Fourier Transform Faradaic Admittance Measurements (FT-FAM): A Description and Some Applications
Abstract
Small amplitude a. c. measurements always have represented a significant component in the vast array of electrochemical relaxation techniques,* which include the familiar techniques of potential step chronoamperometry, current step chronopotentiometry, conventional “d. c.” polarography, linear sweep and cyclic voltammetry, normal and differential pulse polarography, square wave polarography, and a. c. polarography. Such techniques have been applied to a range of measurements from kinetic-mechanistic studies of electrode processes to highly precise and sensitive analytical applications.1–6 The power of a. c. measurements in kinetic and analytical applications became apparent in the late 1940’s and early 1950’s with the pioneering work of groups led by Gerischer7–9, Randies,10,11 and Breyer.12,13 The European school favored use of impedance bridge measurement methods to investigate kinetics of electrode processes, while the Australia workers introduced the concept of automatic recording of “a. c. polarograms”. The latter involved the superposition of a small amplitude a. c. potential (constant amplitude of 5–20 mV and constant frequency) on the normal d. c. ramp used in conventional polarography, and recording the alternating current magnitude as a function of the d. c. potential.
Keywords
Fourier Domain Drop Mercury Electrode Fast Fourier Trans Single Tablet Time Domain WaveformPreview
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Bibliography
- 1.Bard, A. J., and Faulkner, L. R., 1980, Electrochemical Methods, John Wiley and Sons, New York, N.Y.Google Scholar
- 2.Bard, A. J., Ed., Electroanalytical Chemistry, M. Dekker, Inc., New York, N.Y., ALL VOLUMES.Google Scholar
- 3.Bond, A. M., 1980, Modern Polarographic Methods in Analytical Chemistry, M. Dekker, Inc., New York, N.Y.Google Scholar
- 4.Delahay, P. and Tobias, C. W., Advances in Electrochemistry and Electrochemical Engineering, Wiley-Interscience, New York, N.Y., ALL VOLUMES.Google Scholar
- 5.Herovsky, J. and Kuta, J., 1966, Principles of Polarography, Academic Press, New York, N.Y.Google Scholar
- 6.MacDonald, D. D., 1977, Transient Techniques in Electrochemistry, Plenum Press, New York, N.Y.CrossRefGoogle Scholar
- 7.Gerischer, H., 1951, Zeit. Physik. Chem., 198, 286.Google Scholar
- 8.Gerischer, H., 1951, Zeit. Electrochem., 55, 98.Google Scholar
- 9.Gerischer, H., 1952, Zeit. Physik. Chem., 201, 55.Google Scholar
- 10.Randies, J. E. B., 1947, Disc. Faraday Soc, 1, 11, 47.CrossRefGoogle Scholar
- 11.Randies, J. E. B. and Somerton, K. W., 1952, Trans. Faraday Soc, 48, 937, 951.CrossRefGoogle Scholar
- 12.Breyer, B. and Gutman, F, 1947, Disc Faraday Soc, 1, 19.CrossRefGoogle Scholar
- 13.Breyer, B. and Bauer, H. H., 1963, Alternating Current Polargraphy and Tensammetry, Wiley-Interscience, New York, N.Y.Google Scholar
- 14.Delahay, P., 1954, New Instrumental Methods in Electrochemistry, Interscience, New York, N.Y.Google Scholar
