The Role of Selective Two-Dimensional NMR Correlation Methods in Supplementing Computer-Supported Multiplet Analysis by MARCO POLO

  • Lyndon Emsley
  • Geoffrey Bodenhausen
Chapter
Part of the NATO ASI Series book series (NSSA, volume 225)

Abstract

Computer-supported analysis of two-dimensional correlation spectra encounters a number of obstacles which are due, in the simplest case, to insufficient digital resolution, and, in more severe cases, to fundamental ambiguities in multiplet patterns. In this paper, we discuss various strategies involving selective two-dimensional experiments that are designed to circumvent these limitations and lift ambiguities.

Keywords

Transverse Magnetization Cosy Spectrum Coupling Network Digital Resolution Selective Experiment 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    J. C. Hoch, S. Hengyi, M. Kjær, S. Ludvigsen, and P. M. Poulsen, Carlsberg Res. Commun. 52, 111 (1987).CrossRefGoogle Scholar
  2. 2.
    Z. L. Mádi, C. Griesinger, and R. R. Ernst, J. Am. Chem. Soc. 112, 2908 (1990).CrossRefGoogle Scholar
  3. 3.
    B. U. Meier, Z. L. Mádi, and R. R. Ernst, J. Magn. Reson. 74, 565 (1987).Google Scholar
  4. 4.
    M. Novič, and G. Bodenhausen, Anal. Chem. 60, 582 (1988).CrossRefGoogle Scholar
  5. 5.
    M. Novic, U. Eggenberger, and G. Bodenhausen, J. Magn. Reson. 77, 394 (1988).Google Scholar
  6. 6.
    P. Pfändler, G. Bodenhausen, B. U. Meier, and R. R. Ernst, Anal. Chem. 57, 2510 (1985).CrossRefGoogle Scholar
  7. 7.
    P. Pfändler and G. Bodenhausen, J. Magn. Reson. 79, 99 (1988).Google Scholar
  8. 8.
    P. Pfändler and G. Bodenhausen, Magn. Reson. Chem. 26, 888 (1988).CrossRefGoogle Scholar
  9. 9.
    P. Pfändler and G. Bodenhausen, J. Magn. Reson. 87, 26 (1990).Google Scholar
  10. 10.
    R. Brüschweiler, J. C. Madsen, C. Griesinger, O. W. Sørensen, and R. R. Ernst, J. Magn. Reson. 73, 380 (1987).Google Scholar
  11. 11.
    J. Cavanagh, J. P. Waltho, and J. Keeler, J. Magn. Reson. 74, 386 (1987).Google Scholar
  12. 12.
    L. Emsley, and G. Bodenhausen, J. Magn. Reson. 82, 211 (1989).Google Scholar
  13. 13.
    L. Emsley, P. Huber, and G. Bodenhausen, Angew. Chem. 102, 576 (1990); Angew. Chem. Int. Ed. Engl. 29, 517 (1990).CrossRefGoogle Scholar
  14. 14.
    H. Oschkinat, A. Pastore, P. Pfändler, and G. Bodenhausen, J. Magn. Reson. 69, 559 (1986).Google Scholar
  15. 15.
    H. Kessler, W. Bermel, A. Friedrich, G. Krack, and W. E. Hull, J. Am. Chem. Soc. 104, 6297 (1982).CrossRefGoogle Scholar
  16. 16.
    H. Kessler, H. R. Loosli, and H. Oschkinat, Helv. Chim. Acta 68, 661 (1985).CrossRefGoogle Scholar
  17. 17.
    L. Emsley and G. Bodenhausen, Chem. Phys. Lett. 165, 469 (1990).CrossRefGoogle Scholar
  18. 18.
    L. Emsley and G. Bodenhausen, J. Am. Chem. Soc. 113, 3309 (1991).CrossRefGoogle Scholar
  19. 19.
    U. Eggenberger, and G. Bodenhausen, Angew. Chem. 102, 392 (1990).CrossRefGoogle Scholar
  20. U. Eggenberger, and G. Bodenhausen, Angew. Chem. Int. Ed. Engl. 29, 374 (1990).CrossRefGoogle Scholar
  21. 20.
    G. J. Kleywegt, R. M. J. N. Lamerichs, R. Boelens, and R. Kaptein, J. Magn. Reson. 85, 186 (1989).Google Scholar

Copyright information

© Springer Science+Business Media New York 1991

Authors and Affiliations

  • Lyndon Emsley
    • 1
  • Geoffrey Bodenhausen
    • 1
  1. 1.Section de ChimieUniversité de LausanneLausanneSwitzerland

Personalised recommendations