Abstract
A study of the effects of surface treatment of polypropylene on the deposition of thin metal films is presented. The polypropylene samples were treated in a low-pressure air plasma in one case and sputtered by argon ions in the other case. XPS was used to detect compositional surface modifications. Plasma treatment leads to surface oxidation, whereas the sputtering results in oxygen-free surfaces for in-situ analysis. After surface treatment, thin films of Mg, Ca and Ce were deposited. Depending on the surface treatment, we find indications for different bonding mechanisms and very different sticking probabilities. For the case of oxidized surfaces, the formation of a metal-oxygen-polymer complex is anticipated, whereas for oxygen-free surfaces a metal-carbon bond is likely to be formed.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
K.L. Mittal and J.R. Susko, Editors, “Metallized Plastics 1: Fundamental and Applied Aspects”, Plenum Press, New York, 1989.
D.M. Brewis and D. Briggs, Polymer 22, 7 (1981).
L.J. Gerenser, J. Adhesion Sci. Tech. 1, 303 (1987).
B.J. Bachman and M.J. Vasile, J. Vac. Sci. Technol. A7, 2709 (1989).
E.M. Liston, J. Adhesion 30, 199 (1989).
J.M. Burkstrand, J. Appl. Phys. 52, 4795 (1981).
N.J. Chou and C.H. Tang, J. Vac. Sci. Technol A2, 751 (1984).
J.L. Jordan, C.A. Kovac, J.F. Morar and R.A. Pollak, Phys. Rev. B 36, 1369 (1987).
J.G. Clabes, J. Vac. Sci. Technol A6, 2887 (1988).
L.J. Gerenser, J. Vac. Sei.Technol A6, 2897 (1988).
P. Bodö and J.-E. Sundgren, J. Appl. Phys. 60, 1161 (1986).
S. Nowak, H.-P. Haerri, L. Schlapbach and J. Vogt, Surface Interface Anal. 16, 418 (1990).
G. Praline, B.E. Koel, R.L. Hance, H.-I. Lee and J.M. White, J. Electron Spectr. Rel. Phen. 21, 17 (1980).
O. Gunnarsson and K. Schoenhammer, Phys. Rev. B 28, 4315 (1983).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1991 Springer Science+Business Media New York
About this chapter
Cite this chapter
Nowak, S., Mauron, R., Dietler, G., Schlapbach, L. (1991). XPS-Study of Metal-Polymer Interfaces After Polymer Surface Treatment by Ion and Plasma Techniques. In: Mittal, K.L. (eds) Metallized Plastics 2. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-0735-6_19
Download citation
DOI: https://doi.org/10.1007/978-1-4899-0735-6_19
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4899-0737-0
Online ISBN: 978-1-4899-0735-6
eBook Packages: Springer Book Archive