Skip to main content
SpringerLink
Log in

Surface Raman Spectroscopy

  • Chapter
Surface Infrared and Raman Spectroscopy

Part of the book series: Methods of Surface Characterization ((MOSC,volume 3))

Abstract

Raman scattering, an inelastic scattering of photons by chemical entities, is widely utilized for the investigation of the structure of molecules, crystals, and polymer materials.(1–5) The cross section of normal Raman scattering, however, is low for observing surface species, and most surface Raman experiments were confined to porous or finely divided inorganic materials until recently.(6,7) Before the discovery of surface enhanced Raman scattering (SERS), resonance Raman scattering(8,9) was employed for the most part in the observation of bulk solid surfaces.(10)

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
eBook
USD 16.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 109.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. T.R. Gilson and P.J. Hendra, Laser Raman Spectroscopy, Wiley, New York (1970).

    Google Scholar 

  2. J.A. Koningstein, Introduction to the Theory of the Raman Effect, Reidel, Dordrecht, Holland (1972).

    Google Scholar 

  3. D.A. Long, Raman Spectroscopy, McGraw-Hill, New York (1977).

    Google Scholar 

  4. J.G. Grasselli, M.K. Snavely, and B.J. Bulkin, Chemical Applications of Raman Spectroscopy, Wiley, New York (1981).

    Google Scholar 

  5. D.P. Strommen and K. Nakamoto, Laboratory Raman Spectroscopy, Wiley, New York (1985).

    Google Scholar 

  6. W. Krasser and A.J. Renouprez, J. Raman Spectrosc. 8, 92 (1979).

    CAS  Google Scholar 

  7. P.P. Yaney and R.J. Becker, Appl. Surf. Sci. 4, 356 (1980).

    CAS  Google Scholar 

  8. J. Tang and A.C. Albrecht, in: Raman Spectroscopy: Theory and Practice, Vol. 2 (H.A. Szymanski, ed.), Plenum, New York (1970), p. 33.

    Google Scholar 

  9. R.J.H. Clark, in: Advances in infrared and Raman Spectroscopy, Vol. 1 (R.J.H. Clark and R.E. Hester, eds.), Heyden, London (1976).

    Google Scholar 

  10. H. Yamada, Appl. Spectrosc. Rev. 17, 227 (1981).

    CAS  Google Scholar 

  11. A. Campion, in: Vibrational Spectroscopy of Molecules on Surfaces (J.T. Yates, Jr. and T.E. Madey, eds.), Plenum, New York (1987), p. 345.

