Skip to main content

Silicon Oxidation Studies: A Review of Recent Studies on Thin Film Silicon Dioxide Formation

  • Chapter
The Physics and Chemistry of SiO2 and the Si-SiO2 Interface

Abstract

The formation of thin SiO2 films via thermal oxidation on single crystal Si substrates has been found to depend on the method of Si cleaning, impurities on the Si surface, the Si crystal orientation, film stress, and the availability of electrons at the Si surface. Recent studies on these topics are recounted along with a framework for understanding. No fully acceptable model for thin SiO2 formation yet exists, but recent studies lead in new directions towards this goal.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 169.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 219.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 219.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. B.E. Deal and A.S. Grove, J. Appl. Phys., 36. 3770 (1965).

    Article  CAS  Google Scholar 

  2. W.A. Pliskin, IBM J. Res. and Develop., 10, 198 (1965).

    Article  Google Scholar 

  3. A.G. Revesz, K. H. Zaininger and R. J. Evans, J. Electrochem. Soc., 113, 706 (1966).

    Article  Google Scholar 

  4. U.R. Evans, “The Corrosion and Oxidation of Metals’, Arnold, London (1960).

    Google Scholar 

  5. R. Rosenberg, Abstract DG-TUM2, presented at 34” AVS meeting Anaheim, CA, Nov. 2–6, 1987.

    Google Scholar 

  6. W. Kern and D.A. Poutinen, RCA Rev., 31, 187 (1970).

    CAS  Google Scholar 

  7. R. Williams and A.M. Goodman, Appl. Phys. Lett., 25, 531 (1974).

    Article  CAS  Google Scholar 

  8. E.A. Irene and Y.J. van der Meulen, J. Electrochem. Soc., 123, 1380 (1976).

    Article  Google Scholar 

  9. J.R. Ligenza and W.G. Spitzer, J. Phys. Chem. Solids 44, 131 (1960).

    Article  Google Scholar 

  10. V.G. Levich, “Physicochemical Hydrodynamics”, Prentice Hall, Englewood Cliffs, N.J. (1962), pp. 72–78.

    Google Scholar 

  11. E.A. Irene and R. Ghez, Appl. Surface Sci., 30, 1 (1987).

    Article  CAS  Google Scholar 

  12. E.A. Irene, H.Z. Massoud and E. Tierney, J. Electrochem. Soc., 133, 1253 (1986).

    Article  CAS  Google Scholar 

  13. P. Chiaradia and S. Nannarone, Surface Science, 54, 547 (1976).

    Article  CAS  Google Scholar 

  14. J. Derrien and M. Commandre, Surface Science, 118. 32 (1982).

    Article  CAS  Google Scholar 

  15. H. Ibach, H.D. Bruckmann, and H. Wagner, Appl. Phys. A., 29. 113 (1982).

    Article  Google Scholar 

  16. F.N. Schvettman, K.L. Chiang and W.A. Brown, Society Meeting, Abstract 276, May 1978.

    Google Scholar 

  17. F.J. Grunthaner and J. Maserjian, IEEE Trans. Nucl. Sci., NS-24, 2108 (1977).

    Google Scholar 

  18. G. Gould and E.A. Irene, J. Electrochem. Soc., 134, 1031 (1987)

    Article  CAS  Google Scholar 

  19. J. M. DeLarios, C. R. Helms, D. B. Kao and B. E. Deal, Appl. Suface Sci.. 30, 17 (1987).

    Google Scholar 

  20. G. Gould and E.A. Irene, J. Electrochem. Soc. Accepted for publication (1988).

    Google Scholar 

  21. G. Gould and E.A. Irene, J. Electrochem. Soc., submitted 1988.

    Google Scholar 

  22. W.A. Zisman, “Contact Angle: Wetability and Advances in Chemistry Series, Vol. 43, Ed. F. Soc., Washington, D.C. (1964), Chap. 1.

    Google Scholar 

  23. H.W. Fox and W.A. Zisman, J. Colloid Sci., 5, 514 (1950)

    Article  CAS  Google Scholar 

  24. G.B. Larrabee, K.G. Heinen and S.A. Harrell, J. of Electrochem. Soc.. 1, 867 (1967).

    Article  Google Scholar 

  25. E. Yablonovitch, D. L. Allara, C.C. Chang, T. Bright, Phys. Rev. Lett., 57, 249 (1986).

    Article  CAS  Google Scholar 

  26. R.E. Benenson, L.C. Feldman and B.G. Bagley, Nuclear Inst. And Methods, 168, 547 (1980).

    Article  CAS  Google Scholar 

  27. A.G. Revesz and R.J. Evans, J. Phvs. Chem. Solids, 30, 551 (1969).

    Article  CAS  Google Scholar 

  28. E.A. Irene, J. Electrochem. Soc., 121. 1613 (1974).

    Article  Google Scholar 

  29. Y.J. van der Meulen and J.G. Cahill, J. Electronic Materials, 3, 371 (1974).

    Article  Google Scholar 

  30. E.A. Irene and R. Ghez, J. Electrochem. Soc., 124. 1757 (1977).

    Article  CAS  Google Scholar 

  31. A. Cros, J. Physique, 44, 707 (1983).

    CAS  Google Scholar 

  32. A. Franciosi, P. Soukiassian, P. Philip, S. Chang, A. Wall, A. Raisanen and N. Troullier, Phys. Rev. B, 35, 910 (1987).