- 15.Smith, D. E. in Bard, A. J., Ed., 1966, Electroanalytical Chemistry, Vol. I, M. Dekker, Inc., New York, N.Y., Chapt. 1.Google Scholar
- 16.Sluyters-Rehbach, M. and Sluyters, J. H. in Bard, A. J., Ed., 1970, Electroanalytical Chemistry, Vol. IV, M. Dekker, Inc., New York, N.Y, Chapt. 1.Google Scholar
- 17.Delahay, P., 1966, J. Electrochem. Soc, 113, 967 and discussion.CrossRefGoogle Scholar
- 18.Timmer, B., Sluyters-Rehbach, M. and Sluyters, J. H., 1970, J. Electroanal. Chem., 24, 287.CrossRefGoogle Scholar
- 19.Brown, E. R., McCord, T. G., Smith, D. E. and DeFord, D. D., 1966, Anal. Chem., 38, 1119.CrossRefGoogle Scholar
- 20.Brown, E. R., Smith, D. E. and Booman, G. L., 1968, Anal. Chem., 40, 1411.CrossRefGoogle Scholar
- 21.Brown, E. R., Hung, H. L., McCord, T. G., Smith, D. E., and Booman, G. L., 1968, Anal. Chem., 40, 1424.CrossRefGoogle Scholar
- 22.Huebert, B. J. and Smith, D. E., 1972, Anal. Chem., 44, 1179.CrossRefGoogle Scholar
- 23.Pilla, A. A., 1970, J. Electrochem. Soc., 117, 467.CrossRefGoogle Scholar
- 24.Pilla, A. A., 1971, J. Electrochem. Soc., 118, 702.CrossRefGoogle Scholar
- 25.deLevie, R., Thomas, J. W. and Abbey, K. M., 1975, J. Electroanal. Chem., 62, 111.CrossRefGoogle Scholar
- 26.Pilla, A. A., in Mattson, J. S., MacDonald, J. D., Jr. and Mark, H. B., Jr., 1972, Computers in Chemistry and Instrumentation, Vol. 2, M. Dekker, New York, N.Y., Chapt. 6.Google Scholar
- 27.Schwall, R. J., Bond, A. M., Loyd, R. J., Larsen, J. G. and Smith, D. E., 1977, Anal. Chem., 49, 1797.CrossRefGoogle Scholar
- 28.K. F. Drake, 1979, Doctoral Dissertation, Northwestern University, Evanston, IL.Google Scholar
- 29.Smith, D. E., 1971, CRC Critical Rev. Anal. Chem., 2, 247.Google Scholar
- 30.Smith, D. E., Borchers, C. E. and Loyd, R. J., 1971, Physical Methods in Chemistry, Part 1B, Wiley and Sons, Inc., New York, N.Y., Chapt. 8.Google Scholar
- 31.Creason, S. C. and Smith, D. E., 1973, Anal. Chem., 45, 2401.CrossRefGoogle Scholar
- 32.Birke, R. L., 1971, Anal. Chem., 43, 1253.CrossRefGoogle Scholar
- 33.Gabrielli, C. and Keddam, M., 1974, Electrochem. Acta., 19, 355.CrossRefGoogle Scholar
- 34.Bechet, B., Epelboin, I. and Keddam, M., 1977, J. Electroanal. Chem., 76, 129.CrossRefGoogle Scholar
- 35.Brigham, E. O., 1974, The Fast Fourier Transform, Prentice-Hall, Inc., Englewood Cliffs, N.J.Google Scholar
- 36.Gold, B and Rader, C. M., 1969, Digital Processing of Signals, McGraw-Hill, New York, N.Y.Google Scholar
- 37.Otnes, R. K. and Enochson, L., 1971, Digital Time Series Analysis, Wiley-Interscience, New York, N.Y.Google Scholar
- 38.Creason, S. C., Hayes, J. W. and Smith, D. E., 1973, J. Electroanal. Chem., 47, 9.CrossRefGoogle Scholar
- 39.Matsuda, H., 1958, Zeit. Elektrochem., 62, 977.Google Scholar
- 40.Lephardt, J. O., in Griffiths, P., Ed., 1978, Transform Techniques in Chemistry, Plenum Press, New York, N.Y., Chapt. 11.Google Scholar
- 41.Griffiths, P. R., 1975, Appl. Spectrosc., 29, 11.CrossRefGoogle Scholar
- 42.Horlick, G. and Yuen, W. K., 1976, Anal. Chem., 48, 1643.CrossRefGoogle Scholar
- 43.Bond, A. M., O’Halloran, R. J., Ruzic, I. and Smith, D. E., 1976, Anal. Chem., 48, 872.CrossRefGoogle Scholar
