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Phase Equilibria in Polymer Systems Containing a Liquid-Crystalline Phase

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Liquid-Crystal Polymers

Part of the book series: Specialty Polymers ((SPEPO))

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Abstract

In examining phase equilibria in polymer systems, until recently most of the attention has been focused on the transitions between amorphous and crystalline states alone and the transitions from one crystalline modification to another (polymorphic transitions). The detection and the subsequent study of the liquid-crystalline state of polymers showed that it is an independent, thermodynamically equilibrium state. In many phase transitions, it occupies an intermediate position between the amorphous and crystalline states, and the mutual transitions from these two states into the liquid-crystalline state and vice versa are phase transitions of the first kind.

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Papkov, S.P. (1993). Phase Equilibria in Polymer Systems Containing a Liquid-Crystalline Phase. In: Platé, N.A. (eds) Liquid-Crystal Polymers. Specialty Polymers. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-1103-2_2

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  • DOI: https://doi.org/10.1007/978-1-4899-1103-2_2

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4899-1105-6

  • Online ISBN: 978-1-4899-1103-2

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