    Article  CAS  Google Scholar 

  33. M.C. Asensio, E.G. Michel, E.M. Oellig, and R. Miranda, Appl. Phys. Lett., 51. 1714 (1987).

    Article  CAS  Google Scholar 

  34. P.J. Moller and J. He, J. Vac. Sci. Technol. A, S 996 (1987).

    Google Scholar 

  35. G. Abbati, L. Rossi, L. Calliari, L. Braicovich, I. Lindau and W.E. Spicer, J. Vac. Sci. Technol., 21, 409 (1982).

    Article  CAS  Google Scholar 

  36. P. Wetzel, C. Pirri, J. C. Peruchetti, D. Bolmont and G. Gewinner, J. Vac. Sci. Technol. A, 5 3359 (1987).

    Article  CAS  Google Scholar 

  37. P. Soukiassian, T.M. Gentle, M.H. Balshi and Z. Huryck, J. Appl. Phys., 60, 4339 (1986).

    Article  CAS  Google Scholar 

  38. È.A. Irene, “Semiconductor International”, p. 99, April 1983 and p. 92, June 1985.

    Google Scholar 

  39. M.A. Hopper, R.A. Clarke, and L. Young, J. Electrochem. Soc., 122, 1216 (1975).

    Article  CAS  Google Scholar 

  40. H. Z. Massoud, J. D. Plummer and E. A. Irene, J. Electrochem. Soc., 132, 1745, 2685 (1985).

    Article  CAS  Google Scholar 

  41. E.A. Lewis, E. Kobeda and E.A. Irene, in “Semiconductor Silicon 1986.’ H.R. Huff, T. Abe and B. Kolbeson, Eds. p. 416, The Electrochemical Soc., Pennington, N.J. (1986).

    Google Scholar 

  42. E.A. Lewis and E.A. Irene, J. Electrochem. Soc., 134, 2332 (1987).

    Article  CAS  Google Scholar 

  43. J.R. Ligenza, J. Phys. Chem., 65, 2111 (1961).

    Google Scholar 

  44. E. Kobeda and E.A. Irene, J. Vac. Sci. Technol., BS 15 (1987).

    Google Scholar 

  45. J.K. Srivastava and E.A. Irene, J. Electrochem. Soc., 132, 2815 (1985).

    Article  CAS  Google Scholar 

  46. E.A. Irene, E. Tierney and J. Angillelo, J. Electrochem. Soc., 129, 2594 (1982).

    Article  CAS  Google Scholar 

  47. E.P. EerNisse, Appl. Phys. Lett., 30, 290 (1977);

    Article  CAS  Google Scholar 

  48. E.P. EerNisse, Appl. Phys. Lett., 35, 8 (1979).

    Article  CAS  Google Scholar 

  49. E.A. Irene, J. Appl. Phys., 54, 5416 (1983).

    Article  Google Scholar 

  50. E. Kobeda and E. A. Irene, J. Vac. Sci. Technol. B, accepted for publication 1987.

    Google Scholar 

  51. R. Oren and S.K. Ghandi, J. Appl. Phys., 42, 752 (1971).

    Article  CAS  Google Scholar 

  52. S.A. Schafer and S.A. Lyon, J. Vac. Sci. Technol., 19, 494 (1981); 21, 422 (1982).

    Article  CAS  Google Scholar 

  53. Ian W. Boyd, Appl. Phys. Lett., 42, 728 (1983).

    Article  Google Scholar 

  54. F. Micheli and Ian W. Boyd, Appl. Phys. Lett., 51, 1149 (1987).

    Article  CAS  Google Scholar 

  55. E.M. Young and W.A. Tiller, Appl. Phys. Lett., 42, 63 (1983);

    Article  CAS  Google Scholar 

  56. E.M. Young and W.A. Tiller, Appl. Phys. Lett., 50, 46 (1987);

    Article  CAS  Google Scholar 

  57. E.M. Young and W.A. Tiller, Appl. Phys. Lett., 50, 80 (1987).

    Article  CAS  Google Scholar 

  58. P. Quenon, M. Wautelet, and M. Dumont, J. Appl. Phys., 61, 3112 (1987).

    Article  CAS  Google Scholar 

  59. E.A. Irene and E.A. Lewis, Appl. Phys. Lett., 51, 767 (1987).

    Article  CAS  Google Scholar 

  60. S.A. Shafer and S.A. Lyon, Appl. Phys. Lett., 47, 154 (1985).

    Article  Google Scholar 

  61. F.M. d’ Heurle, A. Cros, R. D. Frampton and E.A. Irene, Philos. Maq. B., 55, 291 (1987).

    Article  Google Scholar 

  62. R.D. Frampton, E.A. Irene and F.M. d’Heurle, J. Appl. Phys., 62 2972 (1987).

    Article  CAS  Google Scholar 

  63. M. Liehr, P.E. Schmid, F. K. Le Goues, and P.S. Ho, J. Vac. Sci. Technol., A4, 855 (1986).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1988 Springer Science+Business Media New York

About this chapter

Cite this chapter

Irene, E.A. (1988). Silicon Oxidation Studies: A Review of Recent Studies on Thin Film Silicon Dioxide Formation. In: Helms, C.R., Deal, B.E. (eds) The Physics and Chemistry of SiO2 and the Si-SiO2 Interface. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-0774-5_7

Download citation

  • DOI: https://doi.org/10.1007/978-1-4899-0774-5_7

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4899-0776-9

  • Online ISBN: 978-1-4899-0774-5

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics