution,” Coord. Chem. Revs. 1981, 39, 121.

    Article  CAS  Google Scholar 

  • Kirk, A. D. “Chromium(III) Photochemistry and Photophysics,” Coord. Chem. Revs. 1981, 39, 225–293.

    Article  CAS  Google Scholar 

  • Kutal, C. “Spectroscopic and Photochemical Properties of d 10 Metal Complexes,” Coord. Chem. Revs. 1990, 99, 213.

    Article  CAS  Google Scholar 

  • McMillin, D. R.; Kirchoff, J. R.; Goodwin, K. V. “Exciplex Quenching of Photoexcited Copper Complexes,” Coord. Chem. Revs. 1985, 64, 83.

    Article  CAS  Google Scholar 

  • Monstad, L.; Monstad, G. “Mechanism of Thermal and Photochemical Ligand Substitution Reactions of Chromium(III) and other Octahedral Metal Complexes,” Coord. Chem. Revs. 1989, 94, 109–150.

    Article  Google Scholar 

  • Semerano, G. “Flash Photolysis and Pulse Radiolysis in Coordination Chemistry,” Coord. Chem. Revs. 1975, 16, 185.

    Article  CAS  Google Scholar 

  • Stasicka, Z.; Marchaj, A. “Flash Photolysis of Coordination Compounds.” Coord. Chem. Revs. 1977, 23, 131.

    Article  CAS  Google Scholar 

  • Stochel, G. “High-Pressure Mechanistic Studies on Thermal and Photochemical Reactions of Pentacyanoferrate Complexes,” Coord. Chem. Revs. 1992, 114, 269.

    Article  CAS  Google Scholar 

  • Tamilarasan, R.; McMillin, D. R.; Liu, F. “Metal-DNA Chemistry,” ACS Symposium Ser. 1989, 402, 48.

    Article  CAS  Google Scholar 

  • Valentine, D. “The Photochemistry of Cobalt(III) and Chromium(III) Complexes in Solution,” Adv. Photochem. 1968, 6, 123.

    Article  CAS  Google Scholar 

  • Vanquickenborne, L. G.; Ceulemans, A. “Ligand-Field Models and the Photochemistry of Coordination Compounds,” Coord. Chem. Revs. 1983, 48, 157.

    Article  CAS  Google Scholar 

  • Wasielewski, M. R. “Photoinduced Electron Transfer in Supramolecular Systems for Artificial Photosynthesis,” Chem. Rev. 1992, 92, 435.

