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Template Polymerization of Dimethylaminoethyl Methacrylate in the Presence of Poly(Acrylamide-Acrylic Acid) Induced by Gamma Radiation and its use for Removal of Metal Ions

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Science and Technology of Polymers and Advanced Materials

Abstract

The polymeric material of poly (acrylamide-acrylic acid-dimethylaminoethyl methacrylate) “PAM-AA-DMAEM” was prepared by gamma radiation-induced polymerization of dimethylaminoethyl methacrylate (DMAEM) in the presence of prepared poly(acrylamide-acrylic acid) “PAM-AA” as a template polymer using a template polymerization technique.

The effect of gamma radiation on the polymerization process showed that the conversion increases with increasing the radiation dose. The obtained polymer is water-soluble polymer at low doses <10 KGy. On increasing the radiation dose the polymer was converted into a gel with the swelling degree vary from 15–36. It was found that the capacities of the obtained polymeric gels toward Cu2+ increase with increasing the absorbed dose, monomer concentration and the template polymer/monomer molar ratio.

Spectroscopic studies showed that the mechanism of the floc formation is due to the interaction between the polymer and copper sulphate is a bond formation between the active groups of polymer chains and ions of copper sulphate. The amide and tertiary amino groups form complex with Cu2+ while carboxylic group interacts with ion through ion-exchange mechanism.

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Authors and Affiliations

  1. Nucl. Chem. Dept. Hot Laboratories Centre, Atomic Energy Authority, P. Code 13759, Egypt

    T. Siyam & Z. H. Abd-Elatif

  2. National Resarch Centre, Dokki, Giza, Egypt

    Z. H. Abd-Elatif

Authors
  1. T. Siyam
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  2. Z. H. Abd-Elatif
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Editor information

Editors and Affiliations

  1. Photonics Research Laboratory, State University of New York, Buffalo, New York, USA

    Paras N. Prasad (Director) (Director)

  2. Department of Chemistry, University of Cincinnati, Cincinnati, Ohio, USA

    James E. Mark (Distinguished Research Professor) (Distinguished Research Professor)

  3. Institute of Graduate Studies, Alexandria University, Alexandria, Egypt

    Sherif H. Kandil

  4. Naval Research Laboratory, Washington, D.C., USA

    Zakya H. Kafafi

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Siyam, T., Abd-Elatif, Z.H. (1998). Template Polymerization of Dimethylaminoethyl Methacrylate in the Presence of Poly(Acrylamide-Acrylic Acid) Induced by Gamma Radiation and its use for Removal of Metal Ions. In: Prasad, P.N., Mark, J.E., Kandil, S.H., Kafafi, Z.H. (eds) Science and Technology of Polymers and Advanced Materials. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-0112-5_15

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  • DOI: https://doi.org/10.1007/978-1-4899-0112-5_15

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4899-0114-9

  • Online ISBN: 978-1-4899-0112-5

  • eBook Packages: Springer Book Archive

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