Abstract
Since organofunctional alkoxysilanes are often hydrolyzed before being applied to surfaces to function as coupling agents, it is important to understand their reactions with water and in water. Commercial practice is to apply silane coupling agents to glass from aqueous solutions of the alkoxysilanes. Organofunctional trialkoxysilanes hydrolyze in water and then condense to oligomeric siloxanols as described in Section 2.3.3. Stability and reactivity of aqueous solutions of silanes depend on many factors, including the nature of the organofunctional group on silicon. Since compounds with neutral organofunctional groups behave differently from those with cationic or anionic functions, they will be discussed separately.
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References
E. P. Plueddemann. SPI, 24th nn. Tech. Conf. Reinf. Plast. 19-A (1969).
C. W. Lentz. Inorg. Chem. 3, 574 (1964).
H. Ishida and J. L. Koenig. Appl Spectros. 32(5), 462 (1978).
H. Ishida and J. L. Koenig. Appl. Spectros. 32(5), 469 (1978).
B. W. Pearce, K. G. Mayhan, and J. F. Montle. Polymer 14 (Sept), 420 (1973).
K. A. Andrianov and B. A. Izmaylov. J. Organomet. Chem. 8, 435 (1967).
M. M. Sprung and F. O. Guenther. J. Polymer Sci. 28, 17 (1958).
J. F. Brown, Jr. and L. H. Vogt. J. Am. Chem. Soc. 84, 4313 (1965).
J. F. Brown, Jr. J. Am. Chem. Soc. 84, 4317 (1965).
H. Ishida, S. Naviroj, S. K. Tripathy, J. J. Fitzgerald, and J. L. Koenig. SPI, 36th Tech. Conf. Reinf. Plast. 2-C (1981).
C. H. Chiang, H. Ishida, and J. Koenig. J. Colloid Interface Sci. 74(2), 396 (1980).
O. K. Johannson, F. O. Stark, G. E. Vogel, and R. M. Fleishmann. J. Compos. Mater. 1, 278 (1970).
E. P. Plueddemann. Silylated Surfaces, D. E. Leyden & W. Collins, Ed., p. 40, Gordon & Breach, New York (1980).
B. M. Vanderbilt and R. E. Clayton (to Esso). U.S. Patent 3,350,345 (1967).
C. L. Frye (to Dow Corning). U.S. Patent 2,814,572 (1957).
E. P. Plueddemann (to Dow Corning). U.S. Patent 3,734,763 (1973).
A. J. Isquith, E. A. Abbott, and P. A. Walters. Appl. Microbiol. 24(6), 859 (1973).
R. Wong and J. C. Hood. AFML-TR-65-316 Summary Technical Report, July (1965).
E. P. Plueddemann (to Dow Corning). U.S. Patent 3,956,353 (1976).
E. P. Plueddemann (to Dow Corning). U.S. Patent 4,093,641 (1978).
R. C. Merrill and R. W. Spencer. J. Phys. Colloid Chem. 54, 506 (1950).
E. P. Plueddemann (to Dow Corning). U.S. Patent applied for.
A.N. Pines and E. A. Zientek (to UCC). U.S. Patent 3,198,820 (1965).
C. L. Frye, G. E. Vogel, and J. A. Hall. J. Am. Chem. Soc. 83, 996 (1961).
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Plueddemann, E.P. (1982). Aqueous Solutions of Silane Coupling Agents. In: Silane Coupling Agents. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-0342-6_3
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DOI: https://doi.org/10.1007/978-1-4899-0342-6_3
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