- 44.Erdy-Gruz, T. and Volmer, M., 1930, Zeit. Physik. Chem., 150A, 203.Google Scholar
- 45.Kirmse, K. W. and Westerberger, A. W., 1971, Anal. Chem., 43, 1035.CrossRefGoogle Scholar
- 46.Horlick, G., 1972, Anal. Chem., 44, 943.CrossRefGoogle Scholar
- 47.Grabaric, B. S., O’Halloran, R. J. and Smith, D. E., Anal. Chim. Acta., (Section on Computer Techniques and Optimization).Google Scholar
- 48.deLeeuwe, R., Sluyters-Rehbach, M. and Sluyters, J. H., 1969, Electrochim. Acta., 14, 1183.CrossRefGoogle Scholar
- 49.Rohko, T., Kogoma, M. and Aoyagui, S., 1972, J. Electroanal. Chem., 38, 45.CrossRefGoogle Scholar
- 50.Peover, M. E. and Powell, J. S., 1969, J. Electroanal. Chem., 20, 427.CrossRefGoogle Scholar
- 51.Bond, A. M., Schwall, R. J. and Smith, D. E., 1977, J. Electro-Chem., 85, 231.CrossRefGoogle Scholar
- 52.Grabaric, B. S. and Smith, D. E., in preparation.Google Scholar
- 53.O’Halloran, R. J., Schaar, J. C. and Smith, D. E., 1978, Anal. Chem., 50, 1073.CrossRefGoogle Scholar
- 54.Hayes, J. W. and Smith, D. E., 1980, J. Electroanal. Chem., 114, 283.CrossRefGoogle Scholar
- 55.Hayes, J. W. and Smith, D. E., 1980, J. Electroanal. Chem., 114, 293.CrossRefGoogle Scholar
- 56.Ruzic, I., Smith, D. E. and Feldberg, S. W., 1974, J. Electro-Anal. Chem., 52, 157.CrossRefGoogle Scholar
- 57.Schwall, R. J., Ruzic, I. and Smith, D. E., 1975, J. Electroanal. Chem., 60, 117.CrossRefGoogle Scholar
- 58.Schwall, R. J. and Smith, D. E., 1978, J. Electroanal. Chem., 94, 227.CrossRefGoogle Scholar
- 59.Matusinovic, T. and Smith, D. E., 1979, J. Electroanal. Chem., 98, 133.CrossRefGoogle Scholar
- 60.Matusinovic, T. and Smith, D. E., in press, Inorg. Chem.Google Scholar
- 61.Candlin, J. P., Halperin, J. and Trimm, D. L., 1964, J. Amer. Chem. Soc., 86, 1019.CrossRefGoogle Scholar
- 62.Faragi, M. and Feder, A., 1973, Inorg. Chem., 12, 236.CrossRefGoogle Scholar
- 63.Schwall, R. J., Ruzic, I. and Smith, D. E., 1975, J. Electroanal. Chem., 60, 117.CrossRefGoogle Scholar
- 64.Dulz, G. and Sutin, N., 1964, J. Amer. Chem. Soc., 86, 829.CrossRefGoogle Scholar
- 65.Flato, J. B., 1972, Anal. Chem., 44(11), 75A.CrossRefGoogle Scholar
- 66.Schwall, R. J., Bond, A. M. and Smith, D. E., 1977, Anal. Chem., 49, 1805.CrossRefGoogle Scholar
- 67.Woodson, A. L. and Smith, D. E., 1970, Anal. Chem., 42, 242.CrossRefGoogle Scholar
- 68.Taira, A. and Smith, D.E., 1978, J. Assoc. Official Anal. Chem., 61, 941.Google Scholar
- 69.Schaar, J. C. and Smith, D. E., 1979, J. Electroanal. Chem., 100, 145.CrossRefGoogle Scholar
- 70.Schaar, J. C, 1981, Doctoral Dissertation, Northwestern University, Evanston, IL.Google Scholar
- 71.Reprinted with permission of ACS, 1963, Anal. Chem., 35, 1811.Google Scholar
- 72.Reprinted with permission of ACS, 1973, Anal. Chem., 45, 277.Google Scholar
- 73.Reprinted with permission of ACS, 1978, Anal. Chem., 50, 1391.Google Scholar
- 74.Reprinted with permission of Elsevier Scientific Publishing Company, 1981, Anal. Chim. Acta., ACA Comp., 133, 349.Google Scholar
- 75.Reprinted with permission of Elsevier Scientific Publishing Company, J. Electroanal. Chem., in press.Google Scholar