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Fourier Transform Faradaic Admittance Measurements (FT-FAM): A Description and Some Applications

  • Chapter
Fourier, Hadamard, and Hilbert Transforms in Chemistry

Abstract

Small amplitude a. c. measurements always have represented a significant component in the vast array of electrochemical relaxation techniques,* which include the familiar techniques of potential step chronoamperometry, current step chronopotentiometry, conventional “d. c.” polarography, linear sweep and cyclic voltammetry, normal and differential pulse polarography, square wave polarography, and a. c. polarography. Such techniques have been applied to a range of measurements from kinetic-mechanistic studies of electrode processes to highly precise and sensitive analytical applications.1–6 The power of a. c. measurements in kinetic and analytical applications became apparent in the late 1940’s and early 1950’s with the pioneering work of groups led by Gerischer7–9, Randies,10,11 and Breyer.12,13 The European school favored use of impedance bridge measurement methods to investigate kinetics of electrode processes, while the Australia workers introduced the concept of automatic recording of “a. c. polarograms”. The latter involved the superposition of a small amplitude a. c. potential (constant amplitude of 5–20 mV and constant frequency) on the normal d. c. ramp used in conventional polarography, and recording the alternating current magnitude as a function of the d. c. potential.

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Author information

Authors and Affiliations

  1. Department of Chemistry, Northwestern University, Evanston, Illinois, 60201, USA

    Donald E. Smith

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  1. Donald E. Smith
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Editors and Affiliations

  1. The Ohio State University, Columbus, Ohio, USA

    Alan G. Marshall

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Smith, D.E. (1982). Fourier Transform Faradaic Admittance Measurements (FT-FAM): A Description and Some Applications. In: Marshall, A.G. (eds) Fourier, Hadamard, and Hilbert Transforms in Chemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-0336-5_15

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  • DOI: https://doi.org/10.1007/978-1-4899-0336-5_15

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