    Article  CAS  Google Scholar 

References

  1. Adamson, A. W. J. Phys. Chem. 1967, 1, 798.

    Article  Google Scholar 

  2. Kirk, A. D. Coord. Chem. Rev. 1981, 39, 225.

    Article  CAS  Google Scholar 

  3. Plane, R. A.; Hunt, J. P. J. Am. Chem. Soc. 1957, 79, 3343.

    Article  CAS  Google Scholar 

  4. Geis, W.; Schläfer, H. L. Z. Phys. Chem. 1969, 65, 107.

    Article  CAS  Google Scholar 

  5. Fukuda, R.; Walters, R. T.; Macke, H.; Adamson, A. W. J. Phys. Chem. 1979, 83, 2097.

    Article  CAS  Google Scholar 

  6. Wegner, E. E.; Adamson, A. W. J. Am. Chem. Soc. 1966, 88, 394.

    Article  CAS  Google Scholar 

  7. Edelson, M. R.; Plane, R. A. J. Phys. Chem. 1959, 63, 327.

    Article  CAS  Google Scholar 

  8. Chiang, A.; Adamson, A. W. J. Phys. Chem. 1968, 72, 3827.

    Article  CAS  Google Scholar 

  9. Wasgestian, H. F. Z. Phys. Chem. 1969, 67, 39.

    Article  CAS  Google Scholar 

  10. Spees, S. T.; Adamson, A. W. Inorg. Chem. 1962, 1, 531.

    Article  CAS  Google Scholar 

  11. Wasgestian, H. F.; Schläfer, H. L. Z. Phys. Chem. 1968, 57, 282.

    Article  CAS  Google Scholar 

  12. Wasgestian, H. F.; Schläfer, H. L. Z. Phys. Chem. 1968, 62, 127.

    Article  CAS  Google Scholar 

  13. Riccieri, P.; Schläfer, H. L. Inorg. Chem. 1970, 9, 727.

    Article  CAS  Google Scholar 

  14. Zinato, E.; Lindholm, R. D.; Adamson, A. W. J. Am. Chem. Soc. 1969, 91, 1076.

    Article  CAS  Google Scholar 

  15. Riccieri, P.; Zinato, E. J. Am. Chem. Soc. 1975, 97, 6071.

    Article  CAS  Google Scholar 

  16. Kirk, A. D.; Fernando, S. R. L. Inorg. Chem. 1992, 31, 656.

    Article  CAS  Google Scholar 

  17. Angermann, K.; Schmidt, R.; Van Eldik, R.; Kelm, H.; Wasgestian, F. Inorg. Chem. 1982, 21, 1175.

    Article  CAS  Google Scholar 

  18. Adamson, A. W. J. Inorg. Nucl. Chem. 1960, 13, 275.

    Article  CAS  Google Scholar 

  19. Krause, H. H.; Wasgestian, F. Inorg. Chim. Acta 1978, 29, 231.

    Article  CAS  Google Scholar 

  20. Sabbatini, N.; Balzani, V. J. Am. Chem. Soc. 1972, 94, 7587.

    Article  CAS  Google Scholar 

  21. Sabbatini, N.; Scandola, M. A.; Carassiti, V. J. Phys. Chem. 1973, 77, 1307.

    Article  CAS  Google Scholar 

  22. Wasgestian, H. F. J. Phys. Chem. 1972, 76, 1947.

    Article  CAS  Google Scholar 

  23. Kirk, A. D. Mol. Photochem. 1973, 5, 127.

    CAS  Google Scholar 

  24. Adamson, A. W. Adv. Chem. Ser. 1965, 49, 237.

    Article  CAS  Google Scholar 

  25. Riccieri, P.; Zinato, E. Inorg. Chim. Acta 1981, 52, 133.

    Article  CAS  Google Scholar 

  26. Cimolino, M. C.; Shirley, N. J.; Linck, R. G. Inorg. Chem. 1980, 19, 3291.

    Article  CAS  Google Scholar 

  27. Sastri, V.; Langford, C. H. J. Phys. Chem. 1970, 74, 3945.

    Article  Google Scholar 

  28. Stevenson, K. L. J. Am. Chem. Soc. 1972, 94, 6652.

    Article  CAS  Google Scholar 

  29. Sasseville, R.; Langford, C. H. J. Am. Chem. Soc. 1979, 101, 5834.

    Article  CAS  Google Scholar 

  30. Brunschwig, B.; Sutin, N. J. Am. Chem. Soc. 1978, 100, 7568.

    Article  CAS  Google Scholar 

  31. Serpone, N.; Jamieson, M. A.; Henry, M. S.; Hoffman, M. Z.; Bolletta, E.; Maestri, M. J. Am. Chem. Soc. 1979, 101, 2907.

