Abstract
Many of the crystalline oxide intercalation cathodes go through one or more phase transitions until they are completely discharged. In secondary batteries repetitive phase transitions during cycling cause problems. Apart from fatal irreversible transitions, e.g. due to overdischarge, ever highly reversible phase transitions are undesired, because they are related with dimensional changes and strains and — in the long run — may result in a “powderisation” of the cathode material.
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© 1987 Springer Science+Business Media New York
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Besenhard, J.O., Komenda, P., Schwake, M., Misailidis, N. (1987). Dimensionally stable vitreuos oxide intercalation cathodes for Li-batteries. In: Legrand, A.P., Flandrois, S. (eds) Chemical Physics of Intercalation. NATO ASI Series, vol 172. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-9649-0_40
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DOI: https://doi.org/10.1007/978-1-4757-9649-0_40
Publisher Name: Springer, Boston, MA
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