    Google Scholar 

  12. A. Campion, J. Electron Spectrosc. Relat. Phenom. 54/55, 877 (1990).

    Google Scholar 

  13. J.A. Koningstein and B.F. Gächter, J. Opt. Soc. Am. 63, 892 (1973).

    Google Scholar 

  14. H. Yamada and Y. Yamamoto, J. Raman Spectrosc. 9, 401 (1980).

    CAS  Google Scholar 

  15. P. J. Hendra, ed., Spectrochim. Acta 46A (1990).

    Google Scholar 

  16. R.G. Greenler and T.L. Siager, Spectrochim. Acta 29A, 193 (1973).

    Google Scholar 

  17. D.R. Mullins and A. Campion, J. Phys. Chem. 88, 8 (1984).

    CAS  Google Scholar 

  18. M. Ohsawa, W. Kusakari, and W. Suëtaka, Spectrochim. Acta 36A, 389 (1980).

    CAS  Google Scholar 

  19. Z. Lenac and M.S. Tomaš, J. Raman Spectrosc. 22, 831 (1991).

    CAS  Google Scholar 

  20. M. Moskovits, J. Chem. Phys. 77, 4408 (1982).

    CAS  Google Scholar 

  21. V.M. Hallmark and A. Campion, J. Chem. Phys. 84, 2933, 2942 (1986).

    CAS  Google Scholar 

  22. T. Ikeshoji, Y. Ono, and T. Mizuno, Appl. Opt. 12, 2236 (1973).

    CAS  Google Scholar 

  23. K.H. Redel, D. Spenkuch, and G.R. Wessler, Opt. Spectrosc. 38, 649 (1975).

    Google Scholar 

  24. M. Fujihara and T. Osa, J. Am. Chem. Soc. 98, 7850 (1976).

    Google Scholar 

  25. W. Carious and O. Schrötter, Z. Phys. Chem. (Leipzig) 262, 711 (1981).

    Google Scholar 

  26. J. Cipriani, S. Racine, R. Dupeyrat, H. Hasmonay, M. Dupeyrat, Y. Levy, and C. Imbert, Opt. Comm 11, 70 (1974).

    CAS  Google Scholar 

  27. J.F. Rabolt, R. Santo, and J.D. Swalen, Appl. Spectrosc. 33, 549 (1979).

    CAS  Google Scholar 

  28. R. Iwamoto, M. Miya, K. Ohta, and S. Mima, J. Am. Chem. Soc. 102, 1212 (1980); J. Chem. Phys. 74, 4780 (1981).

    CAS  Google Scholar 

  29. T. Takenaka and T. Nakanaga, J. Phys. Chem. 80, 475 (1976).

    CAS  Google Scholar 

  30. G.S. Agarwal, Phys. Rev. A12, 1475 (1975).

    Google Scholar 

  31. W. Lukosz and R.E. Kunz, J. Opt. Soc. Am. 67, 1607, 1615 (1977).

    Google Scholar 

  32. W. Lukosz, J. Opt. Soc. Am. 69, 1495 (1979); 71, 744 (1981).

    CAS  Google Scholar 

  33. W. Lukosz and R.E. Kunz, Opt. Commn. 31, 251 (1979).

    CAS  Google Scholar 

  34. G. Mattei, B. Fornari, and M. Pagannone, Solid State Comm. 36, 309 (1980).

    CAS  Google Scholar 

  35. M. Ohsawa, K. Hashima, and W. Suëtaka, Appl. Surf. Sci. 20, 109 (1984).

    CAS  Google Scholar 

  36. J.F. Rabolt and J.D. Swalen, in: Spectroscopy of Surfaces (R.J.H. Clarke and R.E. Hester, eds.), Wiley, New York (1988), p. 1.

    Google Scholar 

  37. Y. Levy, C. Imbert, J. Cipriani, S. Racine, and R. Dupeyrat, Opt. Comm. 11, 66 (1974).

    CAS  Google Scholar 

  38. J.F. Rabolt, R. Santo, and J.D. Swalen, Appl. Spectrosc. 34, 517 (1980).

    CAS  Google Scholar 

  39. J.F. Rabolt, N.E. Schlotter, and J.D. Swalen, J. Phys. Chem. 85, 4141 (1981).

    CAS  Google Scholar 

  40. C.G. Zimba, V.M. Hallmark, S. Turrell, J.D. Swalen, and J.F. Rabolt, J. Phys. Chem. 94, 939 (1990).

    CAS  Google Scholar 

  41. C.G. Zimba and J.F. Rabolt, Thin Solid Films 206, 388 (1991).

    CAS  Google Scholar 

  42. G.I. Stcgeman, R. Fortenberry, R. Moshrefzadeh, W.H. Hetherington III, N.E. Van Wyck, and J.E. Sipe, Opt. Lett. 8, 295 (1983).

    Google Scholar 

  43. W.H. Hetherington III, Z.Z. Ho, E.W. Koenig, G.I. Stegcman, and R. Fortenberry, Chem. Phys. Lett. 128, 150 (1986).

    CAS  Google Scholar 

  44. G. Karagounis and R. Issa, Z. Elektrochem. 66, 874 (1962).

    CAS  Google Scholar 

  45. R.O. Kagel, J. Phys. Chem. 74, 4518 (1970).

    CAS  Google Scholar 

  46. T. A. Egerton, A.H. Hardin, Y. Kozirovsky, and N. Shcppard, J. Catal. 32, 343 (1974).

    CAS  Google Scholar 

  47. P.J. Hcndra, J.R. Horder, and E. J. Loader, J. Chem. Soc. 1766 (1971); P.J. Hcndra, I.D.M. Turner, E.J. Loader, and M. Stacey, J. Phys. Chem. 78, 300 (1974).