    Article  CAS  Google Scholar 

  32. Serpone, N.; Jamieson, M. A.; Sriram, R.; Hoffman, M. Z. Inorg. Chem. 1981, 20, 3983.

    Article  CAS  Google Scholar 

  33. Van Houten, J.; Porter, G. B. Inorg. Chem. 1978, 18, 2053.

    Google Scholar 

  34. Jamieson, M. A.; Langford, C. H.; Serpone, N.; Hersey, M. W. J. Phys. Chem. 1983, 87, 1004.

    Article  CAS  Google Scholar 

  35. Jamieson, M. A.; Serpone, N.; Hoffman, M. Z. Coord. Chem. Revs. 1981, 39, 121.

    Article  CAS  Google Scholar 

  36. Henry, M. S. J. Am. Chem. Soc. 1977, 99, 6138.

    Article  CAS  Google Scholar 

  37. Henry, M. S.; Hoffman, M. Z. Adv. Chem. Ser. 1978, 168, 91.

    Article  CAS  Google Scholar 

  38. Sriram, R.; Hoffman, M. Z. Jamieson, M. A.; Serpone, N. J. Am. Chem. Soc. 1980, 102, 1754.

    Article  CAS  Google Scholar 

  39. Hoffman, M. Z.; Serpone, N. In Photochemistry and Photophysics of Coordination Compounds, Yersin, H.; Vogler, A. (eds.), Springer-Verlag, Berlin, 1987, 43.

    Chapter  Google Scholar 

  40. Maestri, M.; Bolletta, F.; Serpone, N.; Moggi, L.; Balzani, V. Inorg. Chem. 1976, 15, 2048.

    Article  CAS  Google Scholar 

  41. Jamieson, M. A.; Serpone, N.; Maestri, M. Inorg. Chem. 1978, 17, 2432.

    Article  CAS  Google Scholar 

  42. Jamieson, M. A.; Serpone, N.; Henry, M. S.; Hoffman, M. Z. Inorg. Chem. 1979, 18, 214.

    Article  CAS  Google Scholar 

  43. Brunschwig, B.; Sutin, N. J. Am. Chem. Soc. 1978, 100, 7568.

    Article  CAS  Google Scholar 

  44. Juris, A.; Manfrin, M. F.; Maestri, M.; Serpone, N. Inorg. Chem. 1978, 17, 2258.

    Article  CAS  Google Scholar 

  45. Ballardini, R.; Varani, G.; Indelli, M.T.; Scandola, R.; Balzani, V. J. Am. Chem. Soc. 1978, 100, 7219.

    Article  CAS  Google Scholar 

  46. Marcus, R. A. J. Chem. Phys. 1965, 43, 679, 2654.

    Article  CAS  Google Scholar 

  47. Bolletta, R.; Maestri, M.; Moggi, L.; Jamieson, M. A.; Serpone, N.; Henry, M. S.; Hoffman, M. Z. Inorg. Chem. 1983, 22, 2502.

