Abstract
To ultimately understand macroscopic adhesion in metallized plastics, fundamental metal-organic bonding chemistry at metal-polymer interfaces must be probed. Experimental surface spectroscopies have generally produced information for well-defined systems in surface chemistry. New applications of surface techniques to complex systems such as metal-polymer interfaces have recently produced exciting new developments in studies related to adhesion technology. Recent studies of electronic and vibrational structure and the morphology of metal-polymer interfaces are reviewed. Due to the high degree of interest in the particular system, we concentrate upon the metal-polyimide interface as a means to describe the scientific approach. The general applicability of these techniques and future directions are discussed.
This is a preview of subscription content, log in via an institution.
Buying options
Tax calculation will be finalised at checkout
Purchases are for personal use only
Learn about institutional subscriptionsPreview
Unable to display preview. Download preview PDF.
References
W.D. Grobman, J. Vac. Sci. Technol. A3, 725 (1985).
A.J. Blodgett and D.R. Barbour, IBM J. Res. Develop. 26, 30 (1982).
A.J. Blodgett, Sci. Am. 249, 86 (1983).
K.L. Mittal, J. Vac. Sci. Technol. 13, 19 (1976).
D.T. Clark, CRC Crit. Rev. Solid State Mater. Sci. 8, 1 (1978).
D.T. Clark, H.R. Thomas, and D. Shuttleworth, J. Polym. Sci. Polym. Lett. Ed. 16, 465 (1978).
James M. Burkstrand, J. Vac. Sci. Technol. 16, 363 (1979).
James M. Burkstrand, J. Appl. Phys. 52, 4795 (1981).
N.J. Chou and C.H. Tang, J. Vac. Sci. Technol. A2, 751 (1984).
N.J. Chou and C.H. Tang, in “Surface and Colloid Science in Computer Technology”, K.L. Mittal, ed., pp. 287–298 (Plenum, New York, 1987).
N.J. DiNardo, J.E. Demuth, W.A. Thompson, and P.G. Ledermann, Rev. Sci. Instrum. 55, 1492 (1984).
Polyimide samples are typically fabricated from DuPont 5878 spun on a flat substrate.
P.O. Hahn, G.W. Rubloff, and P.S. Ho, J. Vac. Sci. Technol. A2, 756 (1984).
J.R. Salem, F.O. Sequeda, J. Duran, W.Y. Lee, and R.M. Yang, J. Vac. Sci. Technol. A4 369 (1986).
Nobuyuki Takahashi, Do Y. Yoon, and William Parrish, Macromolecules, 17, 2583 (1984).
Hatsuo Ishida, Stephen T. Wellinghoff, Eric Baer, and Jack L. Koenig, Macromolecules, 13, 826 (1980).
Stephen T. Wellinghoff, Hatsuo Ishida, Jack L. Koenig, and Eric Baer, Macromolecules, 13, 834 (1980).
N. Ueno, W. Gädeke, E.E. Koch, R. Engelhardt, and R. Dudde, J. Elect. Spect. and Rel. Phen. 36, 143 (1985).
D.R. Penn, Phys. Rev. B13, 5248 (1976).
H. Liehr, P.A. Thiry, J.J. Pireaux, and R. Caudano, Phys. Rev. B33, 5682 (1986).
L. Ley and M. Cardona, eds., “Photoemission in Solids I and II” (Springer-Verlag, New York, 1979).
E.W. Plummer and W. Eberhardt, in “Advances in Chemical Physics”, I. Prigogine and Stuart A. Rice, eds., Vol. 49, pp. 533 (Wiley, New York, 1982).
H. Ibach and D.L. Mills, “Electron Energy Loss Spectroscopy and Surface Vibrations” (Academic, New York, 1982).
Wei-Kan Chu, James W. Mayer, and Marc-A. Nicolet, “Backscattering Spectrometry” (Academic, New York, 1978).
R. Haight, R.C. White, B.D. Silverman, and P.S. Ho, J. Vac. Sci. Technol. A6, 2188 (1988).
R. Haight, B.D. Silverman, R.C. White, P.S. Ho, and A.R. Rossi, Mat. Res. Soc. Symp. Proc, 108, 233 (1988).
R.C. White, R. Haight, B.D. Silverman, and P.S. Ho, Appl. Phys. Lett. 51, 481 (1987).
A.R. Rossi, P.N. Sanda, B.D. Silverman, and P.S. Ho, Organometallics 6, 580 (1987).
B.D. Silverman, J.W. Bartha, J.G. Clabes, P.S. Ho, J. Polym. Sci.: Pt. A: Polym. Chem., 24, 3325 (1986).
P.L. Buchwalter and A.I. Baise, in “Polyimides: Synthesis, Characterization, and Applications”, K.L. Mittal, ed., Vol. 1, P. 537 (Plenum, New York, 1984).
A. Toth, I. Bertoty, T. Szekely, J.N. Sazanov, T.A. Antonova, A.V. Shchukarev, and A.V. Gribanov, Surf. Interface Anal. 8, 261 (1986).
J.L. Jordan, P.N. Sanda, J.F. Morar, C.A. Kovac, F.J. Himpsel, and R.A. Pollak, J. Vac. Sci. Technol. A4, 1046 (1986).
J.L. Jordan, C.A. Kovac, J.F. Morar, and R.A. Pollak, Phys. Rev. B36, 1369 (1987).
P.N. Sanda, J.W. Bartha, J.G. Clabes, J.L. Jordan, C. Feger, B.D. Silverman, and P.S. Ho, J. Vac. Sci. Technol. A4, 1035 (1986).
J.G. Clabes, M.J. Goldberg, A. Viehbeck, and C.A. Kovac, J. Vac. Sci. Technol. A6, 985 (1988).
M.J. Goldberg, J.G. Clabes, and C.A. Kovac, J. Vac. Sci. Technol. A6, 991 (1988) and references therein.
J.L. Brédas and T.C. Clarke, J. Chem. Phys. 86, 253 (1987).
C.B. Duke, Mol. Cryst. Liq. Cryst. 50, 63 (1979).
R.M. Tromp, F. LeGoues, and P.S. Ho, J. Vac. Sci. Technol. A3, 782 (1985).
M.J. Goldberg, unpublished results (1988).
J.L. Jordan-Sweet, C.A. Kovac, M.J. Goldberg, and J.F. Morar, J. Chem. Phys. 89, 2482 (1988).
J.J. Pireaux, C. Grégoire, P.A. Thiry, R. Caudano, and T.C. Clarke, J. Vac. Sci. Technol. A5, 598 (1987).
J.J. Pireaux, C. Grégoire, M. Vermeersch, P.A. Thiry, and R. Caudano, Surf. Sci. 189/190, 903 (1987).
J.J. Pireaux, M. Vermeersch, C. Grégoire, P.A. Thiry, R. Caudano, and T.C. Clarke, J. Chem. Phys. 88, 3353 (1988).
Lj. Atanasoska, Steven G. Anderson, H.M. Meyer, III, Zhangda Lin, and J.H. Weaver, J. Vac. Sci. Technol. A5, 3325 (1987).
J.W. Bartha, P.O. Hahn. F. LeGoues, and P.S. Ho, J. Vac. Sci. Technol. A3, 1390 (1985).
F.S. Ohuchi and S.C. Freilich, J. Vac. Sci. Technol. A4, 1039 (1986).
Steven G. Anderson, H.M. Meyer, III, and J.H. Weaver, J. Vac. Sci. Technol. A6, 2205 (1988).
L.J. Atanasoska, H.M. Meyer III, Steven G. Anderson, and J.H. Weaver, J. Vac. Sci. Technol. A6, 2175 (1988).
N.J. DiNardo, Ph. Avouris, and J.E. Demuth, J. Chem. Phys. 81, 2169 (1984).
H. Ibach, to be published.
W.D. Jennings, G.S. Chottiner, R.W. Hoffman, and I. Lundström, and W.R. Salaneck, Bull. Am. Phys. Soc. 29, 359 (1984).
J.H. Wandass and J.A. Gardella, Surf. Sci. Lett. 150, L107 (1985).
Joseph H. Wandass and Joseph A. Gardella, Langmuir, 2, 543 (1986).
1 meV = 8.0 65 cm−1
N.J. DiNardo, J.E. Demuth, and T.C. Clarke, J. Chem. Phys. 85, 6739 (1986).
N.J. DiNardo, J.E. Demuth, and T.C. Clarke, J. Vac Sci. Technol., A4, 1060 (1986).
B.D. Silverman, to be published.
The gold film circumvented problems with a large loss background due to electron-induced excitations in the Si substrate.
J.J. Pireaux, P.A. Thiry, R. Caudano, and P. Pfluger, J. Chem. Phys. 84, 6452 (1986).
N.J. DiNardo, J.E. Demuth, and T.C. Clarke, Chem. Phys. Lett. 121, 239 (1985).
P.O. Hahn, G.W. Rubloff, J.W. Bartha, F. LeGoues, R. Tromp, and P.S. Ho, Mat. Res. Soc. Symp. Proc, 40, 247 (1985).
B.N.J. Persson and J.E. Demuth, Phys. Rev. B30, 5968 (1984).
R.J. Purtell, private communication (1988).
F.K. LeGoues, B.D. Silverman, and P.S. Ho, J. Vac. Sci. Technol. A6 2200 (1988).
G. Binnig and H. Rohrer, Ch. Gerber, and E. Weibel, Phys. Rev. Lett. 49, 57 (1982).
Tycho Sleator and Robert Tycho, Phys. Rev. Lett. 60, 1418 (1988).
Dawn A. Bonell and Marie Angelopoulos, to be published.
V.M. Hallmark, A. Leone, S. Chiang, J.D. Swalen, and J.F. Rabolt, Polym. Prepr. 28, 22 (1987).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1989 Springer Science+Business Media New York
About this chapter
Cite this chapter
DiNardo, N.J. (1989). Surface Spectroscopic Techniques Applied to Metallized Plastics. In: Mittal, K.L., Susko, J.R. (eds) Metallized Plastics 1. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-0879-7_11
Download citation
DOI: https://doi.org/10.1007/978-1-4899-0879-7_11
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4899-0881-0
Online ISBN: 978-1-4899-0879-7
eBook Packages: Springer Book Archive