    Google Scholar 

  48. M.L. Howe, K.L. Walters, and R.G. Greenler, J. Phys. Chem. 80, 382 (1976).

    CAS  Google Scholar 

  49. J.M. Stencel and E.B. Bradley, Spectrosc. Lett. 11, 563 (1978).

    CAS  Google Scholar 

  50. J.M. Stencel, D.M. Noland, E.B. Bradley, and C.A. Frenzel, Rev. Sci. Instrum. 49, 1163 (1978).

    CAS  Google Scholar 

  51. J.M. Stencel and E.B. Bradley, J. Raman Spectrosc. 8, 203 (1979).

    CAS  Google Scholar 

  52. H.A. Marzouk, K.A. Arunkumar, and E.B. Bradley, Surf. Sci. 147, 477 (1984).

    CAS  Google Scholar 

  53. A. Campion, J.K. Brown, and V.M. Grizzle, Surf. Sci. 115, L153 (1982).

    CAS  Google Scholar 

  54. A. Campion, and D.R. Mullins, Surf. Sci. 158, 263 (1985).

    CAS  Google Scholar 

  55. D. Harradine and A. Campion, Chem. Phys. Lett. 135, 501 (1987).

    CAS  Google Scholar 

  56. C. Shannon and A. Campion, Surf. Sci. 227, 219 (1990).

    CAS  Google Scholar 

  57. R.N. Zitter, Surf. Sci. 28, 335 (1971).

    CAS  Google Scholar 

  58. J.A. Cape, L.G. Hale, and W.E. Tennant, Surf. Sci. 62, 639 (1977).

    CAS  Google Scholar 

  59. R. Tsu and S.S. Jha, J. Phys. (Paris) 41, C4–25 (1980).

    Google Scholar 

  60. H.J. Stolz and A. Abstreiter, Solid State Comm. 36, 857 (1980).

    CAS  Google Scholar 

  61. G.P. Schwartz, B. Schwartz, D. DiStefano, G.J. Gualtieri, and J.E. Griffiths, Appl. Phys. Lett. 34, 205 (1979).

    CAS  Google Scholar 

  62. Y. Dai, J.S. Swinnea, H. Steinfink, J.B. Goodenough, and A. Campion, J. Am. Chem. Soc. 109, 5291 (1987).

    CAS  Google Scholar 

  63. G. Mattei, B. Fornari, M. Pagannone, and L. Mattioli, J. Phys. (Paris) 45, C5–249 (1984); Solid State Comm. 44, 1495 (1982).

    Google Scholar 

  64. Y. Tian, J. Umemura, T. Takenaka, and T. Kunitake, Langmuir 4, 1064 (1988).

    CAS  Google Scholar 

  65. D.R. Miller, O.H. Hahn, and P.W. Bonn, Appl. Spectrosc. 41, 245 (1987).

    CAS  Google Scholar 

  66. J.P. Rabe, J.D. Swalen, and J.F. Rabolt, J. Chem. Phys. 86, 1601 (1987).

    CAS  Google Scholar 

  67. S.S. Perry and A. Campion, Surf. Sci. 234, L275 (1990).

    CAS  Google Scholar 

  68. S.S. Perry and A. Campion, J. Electron Spectrosc. Relat. Phenom. 54/55, 933 (1990).

    Google Scholar 

  69. S.S. Perry and A. Campion, Surf. Sci. 259, 207 (1991).

    CAS  Google Scholar 

  70. M. Fleischmann, P.J. Hendra, and A. J. McQuillan, J. Chem. Soc. Chem. Comm. 80 (1973).

    Google Scholar 

  71. M. Fleischmann, P.J. Hendra, and A.J. McQuillan, Chem. Phys. Lett. 26, 163 (1974).

    CAS  Google Scholar 

  72. E.S. Reid, R.P. Cooney, P.J. Hendra, and M. Fleischmann, J. Electroanal. Chem. 80, 405 (1977).

    CAS  Google Scholar 

  73. M. Pourbaix, Atlas of Electrochemical Equilibria in Aqueous Solutions, Pergamon, Oxford (1966).

    Google Scholar 

  74. B.H. Loo, J. Phys. Chem. 86, 433 (1982).

    CAS  Google Scholar 

  75. B.H. Loo and Y.G. Lee, Appl. Surf. Sci. 18, 345 (1984).

    CAS  Google Scholar 

  76. C. Shannon and A. Campion, J. Phys. Chem. 92, 1385 (1988).

    CAS  Google Scholar 

  77. C.A. Melendres, J.J. McMahon, and W. Ruther, J. Electroanal. Chem. 208, 175 (1986); Proceedings of the Tenth International Congress on Metallic Corrosion 4, 3481 (1987).

    CAS  Google Scholar 

  78. C.A. Melendres, J. Electroanal. Chem. 286, 273 (1990).

    CAS  Google Scholar 

  79. W.P. Acker, B. Tip, D.H. Leach, and R.K. Chang, J. Appl. Phys. 64, 2263 (1988).

    CAS  Google Scholar 

  80. D.K. Veirs, V.K.F. Chia, and G.M. Rosenblatt, Appl. Opt. 26, 3530 (1987).

    CAS  Google Scholar 

  81. D.L. Jeanmaire, M.R. Suchanski, and R.P. Van Duyne, J. Am. Chem. Soc. 97, 1699 (1975).

    CAS  Google Scholar 

  82. M.R. Suchanski and R.P. Van Duyne, J. Am. Chem. Soc. 98, 250 (1976).

    CAS  Google Scholar 

  83. W.L. Wallace, C.D. Jaeger, and A.J. Bard, J. Am. Chem. Soc. 101, 4840 (1979).

    CAS  Google Scholar 

  84. I. Blatter-Mörke, H. von Känel, and P. Wächter, J. Phys. Chem. 91, 663 (1987).

    Google Scholar 

  85. D.L. Akins, J.W. Macklin, and H-R. Zhu, J. Phys. Chem. 96 4515 (1992).

    CAS  Google Scholar 

  86. D.L. Akins, J.W. Macklin, and H-R. Zhu, J. Phys. Chem. 95, 793 (1991).

    CAS  Google Scholar 

  87. M. Ohsawa and W. Suëtaka, Ext. Abst. 26th Intern. Cong. Pure Appl. Chem. 1, 152 (1977).

    Google Scholar 

  88. N. Winograd and T. Kuwana, J. Am. Chem. Soc. 93, 4343 (1971).

    Google Scholar 

  89. W. Suëtaka and M. Ohsawa, Appl. Surf. Sci. 3, 118 (1979).

    Google Scholar 

  90. R.P. Van Duyne, in: Chemical and Biochemical Applications of Lasers, Vol. 4 (C.B. Moore, ed.), Academic, New York (1979), p. 101.