    Article  CAS  Google Scholar 

  48. Zink, J. I. J. Am. Chem. Soc. 1972, 94, 8039.

    Article  CAS  Google Scholar 

  49. Zink, J. I. Mol. Photochem. 1973, 5, 151.

    CAS  Google Scholar 

  50. Wrighton, M.; Gray, H. B.; Hammond, G. S. Mol. Photochem. 1973, 5, 165.

    CAS  Google Scholar 

  51. Zink, J. I. J. Am. Chem. Soc. 1974, 96, 4464.

    Article  CAS  Google Scholar 

  52. Kirk, A. D. Mol. Photochem. 1973, 5, 127.

    CAS  Google Scholar 

  53. Vanquickenborne, L. G.; Ceulemans, A. J. Am. Chem. Soc. 1977, 99, 2208.

    Article  CAS  Google Scholar 

  54. Vanquickenborne, L. G., Ceulemans, A. Inorg. Chem. 1979, 18, 897.

    Article  CAS  Google Scholar 

  55. Kirk, A. D. Inorg. Chem. 1979, 18, 2326.

    Article  CAS  Google Scholar 

  56. Vanquickenborne, L. G.; Ceulemans, A. J. Am. Chem. Soc. 1978, 100, 475.

    Article  CAS  Google Scholar 

  57. Hollebone, B. R.; Langford, C. H.; Serpone, N. Coord. Chem. Revs. 1981, 39, 181.

    Article  CAS  Google Scholar 

  58. Endicott, J. F. Comments Inorg. Chem. 1985, 3, 349.

    Article  CAS  Google Scholar 

  59. Kane-Maguire, N. A. P.; Crippen, W. S.; Miller, P. K. Inorg. Chem. 1983, 22, 696.

    Article  CAS  Google Scholar 

  60. Kane-Maguire, N. A. P.; Wallace, K. C.; Miller, D. B. Inorg. Chem. 1985, 24, 597.

    Article  CAS  Google Scholar 

  61. Perkovic, M. W.; Endicott, J. F. J. Phys. Chem. 1990, 94, 1217.

    Article  CAS  Google Scholar 

  62. Perkovic, M. W.; Heeg, M. J.; Endicott, J. F. Inorg. Chem. 1991, 30, 3140.

    Article  CAS  Google Scholar 

  63. Lessard, R. B.; Heeg, M. J.; Buranda, T.; Perkovic, M. W.; Schwarz, C. L.; Rudong, Y.; Endicott, J. F. Inorg. Chem. 1992, 31, 3091.

    Article  CAS  Google Scholar 

  64. Vanquickenborne, L. G.; Coussens, B.; Postelmans, D.; Ceulemans, A.; Pierloot, L. Inorg. Chem. 1992, 31, 539.

    Article  CAS  Google Scholar 

  65. Fleischauer, P. D.; Adamson, A. W.; Sartori, G. Prog. Inorg. Chem. 1972, 17, 1.

    Article  CAS  Google Scholar 

  66. Peterson, J. D.; Ford, P. C. J. Phys. Chem. 1974, 78, 1144.

    Article  Google Scholar 

  67. Talebinasab-Sarvari, M.; Zanella, A.; Ford, P. C. Inorg. Chem. 1980, 19, 1835.

    Article  CAS  Google Scholar 

  68. Manfrin, M. F.; Varani, G.; Moggi, L.; Balzani, V. Mol. Photochem. 1969, 1, 387.

    CAS  Google Scholar 

  69. Moggi, L.; Bolleta, F.; Balzani, V.; Scandola, F. Inorg. Nucl. Chem. 1966, 28, 2589.

    Article  CAS  Google Scholar 

  70. Nakamura, K.; Jin, K.; Tazawa, A.; Kanno, M. Bull. Chem. Soc. Jpn. 1975, 48, 3486.

    Article  CAS  Google Scholar 

  71. Wilson, R. D.; Solomon, E. I. J. Am. Chem. Soc. 1980, 102, 4085.

    Article  CAS  Google Scholar 

  72. Langford, C. H.; Vuick, C. P. J. J. Am. Chem. Soc. 1976, 98, 5409.

    Article  CAS  Google Scholar 

  73. Nishazawa, M.; Ford, P. C. Inorg. Chem. 1981, 20, 294.

    Article  CAS  Google Scholar 

  74. Endicott, J. F.; Hoffman, M. Z. J. Am. Chem. Soc. 1965, 87, 3348.

    Article  CAS  Google Scholar 

  75. Klein, D.; Moeller, C. W. Inorg. Chem. 1965, 4, 394.

    Article  CAS  Google Scholar 

  76. Manfrin, M. F.; Moggi, L.; Castelvetro, V.; Balzani, V.; Hasseim, M. W.; Lehn, J. M. J. Am. Chem. Soc. 1985, 107, 6888.

    Article  CAS  Google Scholar 

  77. Kirk, A. D.; Kneeland, D. M. Inorg. Chem. 1989, 28, 4274.

    Article  CAS  Google Scholar 

  78. Vianne, L.; D’Obieslager, J.; Ceulemans, A.; Vanquickenborne, L. G. J. Am. Chem. Soc. 1979, 101, 1405.

    Article  Google Scholar 

  79. Vianne, L.; D’Obieslager, J. Inorg. Chem. 1987, 26, 960.

    Article  Google Scholar 

  80. Langford, C. H.; Malkhasian, A. Y. S.; Sharma, D. K. J. Am. Chem. Soc. 1984, 106, 2727.

    Article  CAS  Google Scholar 

  81. Kirk, A. D.; Langford, C. H.; Sharma, D. K. Inorg. Chem. 1989, 28, 974.

    Article  CAS  Google Scholar 

  82. Kawaguchi, S.; Fujioka, H. Bull. Chem. Soc. Jpn. 1967, 40, 802.

    Article  CAS  Google Scholar 

  83. Purcell, K. F.; Clark, S. F.; Petersen, J. D. Inorg. Chem. 1980, 19, 2183.

    Article  CAS  Google Scholar 

  84. Shinozuka, N.; Kikuchi, S. Nippon Kagaku Zasshi 1966, 87, 413.

    Article  CAS  Google Scholar 

  85. Orhanovic, M.; Sutin, N. Inorg. Chem. 1977, 16, 550.

    Article  CAS  Google Scholar 

  86. Noyes, R. M. J. Am. Chem. Soc. 1955, 77, 2042.

    Article  CAS  Google Scholar 

  87. Scandola, F.; Bartocci, C.; Scandola, M. A. J. Phys. Chem. 1974, 78, 572.

    Article  CAS  Google Scholar 

  88. Vogler, A.; Kunkely, H. Ber der Bunsen Gesellschaft 1975, 79, 83.

    Article  CAS  Google Scholar 

  89. Vogler, A.; Osman, A. H.; Kunkely, H. Inorg. Chem. 1987, 26, 2337.

    Article  CAS  Google Scholar 

  90. Nishizawa, M.; Ford, P. C. Inorg. Chem. 1981, 20, 2016.

    Article  CAS  Google Scholar 

  91. Kane-Maguire, N. A. P.; Allen, M. M.; Vaught, J. M.; Hallock, J. S.; Heatherington, A. L. Inorg. Chem. 1983, 22, 3851.

    Article  CAS  Google Scholar 

  92. Ferraudi, G.; Endicott, J. F. Inorg. Chem. 1973, 12, 2389.

    Article  CAS  Google Scholar 

  93. Rehorek, D.; Thomas, P.; Hennig, H. Inorg. Chim. Acta 1979, 32, L1.

    Article  CAS  Google Scholar 

  94. McMillin, D. R.; Buckner, M. T.; Ahn, B. T. Inorg. Chem. 1977, 16, 943.

    Article  CAS  Google Scholar 

  95. Kirchoff, J. R.; Gamache, R. E.; Blaskie, M. W.; Del Paggio, A. A.; Lengel, R. K.; McMillin, D. R. Inorg. Chem. 1983, 22, 2380.

    Article  Google Scholar 

  96. Dietrich-Buchecker, C. O.; Marnot, P. A.; Sauvage, J. P.; Kirchoff, J. R.; McMillin, D. R. JCS, Chem. Comm. 1983, 513.

