Synthetic Poly(phosphates) Related to Nucleic and Teichoic Acids

  • Stanislaw Penczek
  • Pawel Klosinski

Abstract

Three methods leading to high molecular weight poly(alkylene phosphates) are described: ring-opening polymerization of cyclic monomers, polycondensation, and polyaddition of acids of phosphorus to diepoxides,. Three groups of cyclic compounds can be used for the ring-opening polymerization: cyclic phosphates, cyclic hydrogen phosphonates (phosphites), and cyclic phosphoramidites. Polymers obtained from these compounds can further be converted into the corresponding polyelectrolytes (polyalkylene phosphates). The polycondensation of diols with dialkyl hydrogen phosphonates (phosphites) or N,N,N′,N′-tetraalkyldiamides of phosphorous acid, yields the corresponding high molecular weight (Mn~3–4·104) poly(phosphites), were also converted into the acidic form.

Keywords

Teichoic Acid Anionic Polymerization Epoxy Ring Linear Poly Cyclic Phosphate 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer Science+Business Media New York 1990

Authors and Affiliations

  • Stanislaw Penczek
    • 1
  • Pawel Klosinski
    • 1
  1. 1.Center of Molecular and Macromolecular StudiesPolish Academy of SciencesSienkiewicza 112Poland

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