Synthesis of nickel- and iron-hydroxide graphite intercalation compounds and their application to alkaline secondary battery

  • Norio Iwashita
  • Michio Inagaki
Part of the NATO ASI Series book series (NSSB, volume 172)


Recently one of authors developed new process to synthesize different graphite intercalation compounds(GICs) of metal chlorides by using their molten salts[1,2]. Ternary GICs of NiCl2 and FeCl3 were obtained from the molten salts of NiCl2 and FeCl3 with different ratios at 400°C after 3 days without any intentional addition of chlorine gas. The compounds were found to be stable in air and even in boiling water.


Molten Salt Metal Chloride Intentional Addition Graphite Intercalation Compound Detailed Experimental Procedure 
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  1. 1.
    Inagaki, M., and Wang, Z. D., 1987, Synth. Met. 20: 1.CrossRefGoogle Scholar
  2. 2.
    Inagaki, M., Wang, Z. D., Okamoto, Y., and Ohira, M., 1987, Synth. Met. 20:9.CrossRefGoogle Scholar
  3. 3.
    Inagaki, M., Iwashita, N., and Maeda, Y., Electrochem. Acta(to be published).Google Scholar
  4. 4.
    Flandrois, S., Masson, J. M., and Rouillon, J. C, 1981, Synth. Met. 3: 195.CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 1987

Authors and Affiliations

  • Norio Iwashita
    • 1
  • Michio Inagaki
    • 1
  1. 1.Materials ScienceToyohashi University of TechnologyTempaku-cho, Toyohashi, 440Japan

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