    Google Scholar 

  97. Phifer, C. C.; McMillin, D. R. Inorg. Chem. 1986, 25, 1329.

    Article  CAS  Google Scholar 

  98. McMillin, D. R.; Kirchoff, J. R.; Goodwin, K. V. Coord. Chem. Revs. 1985, 64, 83.

    Article  CAS  Google Scholar 

  99. Turro, N. J. Modern Molecular Photochemistry, Benjamin/Cummings, Menlo Park, CA, 1978.

    Google Scholar 

  100. Kavarnos, G. J.; Turro, N. J. Chem. Revs. 1986, 86, 401.

    Article  CAS  Google Scholar 

  101. Blasse, G.; Breddels, P. A.; McMillin, D. R. Chem. Phys. Lett. 1984, 109, 24.

    Article  CAS  Google Scholar 

  102. Wehry, E. L.; Sundararajan, S. JCS, Chem. Comm. 1972, 1135.

    Google Scholar 

  103. Blaskie, M. W.; McMillin, D. R. Inorg. Chem. 1980, 19, 351.

    Article  Google Scholar 

  104. Gushurst, A. K. I.; McMillin, D. R.; Dietrich-Buchecker, C. O.; Sauvage, J.-P. Inorg. Chem. 1989, 28, 4070.

    Article  CAS  Google Scholar 

  105. Stacy, E. M.; McMillin, D. R. Inorg. Chem. 1990, 29, 393.

    Article  CAS  Google Scholar 

  106. Tamilarasan, R.; McMillin, D. R. Inorg. Chem. 1990, 29, 2798.

    Article  CAS  Google Scholar 

  107. Ahn, B. T.; McMillin, D. R. Inorg. Chem. 1978, 17, 2253.

    Article  CAS  Google Scholar 

  108. Ahn, B. T.; McMillin, D. R. Inorg. Chem. 1981, 20, 1427.

    Article  CAS  Google Scholar 

  109. Gamache, Jr., R. E.; Rader, R. A.; McMillin, D. R. J. Am. Chem. Soc. 1985, 107, 1141.

    Article  CAS  Google Scholar 

  110. Crane, D. R.; Ford, P. C. J. Am. Chem. Soc. 1991, 113, 8510.

    Article  CAS  Google Scholar 

  111. Crane, D. R.; Ford, P. C. Inorg. Chem. 1993, 32, 2391.

    Article  CAS  Google Scholar 

  112. Davis, D. D.; Stevenson, K. L.; Davis, C. R. J. Am. Chem. Soc. 1978, 100, 5344.

    Article  CAS  Google Scholar 

  113. Ferraudi, G. Inorg. Chem. 1978, 17, 1370.

    Article  CAS  Google Scholar 

  114. Horvath, O.; Fendler, J. H.; Stevenson, K. L. Inorg. Chem. 1993, 32, 227.

    Article  CAS  Google Scholar 

  115. Cotton, F. A.; Wilkinson, G. Advanced Inorganic Chemistry, 5th Edition, Wiley, New York, 1988, p. 761.

    Google Scholar 

  116. Grutsch, P. A.; Kutal, C. J. Am. Chem. Soc. 1977, 99, 6460.

    Article  CAS  Google Scholar 

  117. Grutsch, P. A.; Kutal, C. J. Am. Chem. Soc. 1979, 101, 4228.

    Article  CAS  Google Scholar 

  118. Rader, R. A.; McMillin., D. R.; Buckner, M. T.; Matthews, T. G.; Casadonte, D. J.; Lengel, R. K.; Wittaker, S. B.; Darmon, L. M.; Lytle, F. E. J. Am. Chem. Soc. 1981, 103, 5906.

    Article  CAS  Google Scholar 

  119. Buckner, M. T.; Matthews, T. G.; Lytle, F. E.; McMillin, D. R. J. Am. Chem. Soc. 1979, 101, 5846.

    Article  CAS  Google Scholar 

  120. Fife, D. J.; Moore, W. M.; Morse, K. W. Inorg. Chem. 1984, 23, 1545.

    Article  CAS  Google Scholar 

  121. Segers, D. P.; DeArmond, M. K.; Grutsch, P. A.; Kutal, C. Inorg. Chem. 1984, 23, 2874.

    Article  CAS  Google Scholar 

  122. De Anna, H. D.; Hardt, H. D. Z. Anorg. Allg. Chem. 1972, 387, 61.

    Article  Google Scholar 

  123. Hardt, H. D.; Pierre, A. Z. Anorg. Allg. Chem. 1973, 402, 107.

    Article  CAS  Google Scholar 

  124. Hardt, H. D. Naturwissenschaften 1974, 61, 107.

    Article  CAS  Google Scholar 

  125. Eitel, E.; Oelkrug, D.; Hiller, W.; Strahle, J. Z. Natuforsch. B: Anorg. Org. Chem. 1980, 35B, 1247.

    CAS  Google Scholar 

  126. Vogler, A.; Kunkely, H. J. Am. Chem. Soc. 1986, 108, 7211.

    Article  CAS  Google Scholar 

  127. Kyle, K. R.; Ryu, C. K.; DiBenedetto, J. A.; Ford, P. C. J. Am. Chem. Soc. 1991, 113, 2954.

    Article  CAS  Google Scholar 

  128. Raston, C. L.; White, A. H. JCS, Dalton Trans. 1976, 2153.

    Google Scholar 

  129. Henary, M.; Zink, J. I. J. Am. Chem. Soc. 1989, 111, 7407.

    Article  CAS  Google Scholar 

  130. Hudson, B. P.; Sou, J.; Berger, D. J.; McMillin, D. R. J. Am. Chem. Soc. 1992, 114, 8997.

    Article  CAS  Google Scholar 

  131. Spassky, A.; Signum, D. S. Biochemistry 1985, 24, 8050.

    Article  CAS  Google Scholar 

  132. Sigman, D. S. Acc. Chem. Res. 1986, 19, 180.

    Article  CAS  Google Scholar 

  133. Veal, J. M.; Rill, R. L. Biochemistry 1988, 27, 1822.

    Article  CAS  Google Scholar 

  134. Sigman, D. S.; Graham, D. R.; D’Aurora, V.; Stern, A. M. J. Biol. Chem. 1979, 254, 12269.

    CAS  Google Scholar 

  135. Tamilarasan, R.; McMillin, D. R.; Liu, F. ACS, Sympos. Ser. 1988, 402, 48.

    Article  CAS  Google Scholar 

  136. Sykora, Von J.; Horvath, E.; Gazo, J. Z. Anorg. Allg. Chem. 1978, 442, 245.

    Article  CAS  Google Scholar 

  137. Sykora, J.; Sima, D.; Valigura, D. Chem. Zvesti 1981, 35, 345.

    CAS  Google Scholar 

  138. Bray, R. G.; Ferguson, J.; Hawkins, C. J. Aust. J. Chem. 1969, 22, 2091.

    Article  CAS  Google Scholar 

  139. Truesdell, K. A.; Crosby, G. A. J. Am. Chem. Soc. 1985, 107, 1787.

    Article  CAS  Google Scholar 

  140. Koester, V. J. Chem. Phys. 1975, 32, 575.

    CAS  Google Scholar 

  141. Crosby, G. A.; Highland, R. G.; Truesdell, K. A. Coord. Chem. Revs. 1985, 64, 41.

    Article  CAS  Google Scholar 

  142. Highland, R. G.; Crosby, G. A. Chem. Phys. Lett. 1985, 119, 454.

    Article  CAS  Google Scholar 

  143. Highland, R. G.; Brummer, J. G.; Crosby, G. A. J. Phys. Chem. 1986, 90, 1593.

    Article  CAS  Google Scholar 

  144. Crosby, G. A. 48th Southwest Regional ACS Meeting, Lubbock, TX, October 21–23, 1992. Abstr. 197.

    Google Scholar 

  145. Fernandez, A.; Görner, H.; Kisch, H. Chem. Ber. 1985, 118, 1936.

    Article  CAS  Google Scholar 

  146. Miller, T. R.; Dance, I. G. J. Am. Chem. Soc. 1973, 95, 6970.

    Article  CAS  Google Scholar 

  147. Schrauzer, G. N.; Zhang, C.; Schleuper, E. O. Inorg. Chem. 1990, 29, 3371.

    Article  CAS  Google Scholar 

  148. Zhang, C.; Reddy, H. K.; Schleuper, E. O.; Schrauzer, G. N. Inorg. Chem. 1990, 29, 4100.

    Article  CAS  Google Scholar 

  149. Ohtani, M.; Ohkoshi, S.-I.; Kajitani, M.; Akiyama, T.; Sugimon, A.; Yamauchi, S.; Ohba, Y.; Iwaizumi, M. Inorg. Chem. 1992, 31, 3873.

