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Synthesis of nickel- and iron-hydroxide graphite intercalation compounds and their application to alkaline secondary battery

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Chemical Physics of Intercalation

Part of the book series: NATO ASI Series ((NSSB,volume 172))

Abstract

Recently one of authors developed new process to synthesize different graphite intercalation compounds(GICs) of metal chlorides by using their molten salts[1,2]. Ternary GICs of NiCl2 and FeCl3 were obtained from the molten salts of NiCl2 and FeCl3 with different ratios at 400°C after 3 days without any intentional addition of chlorine gas. The compounds were found to be stable in air and even in boiling water.

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References

  1. Inagaki, M., and Wang, Z. D., 1987, Synth. Met. 20: 1.

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  2. Inagaki, M., Wang, Z. D., Okamoto, Y., and Ohira, M., 1987, Synth. Met. 20:9.

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  3. Inagaki, M., Iwashita, N., and Maeda, Y., Electrochem. Acta(to be published).

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  4. Flandrois, S., Masson, J. M., and Rouillon, J. C, 1981, Synth. Met. 3: 195.

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© 1987 Springer Science+Business Media New York

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Iwashita, N., Inagaki, M. (1987). Synthesis of nickel- and iron-hydroxide graphite intercalation compounds and their application to alkaline secondary battery. In: Legrand, A.P., Flandrois, S. (eds) Chemical Physics of Intercalation. NATO ASI Series, vol 172. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-9649-0_26

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  • DOI: https://doi.org/10.1007/978-1-4757-9649-0_26

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4757-9651-3

  • Online ISBN: 978-1-4757-9649-0

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