Gold-197 Mössbauer Spectroscopy in the Characterization of Gold Compounds

  • R. V. Parish
Chapter
Part of the Modern Inorganic Chemistry book series (MICE, volume 1)

Abstract

It was demonstrated about ten years ago that 197Au Mössbauer spectroscopy would be useful in the characterization of gold compounds. Mössbauer,1 Shirley,2 and Nicholls; showed that, although neither the isomer shift (IS) nor the quadrupole splitting (QS) alone would allow gold(I) and gold(III) to be distinguished, when the two parameters are taken together diagnosis of the oxidation state is simple. At that time there was little interest in the chemistry of gold, but recently there has been a revival of activity, with the discovery of compounds of gold(II) and gold(V), the cluster compounds, and the ability of gold(I) to expand its coordination number from two to three or four. In all these cases, the Mössbauer spectra have been of value in characterizing the new compounds.

Keywords

Isomer Shift Quadrupole Splitting Gold Atom Dalton Trans Correlation Diagram 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer Science+Business Media New York 1984

Authors and Affiliations

  • R. V. Parish
    • 1
  1. 1.Department of ChemistryThe University of Manchester Institute of Science and TechnologyManchesterEngland

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