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Entanglement Effects in Polymer Solutions

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Polymers in Solution

Abstract

Viscoelastic behavior in polymer solutions is a reflection of dynamical processes at the molecular level. These processes are driven by Brownian motion, and they govern diffusion and the rate of rearrangement of chain orientation and conformation. Mechanical response and molecular relaxation go hand in hand. Properties which depend on large-scale chain motions are strong functions of the molecular architecture (chain length, long chain branching, etc.) at all levels of polymer concentration.

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Author information

Authors and Affiliations

  1. Corporate Research-Science Laboratories, Exxon Research and Engineering Co., Annandale, New Jersey, 08801, USA

    William W. Graessley

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  1. William W. Graessley
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Editors and Affiliations

  1. University of Pennsylvania, Philadelphia, Pennsylvania, USA

    William C. Forsman

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© 1986 Springer Science+Business Media New York

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Graessley, W.W. (1986). Entanglement Effects in Polymer Solutions. In: Forsman, W.C. (eds) Polymers in Solution. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-0465-2_3

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  • DOI: https://doi.org/10.1007/978-1-4899-0465-2_3

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4899-0467-6

  • Online ISBN: 978-1-4899-0465-2

  • eBook Packages: Springer Book Archive

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