    Google Scholar 

  91. F.T. Arecchi, E. Gatti, and A. Sona, Rev. Sci. Instrum. 37, 942 (1966).

    Google Scholar 

  92. M. Ohsawa, K. Nishijima, and W. Suëtaka, Surf. Sci. 104, 270 (1980).

    Google Scholar 

  93. N. Yagi and W. Suëtaka, unpublished data.

    Google Scholar 

  94. M. Ohsawa, D.E. Thesis, Tohoku University (Sendai) 1984.

    Google Scholar 

  95. M. Fleischmann, P.J. Hendra, I.R. Hill, and M.E. Pemble, J. Electroanal. Chem. 117, 243 (1981).

    CAS  Google Scholar 

  96. J.S. Clarke, A.T. Kuhn, and W.J. Orville-Thomas, Electroanal. Chem. Interfacial Electro-chem. 54, 253 (1974).

    CAS  Google Scholar 

  97. D.L. Jeanmaire and R.P. Van Duyne, J. Electroanal. Chem. 60, 235 (1974).

    Google Scholar 

  98. M. Osawa and W. Suëtaka, J. Electroanal. Chem. 270, 261 (1989).

    CAS  Google Scholar 

  99. R. Rosetti, S.M. Beck, and L.E. Brus, J. Am. Chem. Soc. 104, 7322 (1982); J. Am. Chem. Soc. 106, 980 (1984).

    Google Scholar 

  100. M. Froelicher, A. Hugot-Le Goff, C. Pallotta, R. Dupeyrat, and M. Masson, in: Passivity of Metals and Semiconductors (M. Froment, ed.), Elsevier, Amsterdam (1983), p. 101.

    Google Scholar 

  101. R.J. Thibeau, C.W. Brown, A.Z. Goldfarb, and R.H. Heidensbach, J. Electrochem. Soc. 127, 37 (1980).

    CAS  Google Scholar 

  102. R. Kötz and E. Yeager, J. Electroanal. Chem. 111, 105 (1980).

    Google Scholar 

  103. C.A. Melendres and S. Xu, J. Electroanal. Chem. 162, 343 (1984);J. Electrochem. Soc. 131, 2239 (1984).

    CAS  Google Scholar 

  104. C.A. Melendres, N. Camillone, and T. Tipton, Electrochim. Acta 34, 281 (1989).

    CAS  Google Scholar 

  105. K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, 4th Ed., Wiley-Interscience, New York (1986).

    Google Scholar 

  106. C. A. Melendres, T.J. O’Leary and J. Solis, Electrochim. Acta 36, 505 (1991).

    CAS  Google Scholar 

  107. J.J. McMahon, W. Rüther, and C.A. Melendres, J. Electrochem. Soc. 135, 557 (1988).

    CAS  Google Scholar 

  108. D. Cubicciotti, J. Nucl. Mater. 167, 241 (1989).

    Google Scholar 

  109. V.A. Maroni, C.A. Melendres, T.F. Kassner, and S. Siegel, J. Nucl. Mater. 172, 13 (1990).

    CAS  Google Scholar 

  110. G.J. Hansen and W.N. Hansen, J. Electroanal. Chem. 150, 193 (1983).

    CAS  Google Scholar 

  111. J.E. Pemberton and R.L. Sobocinski, J. Electroanal. Chem. 318, 157 (1991).

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Tohoku University, Tsuchiura, Japan

    Professor W. Suëtaka

  2. Surface Science Center, University of Pittsburgh, Pittsburgh, Pennsylvania, USA

    John T. Yates Jr.

Authors
  1. Professor W. Suëtaka
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. John T. Yates Jr.
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

Copyright information

© 1995 Springer Science+Business Media New York

About this chapter

Cite this chapter

Suëtaka, W., Yates, J.T. (1995). Surface Raman Spectroscopy. In: Surface Infrared and Raman Spectroscopy. Methods of Surface Characterization, vol 3. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-0942-8_5

Download citation

  • DOI: https://doi.org/10.1007/978-1-4899-0942-8_5

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4899-0944-2

  • Online ISBN: 978-1-4899-0942-8

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation