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Solution Thermodynamics of Non-Ionic Water-Soluble Polymers

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Chemistry and Technology of Water-Soluble Polymers

Abstract

Non-ionic water soluble polymers exhibit solution properties which often differ strikingly from those of other polymers in organic solvents. The reasons for this difference in behaviour are not fully understood. This presentation is intended to gather together some details of the uncommon properties, rather than to be an in depth interpretation of the data. Three questions will be discussed:-

  1. (1)

    Which quantities can be measured?

  2. (2)

    What is the state of polymer solution theories and how are they able to present an appropriate interpretation of the behaviour of aqueous solutions?

  3. (3)

    What are the reasons for the deviations in behaviour?

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References

Suggested General Reading

  1. P.J. Flory, ‘Principles of Polymer Chemistry’. 1953:Ithaca, New York. Cornell University Press. Chapters 12 and 13.

    Google Scholar 

  2. H. Tompa, ‘Polymer Solutions’. 1956:London. Butterworths. Chapters 3-8.

    Google Scholar 

  3. P. Molyneux, in ‘Water: A Comprehensive Treatise’, (edited by F. Franks). 1975:New York. Plenum Press. Vol. 4, Chapter 7.

    Google Scholar 

  4. R. Koningsveld, Ber. Bunsen-Gesellschaft, 1977, 10, 959.

    Article  Google Scholar 

Specific References

  1. Th.G. Scholte, J.polymer Sci., A-2, 1971, 9, 1553.

    CAS  Google Scholar 

  2. S. Saiki, N. Kuwahara, M. Nakata and M. Kaneko, Polymer, 1976, 17, 685.

    Article  Google Scholar 

  3. K.W. Derham, J. Goldsborough, M. Gordon, R. Koningsveld and L.A. Kleintjens, Makromolek.Chem.Suppl., 1975, 1, 401; K.W. Derham, J. Goldsborough and M. Gordon, Pure Appl.Chem.,1974, 38, 97.

    Article  Google Scholar 

  4. M. Gordon, P.A. Irvine and J. W. Kennedy, J.polymer.Sci., Part C, 1977, 61, 199.

    Article  CAS  Google Scholar 

  5. T.A. Orofino and P.J. Flory, J.chem.Phys., 1957, 26, 1067.

    Article  Google Scholar 

  6. R. Koningsveld and L.J. Kleintjens, Macromolecules, 1971, 4, 637.

    Article  CAS  Google Scholar 

  7. P.J. Flory, R.A. Orwoll and A. Vrij, J. Amer.chem.Soc.,1964,86,3507,3515.

    Article  CAS  Google Scholar 

  8. H. Höcker, H. Shih and P.J. Flory, Trans.Faraday Soc., 1971, 67, 2275.

    Article  Google Scholar 

  9. R. Koningsveld, L.A. Kleintjens and H.R. Shultz, J.polymer.Sci., A-2, 1970, 8, 1261.

    CAS  Google Scholar 

  10. R. Koningsveld, W.H. Stockmayer, J. W. Kennedy and L.A. Kleintjens, Macromolecules, 1974, 7, 73.

    Article  CAS  Google Scholar 

  11. G. Rehage, Kunststoffe, 1963, 53, 605.

    CAS  Google Scholar 

  12. N. Sarkar, J.appl.polymer Sci., 1979, 24, 1073.

    Article  CAS  Google Scholar 

  13. W. Burchard, E. Husemann, and B. Pfannemüller, Makromolek.Chem., 1963, 59, 1, 16.

    Article  Google Scholar 

  14. M.A. Cohen Stuart, Ph.D. Thesis, Wageningen (The Netherlands), 1980.

    Google Scholar 

  15. G.N. Malcolm and J. S. Rowlinson, Trans.Faraday Soc., 1957, 53, 921.

    Article  CAS  Google Scholar 

  16. I. Prigogine and R. Defay, ‘Chemical Thermodynamics’. 1954:London. Longmans.

    Google Scholar 

  17. D. Patterson and G. Delmas. Disc.Faraday Soc.,1970, 49, 98.

    Article  Google Scholar 

  18. J. A. Barker and W. Fock, Disc.Faraday Soc, 1953, 15, 188.

    Article  Google Scholar 

  19. F.E. Bailey and R.W. Callard, J.appl.polymer.Sci., 1959, 1, 56, 373.

    Article  CAS  Google Scholar 

  20. M. Rösch, Kolloid Z., 1956, 147, 78.

    Article  Google Scholar 

  21. F. Franks, This volume.

    Google Scholar 

  22. See, e.g. C. Tanford, ‘The Hydrophobic Effect’, 1973:New York. John Wiley & Sons.

    Google Scholar 

  23. H.S. Frank, in ‘Water: A Comprehensive Treatise’, (edited by F. Franks). 1972:New York. Plenum Press. Volume 1. Chapter 14.

    Google Scholar 

  24. G. Nemethy and H.A. Scheraga, J.chem.Phys., 1962, 36, 1733, 3382,3409; 1964, 41, 680.

    Article  Google Scholar 

  25. W.F. Polik and W. Burchard, Macromolecules: submitted for publication.

    Google Scholar 

  26. F.E. Bailey and J. V. Koleske, ‘Poly(ethylene oxide)’. 1976:New York. Academic Press. Chapter 4.

    Google Scholar 

  27. W. Burchard, Thesis (Habilitation), Freiburg 1966.

    Google Scholar 

  28. See: P.-G. de Gennes, ‘Scaling Concepts in Polymer Physics’. 1979:Ithaca, New York. Cornell University Press.

    Google Scholar 

  29. F.R. Schierbaum, W. Vorwerg and E.N. Belavtseva, Europhys.Conferences Abstr., 1979, 30, 225.

    Google Scholar 

  30. E.E. Brando, E.N. Belavtseva, E.F. Titoca, I.G. Plashchina, V.L. Krylov, V.B. Tolstognzov, F.R. Schierbaum, M. Richter and G. Berth, Stärke, 1979, 31, 188.

    Article  Google Scholar 

  31. W. Vorwerg and F.R. Schierbaum: Prague Meeting on Macromolecules, 7th. Discussion Conference, 1980. ‘Polymer Networks’, Abstract C 15.

    Google Scholar 

  32. M. Peuscher, Ph.D. Thesis, Freiburg 1982.

    Google Scholar 

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Burchard, W. (1983). Solution Thermodynamics of Non-Ionic Water-Soluble Polymers. In: Finch, C.A. (eds) Chemistry and Technology of Water-Soluble Polymers. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-9661-2_7

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  • DOI: https://doi.org/10.1007/978-1-4757-9661-2_7

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4757-9663-6

  • Online ISBN: 978-1-4757-9661-2

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