    Article  CAS  Google Scholar 

  150. Reed, J. L.; Wang, F.; Basolo, F. J. Am. Chem. Soc. 1972, 94, 7173.

    Article  CAS  Google Scholar 

  151. Bartocci, C.; Scandola, F. JCS, Chem. Comm. 1970, 531.

    Google Scholar 

  152. Endicott, J. F.; Hoffman, M. Z.; Beres, L. S. J. Phys. Chem. 1970, 74, 1021.

    Article  CAS  Google Scholar 

  153. Beckalka, A.; Batchelor, R. J.; Einstein, F. W. B.; Hill, R. R.; Palmer, B. J. Inorg. Chem. 1992, 31, 3118.

    Article  Google Scholar 

  154. Bendix, R.; Rehorek, D. Z. Chem. 1988, 28, 192.

    Article  Google Scholar 

  155. Brudvig, G. W.; Holden Thorp, H.; Crabtree, R. H. Acc. Chem. Res. 1991, 24, 311.

    Article  CAS  Google Scholar 

  156. Joliot, P.; Barbieri, G.; Chabaud, R. Photochem. Photobiol 1969, 10, 309.

    Article  CAS  Google Scholar 

  157. Penner-Hahn, J. E.; Franko, R. M.; Pecoraro, V. L.; Yocum, C. F.; Betts, S. D.; Bowlby, N. R. J. Am. Chem. Soc. 1990, 112, 2549.

    Article  CAS  Google Scholar 

  158. George, G. N.; Prince, R. C.; Cramer, S. P. Science 1989, 243, 789.

    Article  CAS  Google Scholar 

  159. Brudvig, G. W. In Advanced EPR: Applications in Biology and Biochemistry, Hoff, A. J. (ed.), Elsevier, Amsterdam, 1989.

    Google Scholar 

  160. Dismukes, G. C.; Siderer, Y. Proc. Natl Acad. Sci. U.S.A. 1981, 78, 274.

    Article  CAS  Google Scholar 

  161. Hansson, Ö.; Aasa, R.; Vänngard, T. Biophys. J. 1987, 51, 825.

    Article  CAS  Google Scholar 

  162. Christou, G. Acc. Chem. Res. 1989, 22, 328.

    Article  CAS  Google Scholar 

  163. Chan, M. K.; Armstrong, W. H. J. Am. Chem. Soc. 1991, 113, 5055.

    Article  CAS  Google Scholar 

  164. Brudvig, G. W.; Crabtree, R. H. Proc. Natl. Acad. Sci. U.S.A. 1986, 83, 4586.

    Article  CAS  Google Scholar 

  165. Micklitz, W.; Bott, S. G.; Bentsen, J. G.; Lippard, S. J. J. Am. Chem. Soc. 1989, 111, 372.

    Article  CAS  Google Scholar 

  166. Bossek, U.; Weyhermüller, T.; Wieghardt, K.; Nuber, B.; Weiss, J. J. Am. Chem. Soc. 1990, 112, 6387.

    Article  CAS  Google Scholar 

  167. Koulougliotis, D.; Hirsh, D. J.; Brudvig, G. W. J. Am. Chem. Soc. 1992, 114, 8322.

    Article  CAS  Google Scholar 

  168. Bocarsly, J. R.; Brudvig, G. W. J. Am. Chem. Soc. 1992, 114, 9762.

    Article  CAS  Google Scholar 

  169. Wang, S.; Huffman, J. C.; Folting, K.; Streib, W. E.; Lobkovsky, E. B.; Christou, G. Agnew. Chem., Int. Ed. Engl. 1991, 30, 1672.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Tulane University, New Orleans, Louisiana, USA

    D. M. Roundhill

Authors
  1. D. M. Roundhill
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

Copyright information

© 1994 Springer Science+Business Media New York

About this chapter

Cite this chapter

Roundhill, D.M. (1994). Photochemistry of Complexes of First-Row Transition Metals. In: Photochemistry and Photophysics of Metal Complexes. Modern Inorganic Chemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-1495-8_2

Download citation

  • DOI: https://doi.org/10.1007/978-1-4899-1495-8_2

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4899-1497-2

  • Online ISBN: 978-1-4899-1495-8

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation