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Acid Corrosion Inhibition of Nickel by Some Organic/Macrocyclic Compounds

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Science and Technology of Polymers and Advanced Materials

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Abstract

The corrosion inhibition of nickel in 0.5 M sulfuric acid solution by 2-(triphenyl phosphoranylidene) succinic anhydride (2TPSA),1,4,8,11 tetraazocyclotetradecane (cyclam), and N, N′-bis(2-aminoethyl)-1,3-propane diamine (2,3,2 tet.) have been investigated using DC polarization technique.

The anodic polarization curves of nickel in 0.5 M H2SO4 at different concentrations of the three inhibitors were recorded at room temperature. The critical current density values were used to calculate the percentage inhibition for each inhibitor concentration. The results were compared with fits obtained from the application of Langmuir, Frumkin, Flory-Huggins isotherm, and also from the application of kinetic-thermodynamic model. The results obtained were correlated to the chemical structure and the macrocyclic effect of the inhibitors.

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References

  1. Reshetnikov, “Metall. Kokskhim”, 89 (1986) p. 14.

    CAS  Google Scholar 

  2. Aramaki, Boshoku Gijutsu, Corros. Eng., 36 (1987), p. 444.

    Google Scholar 

  3. Sastry, R. Packwood, werkst, “Korros.”, 38 (1987) p. 77.

    Article  Google Scholar 

  4. R. Abd El-Gulil, A. Abd El Fattah, “Corros. Prev. Control”, 34 (1987) p. 149.

    CAS  Google Scholar 

  5. Aramaki, T. Mochizuki, H, H, Nishiha, “10th Inter. Congress on Met. Corros., Madras, India, vol. 3 Oxford and IBH, New Delhi, 1988, p. 2759.

    Google Scholar 

  6. Aramaki, Kunit Sugu; Nishihava, Hirdshi (Fac. Sci. Technolo., Keio. Univ, Kokohama, Japan 223). J. Elec-trochem. SOC. 1987, 134 (5), 1059-64 (Eng.).

    Google Scholar 

  7. Muralidharan, M. Verashanmugani, G. Kalaignan, Bull. Electrochem., 1 (1985), p. 373.

    CAS  Google Scholar 

  8. Fillppo, A. Rossi, M. Spezziga, Proceedings of 6th Europ. symp. on Comos. inhibit., Ferrara, Italy, University of Ferrara, (1985).

    Google Scholar 

  9. K. Kishi, S. Lkeda, Application of surface science, 5 (1980) p. 37.

    Article  CAS  Google Scholar 

  10. El-Awady, B.A. Abd El-Nabey, S.G. Aziz, M. Khalifa and H. Al. Ghamdey. “International Jour. Chem.” vol 1, No. 4 (1990). 169–179.

    Google Scholar 

  11. El-Awady, BN.A. Abd-El-Nabey, and S.G. Aziz, “Electrochem. Soc.” vol. 139 No. 8 (1992).

    Google Scholar 

  12. Khamis, F. Bellucci. R.M. Latanision, and E.S.H. El-Ashry “Corrosion” pp. 677-686 (1991).

    Google Scholar 

  13. Frumkin, “Z. Phys. Chem.”, 116 (1925) p. 466.

    CAS  Google Scholar 

  14. Dhar. B. Conway, K. Joshi, “Electrochemica Ata.” 18 (1973) p. 789.

    Article  Google Scholar 

  15. Al-Andouli, F. El-Taib, F. El-Nizami and B. Ateya. Extended Abstracts of the Electrochemical Society Fall meeting, Chicago, Illinas, Electrochem. SOC, Pennington, NJ, p. 188 (1988).

    Google Scholar 

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Authors and Affiliations

  1. Department of Material Science, Institute of Graduate Studies and Research, Alexandria University, 163 Horreya Av., Alexandria, Egypt

    F. M. Mahgoub & A. El-Hefnawy

  2. Department of Chemistry, Faculty of Science, Alexandria University, Egypt

    B. A. Abd-El-Nabey & M. Khalifa

Authors
  1. F. M. Mahgoub
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  2. B. A. Abd-El-Nabey
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  3. M. Khalifa
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  4. A. El-Hefnawy
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Editor information

Editors and Affiliations

  1. Photonics Research Laboratory, State University of New York, Buffalo, New York, USA

    Paras N. Prasad (Director) (Director)

  2. Department of Chemistry, University of Cincinnati, Cincinnati, Ohio, USA

    James E. Mark (Distinguished Research Professor) (Distinguished Research Professor)

  3. Institute of Graduate Studies, Alexandria University, Alexandria, Egypt

    Sherif H. Kandil

  4. Naval Research Laboratory, Washington, D.C., USA

    Zakya H. Kafafi

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© 1998 Springer Science+Business Media New York

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Mahgoub, F.M., Abd-El-Nabey, B.A., Khalifa, M., El-Hefnawy, A. (1998). Acid Corrosion Inhibition of Nickel by Some Organic/Macrocyclic Compounds. In: Prasad, P.N., Mark, J.E., Kandil, S.H., Kafafi, Z.H. (eds) Science and Technology of Polymers and Advanced Materials. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-0112-5_16

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  • DOI: https://doi.org/10.1007/978-1-4899-0112-5_16

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4899-0114-9

  • Online ISBN: 978-1-4899-0112-5

  • eBook Packages: Springer Book Archive

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