Abstract
Polyelectrolytes are macromolecules which, in a suitable polar solvent, usually water, carry a large number of ionized or ionizable groups, often one per monomer unit. Under well defined conditions the macromolecules will bear a considerable charge distributed along the chain (the ‘fixed charges’) accompanied by an equivalent number of small ions of opposite sign (the ‘counterions’) in solution. The charge-bearing groups may all be identical or not, but we shall here treat only homopolyelectolytes, or polyelectrolytes behaving as such. Polyelectrolytes can be of natural origin (nucleic acids, many polysaccharides, etc.) or synthetically prepared (e.g. polyacrylic acid, polyvinyl pyridinium bromide, poly(maleic acid-vinylethylether)-copolymer, etc.).
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References
The following books review the physical chemical properties of polyelectrolyte solutions and their theoretical treatment: a. C. Tanford, ‘Physical Chemistry of Macromolecules’. 1961: New York, John Wiley & Sons.
S.A. Rice and M. Nagasawa, ‘Polyelectrolyte Solutions’, 1961: London, New York. Academic Press.
F. Osawa, ‘Polyelectrolytes’, 1970: New York, Marcel Dekker.
E. Selegny, M. Mandel and U.P. Strauss (Eds.), ‘Polyelectrolytes’, 1974:Dordrecht, Boston. D. Reidel.
H. Eisenberg, ‘Biological Macromolecules and Polyelectrolytes’, 1976: Oxford. Clarendon Press.
T. Kitano, A. Taguchi and M. Nagasawa, Macromolecules, 1980, 13, 57.
I. Noda, T. Tsuge and M. Nagasawa, J.phys.Chem., 1970, 74, 710.
C. Wolff, J. de Physique (Paris), 1978, 39, C2-169.
Y.M. Joshi and J. C.T. Kwak, J.phys.Chem., 1979, 83, 1978.
A. Katchalsky, Pure and Appl.Chem., 1971, 26, 327.
J. Th.G. Overbeek, Bull.soc.chim.Belg., 1948, 57, 252.
A. Katchalsky and P. Spitnik, J.polym.Sci., 1947, 2, 432.
M. Mandel, Europ.polym.J., 1970, 6, 807.
J. C. Leyte and M. Mandel, J.polym.Sci., 1964, A-2, 1879.
T. Alfrey, P.W. Berg and H. Morawetz, J.polym.Sci., 1951, 7, 543.
S. Lifson and A. Katchalsky, J.polym.Sci., 1953, 13, 43.
M. Fixman, J.chem.Phys., 1979, 70, 4995.
G.S. Manning, J.chem.Phys.,1969, 51, 924,934,3249.
G.S. Manning, in Ref.ld, p.9.
G.S. Manning, Ann.rev.phys.Chem.,1972, 23, 117.
J. Skolnick and M. Fixman, Macromolecules, 1977, 10, 844.
T. Odijk, J.polym.Sci.(Polym.Phys.Ed.), 1977, 15, 477.
T. Odijk, Polymer, 1978, 19, 989.
T. Odijk and M. Mandel, Physica, 1978, 93A, 298.
T. Odijk and A.C. Houwart, J.polym.Sci. (Polym.Phys.Ed.), 1978, 16, 627.
M. Mandel and J. Schouten, Macromolecules, 1980, 13, 1247.
T. Odijk, Biopolymers, 1979, 18, 3111.
P.G.de Germes, P. Pincus, R.M. Velasco and F. Brochard, J.de Physique(Paris), 1976, 37, 1461.
T. Odijk, Macromolcules, 1979, 12, 688.
R.S. Koene, H.W.J. Smit and M. Mandel, Chem.Phys.Letters, 1980, 74, 176.
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© 1983 Springer Science+Business Media New York
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Mandel, M. (1983). Aqueous Solutions of Polyelectrolytes. In: Finch, C.A. (eds) Chemistry and Technology of Water-Soluble Polymers. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-9661-2_10
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DOI: https://doi.org/10.1007/978-1-4757-9661-2_10
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