Spectroscopy of the Amide-I Modes of Acetanilide

  • Irving J. Bigio
  • Alwyn C. Scott
  • Clifford T. Johnston
Part of the NATO ASI Series book series (NSSB, volume 243)

Abstract

In 1973, Careri published evidence of an “unconventional” amide-I (CO stretching) band at 1650 cm−1 in crystalline acetanilide (CH3CONHC6H5), abbreviated ACN.1 Following the “soliton” theory of Davydov,2 this band has been assigned to a “self-trapped state” in which CO vibrational energy is localized near a single ACN molecule through interactions with lattice phonons.3, 4 A complementary “polaron” picture5 of this self-trapped state has been presented recently by Alexander and Krumhansl.6, 7

Keywords

Raman Spectrum Wave Packet Color Center Polaron State Acoustic Phonon Mode 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    G. Careri, in Cooperative Phenomena, edited by H. Haken and M. Wagner (Springer, Berlin, 1973) p. 391.CrossRefGoogle Scholar
  2. 2.
    A.S. Davydov, Sov. Phys. Usp. 25, p.898 (1982; Usp. Fiz. Nauk 138, p.603 (1982).Google Scholar
  3. 3.
    G. Careri, U. Buontempo, F. Galluzzi, A. C. Scott, E. Gratton, and E. Shyamsunder, Phys. Rev. B 30, 4689 (1984).ADSCrossRefGoogle Scholar
  4. 4.
    J. C. Eilbeck, P. S. Lomdahl, and A. C. Scott, Phys. Rev. B 30, 4703 (1984).ADSCrossRefGoogle Scholar
  5. 5.
    T. Holstein, Ann. Phys. (N.Y.) 8, p.325 (1959).ADSMATHCrossRefGoogle Scholar
  6. 6.
    D. M. Alexander and J. A. Krumhansl, Phys. Rev. B 33, 7172 (1986).ADSCrossRefGoogle Scholar
  7. 7.
    J. A. Krumhansl, in Energy Transfer Dynamics, edited by T. W. Barrett and H. A. Pohl (Springer, Berlin, 1987) p. 174.CrossRefGoogle Scholar
  8. 8.
    G. Careri, E. Gratton and E. Shyamsunder, Phys. Rev. B 37, p.4048 (1988).ADSGoogle Scholar
  9. 9.
    Alwyn C. Scott, Irving J. Bigio and Clifford T. Johnston, Phys. Rev. B 39, p. 12883 (1989).ADSCrossRefGoogle Scholar
  10. 10.
    H. Fröhlich, Adv. Phys. 3, 325 (1954).ADSCrossRefGoogle Scholar
  11. 11.
    I. S. Gradshteyn and I. M. Ryzhik, Table of Integrals Series and Products (Academic, New York 1965).Google Scholar
  12. 12.
    P. M. Morse and H. Feshbach, Methods of Theoretical Physics (McGraw-Hill, New York, 1953) p. 784.MATHGoogle Scholar
  13. 13.
    K. Huang and A. Rhys, Proc. Roy. Soc. (London) 204A, 406 (1950).ADSGoogle Scholar
  14. 14.
    M. Lax, J. Chem. Phys. 20, 1752 (1952).MathSciNetADSCrossRefGoogle Scholar
  15. 15.
    R. C. O’Rourke, Phys. Rev. 91, 265 (1953).ADSMATHCrossRefGoogle Scholar
  16. 16.
    J. J. Markham, Rev. Mod. Phys. 31, 956 (1959).ADSMATHCrossRefGoogle Scholar
  17. 17.
    T. H. Keil, Phys. Rev. A601, 140 (1965).Google Scholar
  18. 18.
    D. B. Fitchen, in Physics of Color Centers, edited by W. B. Fowler (Academic, New York, 1968) p. 293.Google Scholar
  19. 19.
    A. C. Scott, E. Gratton, E. Shyamsunder, and G. Careri, Phys. Rev. B 32, 5551 (1985).ADSCrossRefGoogle Scholar
  20. 20.
    V. P. Gerasimov, Opt. Spektrosk. 43, 705 (1977) [Opt. Spectros. (USSR) 43, 417 (1978)].Google Scholar
  21. 21.
    A. C. Scott, in Synergetics of the Brain, edited by E. Bazar, F. Flohr, H. Haken, and A. J. Mandell (Springer, Berlin, 1983) p. 345.CrossRefGoogle Scholar
  22. 22.
    A. S. Davydov, Biology and Quantum Mechanics (Pergamon, New York, 1982).Google Scholar

Copyright information

© Springer Science+Business Media New York 1990

Authors and Affiliations

  • Irving J. Bigio
    • 1
  • Alwyn C. Scott
    • 2
  • Clifford T. Johnston
    • 3
  1. 1.Los Alamos National LaboratoryLos AlamosUSA
  2. 2.Department of MathematicsThe University of ArizonaTucsonUSA
  3. 3.University of FloridaGainsvilleUSA

Personalised recommendations